Citation: Fu-Shao LI, Ying-Xian XU, Qing-Qing WU, Hu-Jun SHEN, Ming-Sen DENG. Anode Material Sr2MgMoO6: Preparation and Catalytic Performance[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 2028-2036. doi: 10.11862/CJIC.2022.187 shu

Anode Material Sr2MgMoO6: Preparation and Catalytic Performance

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  • Double-perovskite oxide Sr2MgMoO6 (SMMO) was prepared as anode material for solid-oxide fuel cells by the sol-gel route. The effect of the material preparation scenario on the phase constituents, transport property, and catalyzing activity for H2 oxidization was investigated. The results show that the preparation process of SMMO requires strict control, and a phase-pure sample with a double-perovskite structure can be hardly synthesized by a one-step annealing reaction, and a high purity grade of SMMO requires the repeated thorough mixing and full annealing. In the meanwhile, impurity phase SrMoO4 in a very small amount is almost unavoidable. The impure substance in samples affects a great deal of the electrical conductivity of this material, and a purer sample exhibits better conductive performance. The purity of SMMO has a tremendous impact on the electrochemical performance of this material, and a purer sample exhibits a lower anode interfacial resistance, a higher catalyzing activity for H2 oxidizing, and a larger power output of the corresponding single cell. At a temperature of 800 ℃, the area-specific resistance of the SMMO anode was as low as 1.07 Ω·cm2, and power output from the corresponding single cell reached to 710 mW·cm-2.
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    1. [1]

      Steele B C H, Heinzel A. Materials for Fuel-Cell Technologies[J]. Nature, 2001,414:345-352. doi: 10.1038/35104620

    2. [2]

      Haile S M. Fuel Cell Materials and Components[J]. Acta Mater., 2003,51:5981-6000. doi: 10.1016/j.actamat.2003.08.004

    3. [3]

      Wachsman E D, Lee K T. Lowering the Temperature of Solid Oxide Fuel Cells[J]. Science, 2011,334:935-939. doi: 10.1126/science.1204090

    4. [4]

      Marinha D, Dessemond L, Djurado E. Comprehensive Review of Current Developments in IT-SOFCs[J]. Curr. Inorg. Chem., 2013,3:2-22. doi: 10.2174/1877944111303010003

    5. [5]

      Gao Z, Mogni L V, Miller E C, Railsback J G, Barnett S A. A Perspective on Low-Temperature Solid Oxide Fuel Cells[J]. Energy Environ. Sci., 2016,9:1602-1644. doi: 10.1039/C5EE03858H

    6. [6]

      Zhang Y, Knibbe R, Sunarso J, Zhong Y J, Zhou W, Shao Z P, Zhu Z H. Recent Progress on Advanced Materials for Solid-Oxide Fuel Cells Operating below 500 ℃[J]. Adv. Mater., 2017,291700132. doi: 10.1002/adma.201700132

    7. [7]

      Shao Z, Haile S M. A High-Performance Cathode for the Next Generation of Solid-Oxide Fuel Cells[J]. Nature, 2004,431:170-173. doi: 10.1038/nature02863

    8. [8]

      Mahato N, Banerjee A, Gupta A, Omar S, Balani K. Progress in Material Selection for Solid Oxide Fuel Cell Technology: A Review[J]. Prog. Mater. Sci., 2015,72:141-337. doi: 10.1016/j.pmatsci.2015.01.001

    9. [9]

      Zhang Z B, Zhu Y L, Zhong Y J, Zhou W, Shao Z P. Anion Doping: A New Strategy for Developing High-Performance Perovskite-Type Cathode Materials of Solid Oxide Fuel Cells[J]. Adv. Energy Mater., 2017,71700242. doi: 10.1002/aenm.201700242

    10. [10]

      Ji Q Q, Bi L, Zhang J T, Cao H J, Zhao X S. The Role of Oxygen Vacancies of ABO3 Perovskite Oxides in the Oxygen Reduction Reaction[J]. Energy Environ. Sci., 2020,13:1408-1428. doi: 10.1039/D0EE00092B

