Citation: Li-Zhou WU, Yi-Wei LI, Yi-Dan CHANG, Na YANG, Xin-Yu GE, Jun-Feng HUI, Bin LIU, Gang-Lin XUE. Syntheses, Structures, and Magnetic Properties of Sandwich-Type Tungstobismuthate Containing Manganese[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 2056-2064. doi: 10.11862/CJIC.2022.189 shu

Syntheses, Structures, and Magnetic Properties of Sandwich-Type Tungstobismuthate Containing Manganese

Li-Zhou WU ^{1, 2,,} ,
Yi-Wei LI ¹ ,
Yi-Dan CHANG ¹ ,
Na YANG ¹ ,
Xin-Yu GE ¹ ,
Jun-Feng HUI ^2,, ,
Bin LIU ^3,, ,
Gang-Lin XUE ³

1.
Department of Chemistry and Chemical Engineering, Research Centre of New Advanced Materials, Ankang Research Centre of Zn-Based Materials Science and Technology, Ankang University, Ankang, Shaanxi 725000, China
2.
School of Chemical Engineering, Northwest University, Xi′an 710069, China
3.
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi′an 710069, China

Corresponding author: Li-Zhou WU, akxywlz@163.com Jun-Feng HUI, huijunfeng@126.com Bin LIU, liubin@nwu.edu.cn
Received Date: 9 February 2022
Revised Date: 6 August 2022

Figures(8)

A new sandwich - type tungstobismuthate containing manganese (Ⅱ), Na₉H[(Mn(H₂O)₃)₂(Mn(H₂O)₂) (WO₂) (BiW₉O₃₃)₂]·30H₂O (1), has been synthesized in the aqueous solutions and structurally characterized by elemental analyses, UV-Vis spectroscopy, IR spectroscopy, powder X -ray diffraction, single-crystal X-ray diffraction and ther- mogravimetric analysis. Single crystal X-ray analysis shows that the polyanion of 1 is composed of two trivacant β-B-[BiW₉O₃₃]^9- Keggin fragments joined together by two [(Mn(H₂O)₂)_0.5(WO₂)_0.5]²⁺ moieties and two [Mn(H₂O)₃]²⁺ subunits located in the inner and outer positions, respectively. Magnetic measurements indicate that 1 exhibits the antiferro-magnetic couplings between Mn(Ⅱ) centers.
- polyoxometalates,
- sandwich-type,
- crystal structure,
- magnetic property
1. [1]
  Rhule J T, Hill C L, Judd D A, Schinazi R F. Polyoxometalates in Medicine[J]. Chem. Rev., 1998,98(1):327-358. doi: 10.1021/cr960396q
2. [2]
  Long D L, Burkholder E, Cronin L. Polyoxometalate Clusters, Nanostructures and Materials: From Self Assembly to Designer Materials and Devices[J]. Chem. Soc. Rev., 2007,36(1):105-121. doi: 10.1039/B502666K
3. [3]
  Dolbecq A, Dumas E, Mayer C R, Mialane P. Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications[J]. Chem. Rev., 2010,110(10):6009-6048. doi: 10.1021/cr1000578
4. [4]
  Chen L, Chen W L, Wang X L, Li Y G, Su Z M, Wang E B. Polyoxometalates in Dye-Sensitized Solar Cells[J]. Chem. Soc. Rev., 2019,48(1):260-284. doi: 10.1039/C8CS00559A
5. [5]
  Zheng S T, Yang G Y. Recent Advances in Paramagnetic-TM-Substituted Polyoxometalates (TM=Mn, Fe, Co, Ni, Cu)[J]. Chem. Soc. Rev., 2012,41(22):7623-7646. doi: 10.1039/c2cs35133a
