Citation: Fu-Shao LI, Ying-Xian XU, Qing-Qing WU, Hu-Jun SHEN, Ming-Sen DENG. Anode Material Sr₂MgMoO₆: Preparation and Catalytic Performance[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 2028-2036. doi: 10.11862/CJIC.2022.187 shu

Anode Material Sr₂MgMoO₆: Preparation and Catalytic Performance

Guizhou Provincial Key Laboratory of Computational Nano-material Science, Guizhou Education University, Guiyang 550018, China

Corresponding author: Fu-Shao LI, lifushao@126.com Ming-Sen DENG, deng@gznc.edu.cn
Received Date: 12 April 2022
Revised Date: 18 July 2022

Figures(8)

Double-perovskite oxide Sr₂MgMoO₆ (SMMO) was prepared as anode material for solid-oxide fuel cells by the sol-gel route. The effect of the material preparation scenario on the phase constituents, transport property, and catalyzing activity for H₂ oxidization was investigated. The results show that the preparation process of SMMO requires strict control, and a phase-pure sample with a double-perovskite structure can be hardly synthesized by a one-step annealing reaction, and a high purity grade of SMMO requires the repeated thorough mixing and full annealing. In the meanwhile, impurity phase SrMoO₄ in a very small amount is almost unavoidable. The impure substance in samples affects a great deal of the electrical conductivity of this material, and a purer sample exhibits better conductive performance. The purity of SMMO has a tremendous impact on the electrochemical performance of this material, and a purer sample exhibits a lower anode interfacial resistance, a higher catalyzing activity for H₂ oxidizing, and a larger power output of the corresponding single cell. At a temperature of 800 ℃, the area-specific resistance of the SMMO anode was as low as 1.07 Ω·cm², and power output from the corresponding single cell reached to 710 mW·cm^-2.
- solid-oxide fuel cell,
- anode,
- double-perovskite,
- electrochemical performance
1. [1]
  Steele B C H, Heinzel A. Materials for Fuel-Cell Technologies[J]. Nature, 2001,414:345-352. doi: 10.1038/35104620
2. [2]
  Haile S M. Fuel Cell Materials and Components[J]. Acta Mater., 2003,51:5981-6000. doi: 10.1016/j.actamat.2003.08.004
3. [3]
  Wachsman E D, Lee K T. Lowering the Temperature of Solid Oxide Fuel Cells[J]. Science, 2011,334:935-939. doi: 10.1126/science.1204090
4. [4]
  Marinha D, Dessemond L, Djurado E. Comprehensive Review of Current Developments in IT-SOFCs[J]. Curr. Inorg. Chem., 2013,3:2-22. doi: 10.2174/1877944111303010003
5. [5]
  Gao Z, Mogni L V, Miller E C, Railsback J G, Barnett S A. A Perspective on Low-Temperature Solid Oxide Fuel Cells[J]. Energy Environ. Sci., 2016,9:1602-1644. doi: 10.1039/C5EE03858H
6. [6]
  Zhang Y, Knibbe R, Sunarso J, Zhong Y J, Zhou W, Shao Z P, Zhu Z H. Recent Progress on Advanced Materials for Solid-Oxide Fuel Cells Operating below 500 ℃[J]. Adv. Mater., 2017,291700132. doi: 10.1002/adma.201700132
7. [7]
  Shao Z, Haile S M. A High-Performance Cathode for the Next Generation of Solid-Oxide Fuel Cells[J]. Nature, 2004,431:170-173. doi: 10.1038/nature02863
