Citation: Wen-Hui HE, Xing YE, Zi-Yu WANG, Zhen-Hong WEI, Wen-Jun RAO, Hu CAI. Chemical Modification of Cyclen to Raise the Phase Transition Temperature of Its Perrhenic Compounds[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1586-1592. doi: 10.11862/CJIC.2022.162 shu

Chemical Modification of Cyclen to Raise the Phase Transition Temperature of Its Perrhenic Compounds

School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, China

Corresponding author: Zhen-Hong WEI, weizh@ncu.edu.cn Hu CAI, caihu@ncu.edu.cn
Received Date: 21 March 2022
Revised Date: 7 May 2022

Figures(4)

A methyl-substituted 1, 4, 7, 10-tetraazacyclododecane (N-methyl-1, 4, 7, 10-tetraazacyclododecane, Me-cyclen) was isolated by chemical modification of 1, 4, 7, 10-tetraazacyclododecane (cyclen) with iodomethane. Reactions of cyclen and Me-cyclen with two equivalents of HReO₄ led to phase transition molecules (cyclen)(ReO₄)₂ (1) and (Me -cyclen)(ReO ₄)₂ (2), respectively. Differential scanning calorimetry and dielectric studies revealed that compounds 1 and 2 show reversible phase transition with temperatures at 324 K for 1 and 384 K for 2. The research results demonstrate a way that the high-temperature phase transition organic-inorganic hybrid materials can be obtained by reducing molecular symmetry through chemical modification of organic amines.
- cyclic organic amine,
- perrhenic acid,
- phase transition,
- dielectric,
- chemical modification
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