6. [6]
  Oms O, Dolbecq A, Mialane P. Diversity in Structures and Properties of 3d-Incorporating Polyoxotungstates[J]. Chem. Soc. Rev., 2012,41(22):7497-7536. doi: 10.1039/c2cs35148j
7. [7]
  Du D Y, Qin J S, Li S L, Su Z M, Lan Y Q. Recent Advances in Porous Polyoxometalate-Based Metal-Organic Framework Materials[J]. Chem. Soc. Rev., 2014,43(13):4615-4632. doi: 10.1039/C3CS60404G
8. [8]
  Anyushin A V, Kondinski A, Parac-Vogt T N. Hybrid Polyoxometalates as Post - functionalization Platforms: From Fundamentals to Emerging Applications[J]. Chem. Soc. Rev., 2020,49(2):382-432. doi: 10.1039/C8CS00854J
9. [9]
  Zhang X, Chen Q, Duncan D C, Campana C F, Hill C L. Multiiron Polyoxoanions. Syntheses, Characterization, X-ray Crystal Structures, and Catalysis of H₂O₂-Based Hydrocarbon Oxidations by [Fe^Ⅲ₄(H₂O)₂(P₂W₁₅O₅₆)₂]^12-[J]. Inorg. Chem., 1997,36(19):4208-4215. doi: 10.1021/ic970690g
10. [10]
  Bi L H, Wang E B, Peng J, Huang R D, Xu L, Hu C W. Crystal Structure and Replacement Reaction of Coordinated Water Molecules of the Heteropoly Compounds of Sandwich-Type Tungstoarsenates[J]. Inorg. Chem., 2000,39(4):671-679. doi: 10.1021/ic990596v
11. [11]
  Kortz U, Nellutla S, Stowe A C, Dalal N S, Rauwald U, Danquah W, Ravot D. Sandwich-Type Germanotungstates: Structure and Magnetic Properties of the Dimeric Polyoxoanions [M₄(H₂O)₂(GeW₉O₃₄)₂]^12- (M=Mn²⁺, Cu²⁺, Zn²⁺, Cd²⁺)[J]. Inorg. Chem., 2004,43(7):2308-2317. doi: 10.1021/ic0354421
12. [12]
  Bösing M, Nöh A, Loose I, Krebs B. Highly Efficient Catalysts in Directed Oxygen-Transfer Processes: Synthesis, Structures of Novel Manganese-Containing Heteropolyanions, and Applications in Regioselective Epoxidation of Dienes with Hydrogen Peroxide[J]. J. Am. Chem. Soc., 1998,120(29):7252-7259. doi: 10.1021/ja974281v
13. [13]
  Kortz U, Al-Kassem N K, Savelieff M G, Al Kadi N A, Sadakane M. Synthesis and Characterization of Copper-, Zinc-, Manganese-, and Cobalt-Substituted Dimeric Heteropolyanions, [(α-XW₉O₃₃)₂M₃ (H₂O)₃]^n- (n=12, X=As^Ⅲ, Sb^Ⅲ, M=Cu²⁺, Zn²⁺; n=10, X=Se^Ⅳ, Te^Ⅳ, M= Cu²⁺) and [(α-AsW₉O₃₃)₂WO(H₂O)M₂(H₂O)₂]^10- (M=Zn²⁺, Mn²⁺, Co²⁺)[J]. Inorg. Chem., 2001,40(18):4742-4749. doi: 10.1021/ic0101477
14. [14]
  Kortz U, Nellutla S, Stowe A C, Dalal N S, Van Tol J, Bassil B S. Structure and Magnetism of the Tetra-Copper(Ⅱ)-Substituted Heteropolyanion [Cu₄K₂(H₂O)₈ (α - AsW₉O₃₃)₂]^8-[J]. Inorg. Chem., 2004,43(1):144-154. doi: 10.1021/ic034697b
15. [15]
  Loose I, Droste E, Bössing M, Pohlmann H, Dickman M H, Rosu C, Pope M T, Krebs B. Heteropolymetalate Clusters of the Subvalent Main Group Elements Bi^Ⅲ and Sb^Ⅲ[J]. Inorg. Chem., 1999,38(11):2688-2694. doi: 10.1021/ic981313m
16. [16]