    11. [11]

      Zhu X D, Sun K N, Zhang N Q, Chen X B, Wu L J, Jia D C. Improved Electrochemical Performance of SrCo0.8Fe0.2O3-δ-La0.45Ce0.55O2-δ Composite Cathodes for IT-SOFC[J]. Electrochem. Commun., 2007,9:431-435. doi: 10.1016/j.elecom.2006.09.029

    12. [12]

      Zhu X D, Le S R, Chen X B, Sun K N, Yuan Y X, Zhang N Q. Chemical Compatibility, Thermal Expansion Matches and Electrochemical Performance of SrCo0.8Fe0.2O3-δ-La0.45Ce0.55O2-δ Composite Cathodes for Intermediate-Temperature Solid Oxide Fuel Cells[J]. Int. J. Hydrogen Energy, 2011,36:12549-12554. doi: 10.1016/j.ijhydene.2011.06.111

    13. [13]

      Fu Q X, Tietz F, Stöver D. La0.4Sr0.6Ti1-xMnxO3-δ Perovskites as Anode Materials for Solid Oxide Fuel Cells[J]. J. Electrochem. Soc., 2006,153D74. doi: 10.1149/1.2170585

    14. [14]

      Escudero M J, Irvine J T S, Daza L. Development of Anode Material Based on La-Substituted SrTiO3 Perovskites Doped with Manganese and/or Gallium for SOFC[J]. J. Power Sources, 2009,192:43-50. doi: 10.1016/j.jpowsour.2008.11.132

    15. [15]

      Liu Q, Dong X H, Xiao G L, Zhao F, Chen F L. A Novel Electrode Material for Symmetrical SOFCs[J]. Adv. Mater., 2010,22:5478-5482. doi: 10.1002/adma.201001044

    16. [16]

      Munoz-Garcia A B, Bugaris D E, Pavone M, Hodges J P, Huq A, Chen F, zur Loye H C, Carter E A. Unveiling Structure-Property Relationships in Sr2Fe1.5Mo0.5O6-δ, An Electrode Material for Symmetric Solid Oxide Fuel Cells[J]. J. Am. Chem. Soc., 2012,134:6826-6833. doi: 10.1021/ja300831k

    17. [17]

      Xie Z X, Zhao H L, Du Z H, Chen T, Chen N, Liu X T, Skinner S J. Effects of Co Doping on the Electrochemical Performance of Double Perovskite Oxide Sr2MgMoO6-δ as an Anode Material for Solid Oxide Fuel Cells[J]. J. Phys. Chem. C, 2012,116:9734-9743. doi: 10.1021/jp212505c

    18. [18]

      Du Z H, Zhao H L, Yi S, Xia Q, Gong Y, Zhang Y, Cheng X, Li Y, Gu L, Świerczek K. High-Performance Anode Material Sr2FeMo0.65Ni0.35O6-δ with In Situ Exsolved Nanoparticle Catalyst[J]. ACS Nano, 2016,10:8660-8669. doi: 10.1021/acsnano.6b03979

    19. [19]

      Falcón H, Barbero J A, Araujo G, Casais M T, Martínez-Lope M J, Alonso J A, Fierro J L G. Double Perovskite Oxides A2FeMoO6-δ (A= Ca, Sr and Ba) as Catalysts for Methane Combustion Appl[J]. Catal. B-Environ., 2004,53:37-45. doi: 10.1016/j.apcatb.2004.05.004

    20. [20]

      Vasala S, Yamauchi H, Karppinen M. Role of SrMoO4 in Sr2MgMoO6 Synthesis[J]. J. Solid State Chem., 2011,184:1312-1317. doi: 10.1016/j.jssc.2011.03.045

    21. [21]

      Dager P K, Chanquía C M, Mogni L, Caneiro A. Synthesis of Pure-Phase Sr2MgMoO6 Nanostructured Powder by the Combustion Method[J]. Mater. Lett., 2015,141:248-251. doi: 10.1016/j.matlet.2014.11.037