8. [8]
  Mahato N, Banerjee A, Gupta A, Omar S, Balani K. Progress in Material Selection for Solid Oxide Fuel Cell Technology: A Review[J]. Prog. Mater. Sci., 2015,72:141-337. doi: 10.1016/j.pmatsci.2015.01.001
9. [9]
  Zhang Z B, Zhu Y L, Zhong Y J, Zhou W, Shao Z P. Anion Doping: A New Strategy for Developing High-Performance Perovskite-Type Cathode Materials of Solid Oxide Fuel Cells[J]. Adv. Energy Mater., 2017,71700242. doi: 10.1002/aenm.201700242
10. [10]
  Ji Q Q, Bi L, Zhang J T, Cao H J, Zhao X S. The Role of Oxygen Vacancies of ABO₃ Perovskite Oxides in the Oxygen Reduction Reaction[J]. Energy Environ. Sci., 2020,13:1408-1428. doi: 10.1039/D0EE00092B
11. [11]
  Zhu X D, Sun K N, Zhang N Q, Chen X B, Wu L J, Jia D C. Improved Electrochemical Performance of SrCo_0.8Fe_0.2O_3-δ-La_0.45Ce_0.55O_2-δ Composite Cathodes for IT-SOFC[J]. Electrochem. Commun., 2007,9:431-435. doi: 10.1016/j.elecom.2006.09.029
12. [12]
  Zhu X D, Le S R, Chen X B, Sun K N, Yuan Y X, Zhang N Q. Chemical Compatibility, Thermal Expansion Matches and Electrochemical Performance of SrCo_0.8Fe_0.2O_3-δ-La_0.45Ce_0.55O_2-δ Composite Cathodes for Intermediate-Temperature Solid Oxide Fuel Cells[J]. Int. J. Hydrogen Energy, 2011,36:12549-12554. doi: 10.1016/j.ijhydene.2011.06.111
13. [13]
  Fu Q X, Tietz F, Stöver D. La_0.4Sr_0.6Ti_1-xMn_xO_3-δ Perovskites as Anode Materials for Solid Oxide Fuel Cells[J]. J. Electrochem. Soc., 2006,153D74. doi: 10.1149/1.2170585
14. [14]
  Escudero M J, Irvine J T S, Daza L. Development of Anode Material Based on La-Substituted SrTiO₃ Perovskites Doped with Manganese and/or Gallium for SOFC[J]. J. Power Sources, 2009,192:43-50. doi: 10.1016/j.jpowsour.2008.11.132
15. [15]
  Liu Q, Dong X H, Xiao G L, Zhao F, Chen F L. A Novel Electrode Material for Symmetrical SOFCs[J]. Adv. Mater., 2010,22:5478-5482. doi: 10.1002/adma.201001044
16. [16]
  Munoz-Garcia A B, Bugaris D E, Pavone M, Hodges J P, Huq A, Chen F, zur Loye H C, Carter E A. Unveiling Structure-Property Relationships in Sr₂Fe_1.5Mo_0.5O_6-δ, An Electrode Material for Symmetric Solid Oxide Fuel Cells[J]. J. Am. Chem. Soc., 2012,134:6826-6833. doi: 10.1021/ja300831k
17. [17]
  Xie Z X, Zhao H L, Du Z H, Chen T, Chen N, Liu X T, Skinner S J. Effects of Co Doping on the Electrochemical Performance of Double Perovskite Oxide Sr₂MgMoO_6-δ as an Anode Material for Solid Oxide Fuel Cells[J]. J. Phys. Chem. C, 2012,116:9734-9743. doi: 10.1021/jp212505c
18. [18]
  Du Z H, Zhao H L, Yi S, Xia Q, Gong Y, Zhang Y, Cheng X, Li Y, Gu L, Świerczek K. High-Performance Anode Material Sr₂FeMo_0.65Ni_0.35O_6-δ with In Situ Exsolved Nanoparticle Catalyst[J]. ACS Nano, 2016,10:8660-8669. doi: 10.1021/acsnano.6b03979
19. [19]
  Falcón H, Barbero J A, Araujo G, Casais M T, Martínez-Lope M J, Alonso J A, Fierro J L G. Double Perovskite Oxides A₂FeMoO_6-δ (A= Ca, Sr and Ba) as Catalysts for Methane Combustion Appl[J]. Catal. B-Environ., 2004,53:37-45. doi: 10.1016/j.apcatb.2004.05.004
20. [20]