  Bösing M, Loose I, Pohlmann H, Krebs B. New Strategies for the Generation of Large Heteropolymetalate Clusters: The β-B-SbW₉ Fragment as a Multifunctional Unit[J]. Chem. Eur. J., 1997,3(8):1232-1237. doi: 10.1002/chem.19970030810
17. [17]
  Kortz U, Savelieff M G, Bassil B S, Keita B. Synthesis and Characterization of Iron(Ⅲ)-Substituted, Dimeric Polyoxotungstates, [Fe₄(H₂O)₁₀ (β-XW₉O₃₃)₂]^n- (n=6, X=As^Ⅲ, Sb^Ⅲ; n=4, X=Se^Ⅳ, Te^Ⅳ)[J]. Inorg. Chem., 2002,41(4):783-789. doi: 10.1021/ic010855s
18. [18]
  Knoth W H, Domaille P J, Farlee R D. Anions of the Type (RMOH₂)₃ W₁₈P₂O₆₈^9- and [H₂OCo]₃W₁₈P₂O₆₈^12-. A Reinvestigation of "B, β-W₉PO₃₄^9-"[J]. Organometallics, 1985,4(1):62-68. doi: 10.1021/om00120a012
19. [19]
  Xin F B, Pope M T. Lone-Pair-Induced Chirality in Polyoxotungstate Structures: Tin(Ⅱ) Derivatives of A-Type XW₉O₃₄^n-(X=P, Si). Interaction with Amino Acids[J]. J. Am. Chem. Soc., 1996,118(33):7731-7736. doi: 10.1021/ja954045p
20. [20]
  Dai X J, Luo Y S, Zhang W D, Fu S Y. Facile Hydrothermal Synthesis and Photocatalytic Activity of Bismuth Tungstate Hierarchical Hollow Spheres with an Ultrahigh Surface Area[J]. Dalton Trans., 2010,39(14):3426-3432. doi: 10.1039/b923443h
21. [21]
  Chen Z, Qian L W, Zhu J, Yuan Y P, Qian X F. Controlled Synthesis of Hierarchical Bi₂WO₆ Microspheres with Improved Visible-Light-Driven Photocatalytic Activity[J]. CrystEngComm, 2010,12(7):2100-2106. doi: 10.1039/b921228k
22. [22]
  Tian Y, Hua G M, Xu W, Li N, Fang M, Zhang L D. Bismuth Tungstate Nano/Microstructures: Controllable Morphologies, Growth Mechanism and Photocatalytic Properties[J]. J. Alloy. Compd., 2011,509(3):724-730. doi: 10.1016/j.jallcom.2010.09.010
23. [23]
  Rodewald D, Jeannin Y. Two New Bismutho (Ⅲ) Polytungstates, Na₁₀[Bi₂Ni₂W₂₀O₇₀(H₂O)₆]·26H₂O and Na₈[Bi₂W₂₀O₇₀(OH)₆]·31H₂O[J]. Comptes Rendus Acad. Sci. Ser. Ⅱ C, 1998,1(3):175-181.
24. [24]
  Rosu C, Weakley T J R. Redetermination of Sodium [Bis(pentatungstato)cerate (Ⅳ)]^8- 30-Hydrate, Na₈[Ce(W₅O₁₈)₂] ·30H₂O[J]. Acta Cryst., 1999,55(4)IUC9900034.
25. [25]
  Rosu C, Rusu M, Casän-Pastor N, Gómez-Garciá C J. Synthesis, Characterization and Electrochemistry of Cobalt (Ⅱ) and Copper (Ⅱ) Complexes of Bismutho (Ⅲ) Polyoxotungstate Ligand Anion[J]. Synth. React. Inorganic Met.-Org. Chem., 2000,30(3):369-377. doi: 10.1080/00945710009351769
26. [26]
  Sun C Y, Liu S X, Wang C L, Xie L H, Zhang C D, Wang E B. Reactions of Trivacant Lone-Pair-Containing Tungstobismutate and Electrochemical Behaviors of Its Sandwich - Type Products[J]. J. Coord. Chem., 2007,60(5):567-579. doi: 10.1080/00958970600894972
27. [27]
  Krebs B, Klein R. Molecular Organization and Engineering. Berlin: Springer, 1994: 43-59
28. [28]
  Rusu D, Roşu C, Crăciun C, David L, Rusu M, Marcu G. FT-IR, UV-Vis and EPR Investigations of Multicopper Polyoxotungstates with Bi^Ⅲ as Heteroatom[J]. J. Mol. Struct., 2001,563:427-433.
