Citation: Garci Fatma, Klein Axel, Chebbi Hammouda, Faouzi Zid Mohamed. Crystal Structure, Spectroscopic Characterization, and Optical Properties of the Hybrid Compound (C₇H₁₁N₂)₂[CdCl₄]·0.5H₂O[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1834-1842. doi: 10.11862/CJIC.2022.183 shu

Crystal Structure, Spectroscopic Characterization, and Optical Properties of the Hybrid Compound (C₇H₁₁N₂)₂[CdCl₄]·0.5H₂O

1.
University of Tunis El Manar, Faculty of Sciences of Tunis, Laboratory of Materials, Crystal Chemistry and Applied Thermodynamics, Tunis, Tunisia
2.
University of Cologne, Faculty of Mathematics and Natural Sciences, Department of Chemistry, Institute for Inorganic Chemistry, Cologne, Germany
3.
University of Tunis, Preparatory Institute for Engineering Studies of Tunis, Tunis, Tunisia

Corresponding author: Chebbi Hammouda, chebhamouda@yahoo.fr
Received Date: 14 February 2022
Revised Date: 31 May 2022

Figures(10)

A preparation procedure for the title compound (C₇H₁₁N₂)₂[CdCl₄]·0.5H₂O (C₇H₁₁N₂=4-(dimethylamino) pyridinium) was developed and gave good yields and purity. The Cd(Ⅱ) ion is coordinated in a slightly distorted tetrahedral environment by four chlorides. The crystal arrangement shows a layered structure with alternating organic and inorganic layers parallel to the (001) plane and located at x=n+1/2 (n ∈ Z). In the crystal, the organic and inorganic layers are linked by C—H…Cl, C—H…O, N—H…Cl and N —H…O hydrogen bonding interactions. Hirshfeld surface analysis and fingerprint plots of the structure reveal that molecular packing is governed by hydrogen bonds and π-stacking. The UV-Vis diffuse reflectance spectrum allowed us to determine a direct band gap of 3.596 eV with a semiconducting character, using the Tauc-extrapolation method. The observed photoluminescence band with a maximum at 562 nm is assigned to excited π-π* states in the 4-(dimethylamino)pyridinium cation.
- chlorocadmate(Ⅱ),
- 4-(dimethylamino)pyridinium,
- crystal structure,
- Hirshfeld surface analysis,
- photoluminescence
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Crystal Structure, Spectroscopic Characterization, and Optical Properties of the Hybrid Compound (C7H11N2)2[CdCl4]·0.5H2O

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Crystal Structure, Spectroscopic Characterization, and Optical Properties of the Hybrid Compound (C₇H₁₁N₂)₂[CdCl₄]·0.5H₂O