  Vasala S, Yamauchi H, Karppinen M. Role of SrMoO₄ in Sr₂MgMoO₆ Synthesis[J]. J. Solid State Chem., 2011,184:1312-1317. doi: 10.1016/j.jssc.2011.03.045
21. [21]
  Dager P K, Chanquía C M, Mogni L, Caneiro A. Synthesis of Pure-Phase Sr₂MgMoO₆ Nanostructured Powder by the Combustion Method[J]. Mater. Lett., 2015,141:248-251. doi: 10.1016/j.matlet.2014.11.037
22. [22]
  Marrero-López D, Peña-Martínez J, Ruiz-Morales J C, Pérez-Coll D, Aranda M A G, Núñez P. Synthesis, Phase Stability and Electrical Conductivity of Sr₂MgMoO_6-δ Anode[J]. Mater. Res. Bull., 2008,43:2441-2450. doi: 10.1016/j.materresbull.2007.07.032
23. [23]
  Marrero-López D, Peña-Martínez J, Ruiz-Morales J C, Gabás M, Núñez P, Aranda M A G, Ramos-Barrado J R. Redox Behaviour, Chemical Compatibility and Electrochemical Performance of Sr₂MgMoO_6-δ as SOFC Anode[J]. Solid State Ionics, 2010,180:1672-1682. doi: 10.1016/j.ssi.2009.11.005
24. [24]
  Jiang L, Liang G, Han J T, Huang Y H. Effects of Sr-Site Deficiency on Structure and Electrochemical Performance in Sr₂MgMoO₆ for Solid-Oxide Fuel Cell[J]. J. Power Sources, 2014,270:441-448. doi: 10.1016/j.jpowsour.2014.07.079
25. [25]
  Wei T, Huang Y H, Zhang Q, Yuan L X, Yang J Y, Sun Y M, Hu X L, Zhang W X, Goodenough J B. Thermoelectric Solid-Oxide Fuel Cells with Extra Power Conversion from Waste Heat[J]. Chem. Mater., 2012,24:1401-1403. doi: 10.1021/cm300159w
26. [26]
  Huang Y H, Liang G, Croft M, Lehtimäki M, Karppinen M, Goodenough J B. Double-Perovskite Anode Materials Sr₂MMoO₆ (M=Co, Ni) for Solid Oxide Fuel Cells[J]. Chem. Mater., 2009,21:2319-2326. doi: 10.1021/cm8033643
27. [27]
  Zhu X D, Zhang N D, Wu L J, Sun K N, Yuan Y X. Preparation and Performance of Large-Area La_0.9Sr_0.1Ga_0.8Mg_0.2O_3-δ Electrolyte for Intermediate Temperature Solid Oxide Fuel Cell[J]. J. Power Sources, 2010,195:7583-7586. doi: 10.1016/j.jpowsour.2010.05.060
28. [28]
  Li F S, Jiang L, Zeng R, Wang F, Xu Y X, Huang Y H. Hetero-Structured La_0.5Sr_0.5CoO_3-δ/LaSrCoO_4±δ Cathode with High Electrocatalytic Activity for Solid-Oxide Fuel Cells[J]. Int. J. Hydrogen Energy, 2017,42:29463-29471. doi: 10.1016/j.ijhydene.2017.10.001
29. [29]
  Li F S, Xu Y X, Xia S B, Liu J J, Yan Y X, Cheng F X, Jiang L, Huang Y H. LaSrCoO_4±δ@La_0.5Sr_0.5CoO_3-δ Core-Shell Hybrid as the Cathode Materials for Solid Oxide Fuel Cells[J]. J. Alloy. Compd., 2020,819152996. doi: 10.1016/j.jallcom.2019.152996
30. [30]
  Bernuy-Lopez C, Allix M, Bridges C A, Claridge J B, Rosseinsky M J. Sr₂MgMoO_6-δ: Structure, Phase Stability, and Cation Site Order Control of Reduction[J]. Chem. Mater., 2007,19:1035-1043. doi: 10.1021/cm0624116
31. [31]
  Adler S B. Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes[J]. Chem. Rev., 2004,104:4791-4844. doi: 10.1021/cr020724o
32. [32]
  Klotz D, Weber A, Ivers-Tiffée E. Practical Guidelines for Reliable Electrochemical Characterization of Solid Oxide Fuel Cells[J]. Electrochim. Acta, 2017,227:110-126. doi: 10.1016/j.electacta.2016.12.148
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Anode Material Sr₂MgMoO₆: Preparation and Catalytic Performance