29. [29]
  Bernt K, Elisabeth D, Markus P, Guido V. Novel Keggin Stannato(Ⅱ) Tungstates with Lone - Pair Assembling Atoms. Syntheses, Crystal Structure and Spectroscopic Studies[J]. Comptes Rendus Acad. Sci. Ser. Ⅱ C, 2000,3(3):205-210.
30. [30]
  WU J, WANG C X, SU Z H, YU K, XU Y L, ZHOU B B. Synthesis, Crystal Structures and Electrochemical Properties of Three New One-Dimensional Compounds Based on the BiW₉O₃₃ Unit[J]. Chin. J. Struct. Chem., 2012,31(2):271-279.
31. [31]
  Drewes D, Limanski E M, Piepenbrink M, Krebs B. New Heteropolyanions of Tungsten with Vanadium(Ⅳ) as Heteroatom[J]. Z. Anorg. Allg. Chem., 2004,630(1):58-62. doi: 10.1002/zaac.200300245
32. [32]
  Bi L H, Dickman M H, Kortz U. The Palladium (Ⅱ) - Decorated 22-Tungsto-2-Bismuthate (Ⅲ), [Pd₃(H₂O)₉Bi₂W₂₂O₇₆]^8-[J]. CrystEngComm, 2009,11(6):965-966. doi: 10.1039/b820888c
33. [33]
  Bi L H, Hou G F, Bao Y Y, Li B, Wu L X, Gao Z M, McCormac T, Mal S S, Dickman M H, Kortz U. Syntheses and Crystal Structures of dmso-Coordinated Tungstoantimonates(Ⅲ) and -bismuthates(Ⅲ)[J]. Eur. J. Inorg. Chem., 2009,34:5259-5266.
34. [34]
  Sartorel A, Carraro M, Scorrano G, Bassil B S, Dickman M H, Keita B, Nadjo L, Kortz U, Bonchio M. Iron-Substituted Polyoxotungstates as Inorganic Synzymes: Evidence for a Biomimetic Pathway in the Catalytic Oxygenation of Catechols[J]. Chem. Eur. J., 2009,15(32):7854-7858. doi: 10.1002/chem.200901392
35. [35]
  Bi L H, Al-Kadamany G, Chubarova E V, Dickman M H, Chen L, Gopala D S, Richards R M, Keita B, Nadjo L, Jaensch H, Mathys G, Kortz U. Organo - Ruthenium Supported Heteropolytungstates: Synthesis, Structure, Electrochemistry, and Oxidation Catalysis[J]. Inorg. Chem., 2009,48(21):10068-10077. doi: 10.1021/ic9009306
36. [36]
  Wang L, Zhou B B, Yu K, Su Z H, Gao S, Chu L L, Liu J R, Yang G Y. Novel Antitumor Agent, Trilacunary Keggin - Type Tungstobismuthate, Inhibits Proliferation and Induces Apoptosis in Human Gastric Cancer SGC-7901 Cells[J]. Inorg. Chem., 2013,52(9):5119-5127. doi: 10.1021/ic400019r
37. [37]
  Wang Z J, Zhang L C, Zhu Z M, Chen W L, You W S, Wang E B. Two New Sandwich-Type Tungstobismuthates Constructed from Trivacant Keggin Units, Estertin and Transition Metals[J]. Inorg. Chem. Commun., 2012,17:151-154. doi: 10.1016/j.inoche.2011.12.038
38. [38]
  Zhang W, Liu S X, Feng D, Zhang C D, Sun P, Ma F J. Two Novel Krebs - Type Polyoxoanions [Cu^Ⅰ₂(WO₂)₂(β - XW₉O₃₃)₂]^12- (X=Sb^Ⅲ, Bi^Ⅲ) Resulting in 2D Layer Structures Linked by Copper(Ⅰ) Ions and Copper(Ⅱ) Complex Groups[J]. J. Mol. Struct., 2009,936(1/2/3):194-198.
39. [39]
  Zhang L, Zhang Y, Hao Z M, Luo F. Synthesis, Structure, and Magnetic Properties of Three Novel Sandwich-Type Tungstobismuthates with Triethanolamine[J]. Z. Anorg. Allg. Chem., 2010,636(11):1991-1997. doi: 10.1002/zaac.201000011
40. [40]
  Krebs B, Loose I, Bösing M, Nöh E, Droste E. Novel Polymeric Heteropolytungstates and -molybdates[J]. Comptes Rendus Acad. Sci. Ser. Ⅱ C, 1998,1(5):351-360.
