Citation: Sheng WANG, Rui-Qin HUANG, Shao-Cong WANG, Zheng LIU, Qun TANG. Synthesis, Structure, and Properties of Rare-Earth Complexes Based on Pyridine Dicarboxylic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1663-1671. doi: 10.11862/CJIC.2022.157 shu

Synthesis, Structure, and Properties of Rare-Earth Complexes Based on Pyridine Dicarboxylic Acid Ligands

Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, College of Chemical and Biological Engineering, Guilin University of Technology, Guilin, Guangxi 541004, China

Corresponding author: Zheng LIU, lisa4.6@163.com Qun TANG, tangq@glut.edu.cn
Received Date: 5 May 2022
Revised Date: 10 June 2022

Figures(7)

The 2, 6-lutidine- 3, 5-dicarboxylic acid (H₂L₁) was used as the main ligand, 1, 10-phenanthroline (L₂) as the auxiliary ligand, and the complexes [Dy₂(L₁)₃ (L₂)₂]_n (1), {[Tb₂(L₁)₃ (L₂)₂]·5H₂O}_n (2), and {[Eu₂(L₁)₃(L₂)₂]·5H₂O}_n (3) were synthesized by solvothermal reaction with dysprosium nitrate pentahydrate, terbium nitrate hexahydrate, and europium nitrate hexahydrate, respectively. The structures and properties of the complexes were characterized by single - crystal X - ray diffraction, IR, fluorescence spectroscopy, and thermogravimetric analysis. The results show that complexes 1-3 all use rare-earth ions as metal nodes to connect with ligands L₁^2- and L₂ to form an infinitely extending 1D chain structure.
- rare-earth complex,
- dipicolinate,
- 1, 10-phenanthroline,
- crystal structure
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