Citation: Xiang-Wen WANG. Layered Hexagonal Co_1-xS Decorating N-Doped Carbon Nanotubes as a Sulfur Host for Li-S Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 2065-2071. doi: 10.11862/CJIC.2022.180 shu

Layered Hexagonal Co_1-xS Decorating N-Doped Carbon Nanotubes as a Sulfur Host for Li-S Batteries

Xiang-Wen WANG

Department of Food Engineering, Dezhou Vocational and Technical College, Dezhou, Shandong 253034, China

Author Bio: E-mail: wxw_wyy@sina.com
Received Date: 25 February 2022
Revised Date: 10 July 2022

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The design and assembly of nanostructured materials are devoted to improving the electrochemical properties of the Li-S batteries (LSBs) by synergistic effect. In this work, a composite of hexagonal Co_1-xS nanosheets decorating N-doped carbon nanotube (Co_1-xS-CNT) was successfully synthesized and used as a sulfur host for Li-S batteries (LSBs). In Co_1-xS-CNT/S, the polar hexagonal Co_1-xS nanosheets can absorb the lithium polysulfide through chemisorption, at the same time, the CNT can provide a highly conductive network. Based on the synergy of physical encapsulating and chemical trapping, the Co_1-xS-CNT/S cathode exhibited excellent electrochemical performance, especially the superior cycle performance. After 170 cycles, the Co_1-xS-CNT/S can maintain a discharge capacity of 405.6 mAh·g^-1 at 0.5C, with a stable Coulombic efficiency (over 99.2%).
- Li-S batteries,
- hexagonal Co_1-xS nanosheets,
- cathode,
- carbon nanotube,
- chemisorption
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沈阳化工大学材料科学与工程学院沈阳 110142

Layered Hexagonal Co1-xS Decorating N-Doped Carbon Nanotubes as a Sulfur Host for Li-S Batteries

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通讯作者: 陈斌, bchen63@163.com

Layered Hexagonal Co_1-xS Decorating N-Doped Carbon Nanotubes as a Sulfur Host for Li-S Batteries