41. [41]
  WANG Y J, ZHANG H H, HUANG C C, YU X H, SUN Q Z, SUN R Q. Synthesis and Crystal Structure of the Heteropolymate Compound Na₃H₂[Ce₃(H₂O)₁₈Bi₂W₂₂O₇₆]·23H₂O[J]. Chin. J. Struct. Chem., 2004,23(8):902-907. doi: 10.3969/j.issn.0254-5861.2004.08.013
42. [42]
  Ozawa Y, Sasaki Y. Synthesis and Crystal Structure of [(CH₃)₄N]₆[H₃BiW₁₈O₆₀][J]. Chem. Lett., 1987,16(5):923-926. doi: 10.1246/cl.1987.923
43. [43]
  WANG H L, XUE G L, WANG J W, WANG D Q, LI J, SHI Q Z. Synthesis, Crystal Structure and Magnetic Property of Sandwich-TypeHeteropolyoxometalate Na₉[{Na(H₂O)}₃{Co(C₃H₄N₂)}₃(BiW₉O₃₃)₂]·33H₂O[J]. Acta Chim. Sinica, 2003,61(11):1839-1843. doi: 10.3321/j.issn:0567-7351.2003.11.027
44. [44]
  LIU H, XU L, QIU Y F, AN W J, JIN Y N, XU B B. Synthesis and Crystal Structure of a Novel Supramolecular (the original text is superamolecular) Compound Based on Imidazole Functionalized Sandwich Type of Tungstobismutate[J]. Chem. J. Chinese Universities, 2006,27(8):1409-1412. doi: 10.3321/j.issn:0251-0790.2006.08.004
45. [45]
  Yamase T, Ishikawa E, Fukaya K, Nojiri H, Taniguchi T, Atake T. Spin - Frustrated (VO)₃⁶⁺ - Triangle - Sandwiching Octadecatungstates as a New Class of Molecular Magnets[J]. Inorg. Chem., 2004,43(25):8150-8157. doi: 10.1021/ic049669n
46. [46]
  Botar B, Yamase T, Ishikawa E. Synthesis and Crystal Structure of a Novel Vanadium-Containing Tungstobismutate (Ⅲ) K₁₂[(VO)₃(BiW₉O₃₃)₂]·30H₂O[J]. Inorg. Chem. Commun., 2001,4(10):551-554. doi: 10.1016/S1387-7003(01)00263-5
47. [47]
  Alizadeh M H, Mohadeszadeh M. Sandwich-Type Uranium-Substituted of Bismuthotungstate: Synthesis and Structure Determination of [Na(UO₂)₂(H₂O)₄(BiW₉O₃₃)₂]^13-[J]. J. Clust. Sci., 2008,19(2):435-443. doi: 10.1007/s10876-008-0184-7
48. [48]
  Rusu D, Crăciun C, Barra A L, David L, Rusu M, Roşu C, Cozar O, Marcu G. Spectroscopic and Electron Paramagnetic Resonance Behavior of Trinuclear Metallic Clusters Encapsulated in [Mⁿ⁺₃(H₂O)_x (BiW₉O₃₃)₂]^(18-3n)- Heteropolyanion (Mⁿ⁺=(VO)^Ⅱ, x=0 and Mⁿ⁺=Cr^Ⅲ, Mn^Ⅱ, Fe^Ⅲ, Co^Ⅱ, N^Ⅲ, Cu^Ⅱ, x=3)[J]. J. Chem. Soc. Dalton Trans., 2001(19):2879-2887. doi: 10.1039/b104848c
49. [49]
  Rosu C, Rasu D, Weakley T J R. X-ray Structure of Dodecasodium Tricopper(Ⅱ) Bis[nonatungstabismuthate(Ⅲ)] Hydrate, a Polyoxometalate Salt Containing α-B-BiW₉O₃₃ Units[J]. J. Chem. Crystallogr., 2003,33(10):751-755. doi: 10.1023/A:1026103306556
50. [50]
  Xu Z H, Liu J, Wang E B, Qin C, Wu Q, Shi Q. Synthesis, Characterization and Crystal Structure of a Novel Vanadium-Substituted Polyoxometalate Based on the [BiW₉O₃₃]^9- Units[J]. J. Mol. Struct., 2008,873(1/2/3):41-45.
