Citation: Bin GUO, Jing YANG, Wen-Xin LU, Peng WANG. Effect of Coordination Environment on Fenton-like Reactivity in Cu(Ⅱ) Metal-Organic Frameworks[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 1981-1992. doi: 10.11862/CJIC.2022.185 shu

Effect of Coordination Environment on Fenton-like Reactivity in Cu(Ⅱ) Metal-Organic Frameworks

College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China

Corresponding author: Wen-Xin LU, lwx08lwx@126.com Peng WANG, pengwang@sdust.edu.cn
Received Date: 5 March 2022
Revised Date: 31 July 2022

Figures(13)

Using copper acetate monohydrate as a copper source, 1D chain coordination polymer {[(Cu(OAc)₂)₂(L)]·3CH₃CN}_n (1, OAc^-=CH₃CO₂^-) was synthesized using 2, 6-bis(4'-pyridyl)-4-methylaniline (L) as bridged pyridine ligand, and 2D network coordination polymer {[Cu(IPA)(L)(H₂O)]₂·H₂IPA·H₂O}_n (2) was prepared by L and isophthalic acid (H₂IPA) as the co-ligand. It can be seen from the single crystal structure analysis that the copper atoms in complex 1 are located in the center of the tetrahedral coordination environment in the [CuNO₄]₂ clusters, and the copper atoms in complex 2 are in the [CuNO₃] deformed hexahedral coordination environment. The comparative experiments on Fenton - like photocatalytic degradation with methylene blue as substrate show that the catalytic effect of complex 1 with Cu—N and Cu—O coordination environment was better than that of HKUST-1 with the same tetrahedral coordination environment. The comparison of the catalytic performance of complexes 1 and 2 also proves that the photocatalytic degradation activity of the open mononuclear copper coordination center was better than that of the copper coordination center in the cluster complex. Benefiting from the stability of the ligands and the existence of the framework structure, both complexes had higher catalytic activity and recyclability compared with the catalytic performance of the unconstrained copper acetate under the same conditions. The band gaps of the two complexes were calculated through UV-Vis spectra. The stability of the complexes after the reaction was confirmed by X-ray diffraction and inductively coupled plasma mass spectrometry. By adding free radical scavengers benzoquinone, tertiary butanol, and triethanolamine, it is confirmed that the catalytic process is a Fenton-like reaction mechanism of the hydroxyl radical process.
- bridged pyridine ligands,
- Cu(Ⅱ) complex,
- Fenton?like photodegradation,
- hydroxyl radical mechanism
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