    22. [22]

      Marrero-López D, Peña-Martínez J, Ruiz-Morales J C, Pérez-Coll D, Aranda M A G, Núñez P. Synthesis, Phase Stability and Electrical Conductivity of Sr2MgMoO6-δ Anode[J]. Mater. Res. Bull., 2008,43:2441-2450. doi: 10.1016/j.materresbull.2007.07.032

    23. [23]

      Marrero-López D, Peña-Martínez J, Ruiz-Morales J C, Gabás M, Núñez P, Aranda M A G, Ramos-Barrado J R. Redox Behaviour, Chemical Compatibility and Electrochemical Performance of Sr2MgMoO6-δ as SOFC Anode[J]. Solid State Ionics, 2010,180:1672-1682. doi: 10.1016/j.ssi.2009.11.005

    24. [24]

      Jiang L, Liang G, Han J T, Huang Y H. Effects of Sr-Site Deficiency on Structure and Electrochemical Performance in Sr2MgMoO6 for Solid-Oxide Fuel Cell[J]. J. Power Sources, 2014,270:441-448. doi: 10.1016/j.jpowsour.2014.07.079

    25. [25]

      Wei T, Huang Y H, Zhang Q, Yuan L X, Yang J Y, Sun Y M, Hu X L, Zhang W X, Goodenough J B. Thermoelectric Solid-Oxide Fuel Cells with Extra Power Conversion from Waste Heat[J]. Chem. Mater., 2012,24:1401-1403. doi: 10.1021/cm300159w

    26. [26]

      Huang Y H, Liang G, Croft M, Lehtimäki M, Karppinen M, Goodenough J B. Double-Perovskite Anode Materials Sr2MMoO6 (M=Co, Ni) for Solid Oxide Fuel Cells[J]. Chem. Mater., 2009,21:2319-2326. doi: 10.1021/cm8033643

    27. [27]

      Zhu X D, Zhang N D, Wu L J, Sun K N, Yuan Y X. Preparation and Performance of Large-Area La0.9Sr0.1Ga0.8Mg0.2O3-δ Electrolyte for Intermediate Temperature Solid Oxide Fuel Cell[J]. J. Power Sources, 2010,195:7583-7586. doi: 10.1016/j.jpowsour.2010.05.060

    28. [28]

      Li F S, Jiang L, Zeng R, Wang F, Xu Y X, Huang Y H. Hetero-Structured La0.5Sr0.5CoO3-δ/LaSrCoOδ Cathode with High Electrocatalytic Activity for Solid-Oxide Fuel Cells[J]. Int. J. Hydrogen Energy, 2017,42:29463-29471. doi: 10.1016/j.ijhydene.2017.10.001

    29. [29]

      Li F S, Xu Y X, Xia S B, Liu J J, Yan Y X, Cheng F X, Jiang L, Huang Y H. LaSrCoOδ@La0.5Sr0.5CoO3-δ Core-Shell Hybrid as the Cathode Materials for Solid Oxide Fuel Cells[J]. J. Alloy. Compd., 2020,819152996. doi: 10.1016/j.jallcom.2019.152996

    30. [30]

      Bernuy-Lopez C, Allix M, Bridges C A, Claridge J B, Rosseinsky M J. Sr2MgMoO6-δ: Structure, Phase Stability, and Cation Site Order Control of Reduction[J]. Chem. Mater., 2007,19:1035-1043. doi: 10.1021/cm0624116

    31. [31]

      Adler S B. Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes[J]. Chem. Rev., 2004,104:4791-4844. doi: 10.1021/cr020724o

    32. [32]

      Klotz D, Weber A, Ivers-Tiffée E. Practical Guidelines for Reliable Electrochemical Characterization of Solid Oxide Fuel Cells[J]. Electrochim. Acta, 2017,227:110-126. doi: 10.1016/j.electacta.2016.12.148

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