51. [51]
  Liu H, Xu L, Gao G G, Li F Y, Jiang N. Sandwich Transitional Metal Complexes with Tungstobismuthates and 1-Methylimidazole Ligands: Syntheses, Structures and Magnetic Properties[J]. J. Mol. Struct., 2008,873(1/2/3):124-130.
52. [52]
  David L, Crǎciun C, Chis V, Tetean R. EPR and HF-EPR Study of a Trinuclear Mn^Ⅱ Cluster Encapsulated in One Sandwich-Type Heteropolyanion[J]. Solid State Commun., 2002,121(12):675-678. doi: 10.1016/S0038-1098(02)00068-6
53. [53]
  Xu X, Zhang L, Zhang Y, Qi B, Luo F. Synthesis and Crystal Structure of a Sandwich-Type Transition Metal Complex with Tungstobismutate and Triethanolamine[J]. Z. Naturforsch. B, 2009,64(7):821-825. doi: 10.1515/znb-2009-0708
54. [54]
  Liu H, Qin C, Wei Y G, Xu L, Gao G G, Li F Y, Qu X S. Copper-Complex-Linked Polytungsto-Bismuthate (-Antimonite) Chain Containing Sandwich Cu (Ⅱ) Ions Partially Modified with Imidazole Ligand[J]. Inorg. Chem., 2008,47(10):4166-4172. doi: 10.1021/ic7022264
55. [55]
  Liu H, Liu Y, Liu H Y, Shi C H, Liu F H, Liu H L. Trinuclear Cobalt (Ⅱ) Sandwiched Polyoxotungstobismuthate with Antennal Copper(Ⅱ)-Complex: A New Method to Combine Hetero-Transition-Metallic Ions[J]. Inorg. Chem. Commun., 2009,12(1):1-3. doi: 10.1016/j.inoche.2008.10.009
56. [56]
  Tan H Q, Zhang Z M, Liu D, Qi Y F, Wang E B, Li Y G. A New Sandwich Polyoxometalate Constructed from a Zn₆¹²⁺ Hexagon Cluster Sandwiched by Two B-α-[BiW₉O₃₃]^9-[J]. J. Cluster Sci., 2008,19(3):543-550. doi: 10.1007/s10876-008-0188-3
57. [57]
  Copping R, Gaunt A J, May I, Sharrad C A, Collison D, Helliwell M, Foxc O D, Jones C J. Oxoneptunium(Ⅴ) as Part of the Framework of a Polyoxometalate[J]. Chem. Commun., 2006(36):3788-3790. doi: 10.1039/b608589j
58. [58]
  Zeng L, Chen Y Q, Liu G C, Zhang J X. Large Polytungstobismuthate Aggregate Linked by Unusual Silver-Tungsten-Bismuth Cluster[J]. J. Mol. Struct., 2009,930(1/2/3):176-179.
59. [59]
  Botar B, Yamase T, Ishikawa E. A Highly Nuclear Vanadium-Containing Tungstobismutate: Synthesis and Crystal Structure of K₁₁H[(BiW₉O₃₃)₃Bi₆(OH)₃(H₂O)₃V₄O₁₀]·25H₂O[J]. Inorg. Chem. Commun., 2000,3(11):579-584. doi: 10.1016/S1387-7003(00)00146-5
60. [60]
  Cui K Y, Li F Y, Xu L, Xu B B, Jiang N, Wang Y C, Zhang J P. Lanthanide-Tungstobismuthate Clusters Based on [BiW₉O₃₃]^9- Building Units: Synthesis, Crystal Structures, Luminescent and Magnetic Properties[J]. Dalton Trans., 2012,41(16):4871-4877. doi: 10.1039/c2dt11478j
61. [61]
  Yamase T. Photo - and Electrochromism of Polyoxometalates and Related Materials[J]. Chem. Rev., 1998,98(1):307-325. doi: 10.1021/cr9604043
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11. [11]
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沈阳化工大学材料科学与工程学院沈阳 110142