Citation: Sheng WANG, Rui-Qin HUANG, Shao-Cong WANG, Zheng LIU, Qun TANG. Synthesis, Structure, and Properties of Rare-Earth Complexes Based on Pyridine Dicarboxylic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1663-1671. doi: 10.11862/CJIC.2022.157 shu

Synthesis, Structure, and Properties of Rare-Earth Complexes Based on Pyridine Dicarboxylic Acid Ligands

Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, College of Chemical and Biological Engineering, Guilin University of Technology, Guilin, Guangxi 541004, China

Corresponding author: Zheng LIU, lisa4.6@163.com Qun TANG, tangq@glut.edu.cn
Received Date: 5 May 2022
Revised Date: 10 June 2022

Figures(7)

The 2, 6-lutidine- 3, 5-dicarboxylic acid (H₂L₁) was used as the main ligand, 1, 10-phenanthroline (L₂) as the auxiliary ligand, and the complexes [Dy₂(L₁)₃ (L₂)₂]_n (1), {[Tb₂(L₁)₃ (L₂)₂]·5H₂O}_n (2), and {[Eu₂(L₁)₃(L₂)₂]·5H₂O}_n (3) were synthesized by solvothermal reaction with dysprosium nitrate pentahydrate, terbium nitrate hexahydrate, and europium nitrate hexahydrate, respectively. The structures and properties of the complexes were characterized by single - crystal X - ray diffraction, IR, fluorescence spectroscopy, and thermogravimetric analysis. The results show that complexes 1-3 all use rare-earth ions as metal nodes to connect with ligands L₁^2- and L₂ to form an infinitely extending 1D chain structure.
- rare-earth complex,
- dipicolinate,
- 1, 10-phenanthroline,
- crystal structure
1. [1]
  Lin S C A, Liu Y H, Peng S M, Liu S T. Hetero-Bimetallic Complexes Based on an Anthyridine Ligand Preparation and Catalytic Activity[J]. Organometallics, 2020,39(1):123-131. doi: 10.1021/acs.organomet.9b00682
2. [2]
  Hirahara M, Goto H, Yagi M, Umemura Y. A Multi-Stimuli Respon-sive Ruthenium Complex for Catalytic Water Oxidation[J]. Chem. Commun., 2020,56(84):12825-12828. doi: 10.1039/D0CC04940A
3. [3]
  Grover P, Ferch L S, Schreckenbach G. Adsorption of Actinide (U-Pu) Complexes on the Silicene and Germanene Surface: A Theoretical Study[J]. J. Phys. Chem. A, 2020,124(8):1522-1534. doi: 10.1021/acs.jpca.9b10888
4. [4]
  Devi L, Madarasi P K, Jeyakumar T C. Computational Studies of Adsorption of Dinitrogen over the Group 8 Metal-Borazine Complexes[J]. Chem. Pap., 2022,76(3):1539-1552. doi: 10.1007/s11696-021-01953-9
5. [5]
  Cai M R, Qin L Y, Pang L N, Ma B R, Bai J, Liu J L, Dong X X, Yin X B, Ni J. Amino -Functionalized Zn Metal Organic Frameworks as Antitumor Drug Curcumin Carriers[J]. New J. Chem., 2020,44(41):17693-17704. doi: 10.1039/D0NJ03680C
6. [6]
  Feng A L, Wang Y N, Ding J Z, Xu R, Li X D. Progress of Stimuli-Responsive Nanoscale Metal Organic Frameworks as Controlled Drug Delivery Systems[J]. Curr. Drug Deliv., 2021,18(3):297-311. doi: 10.2174/1567201817666200917120201
7. [7]
  Qu S M, Cao Q, Ma J T, Jia Q. A Turn-On Fluorescence Sensor for Creatinine Based on the Quinoline -Modified Metal Organic Frame-works[J]. Talanta, 2020,219121280. doi: 10.1016/j.talanta.2020.121280
8. [8]
  Olorunyomi J F, Sadiq M M, Batten M, Konstas K, Chen D H, Doherty C M, Caruso R A. Advancing Metal -Organic Frameworks toward Smart Sensing: Enhanced Fluorescence by a Photonic Metal-Organic Framework for Organic Vapor Sensing[J]. Adv. Opt. Mater., 2020,8(19)2000961. doi: 10.1002/adom.202000961
9. [9]
  Xian G X, Chen Y Q, Wang Y H, Wan X Y, Li Y W, Wang H W, Lu J, Dou J M, Li D C, Wang S N. Multifunctional Sensing Activities toward Heavy Metals of Three Luminescent Complexes: Effect of N-Donor Coligands and Sensing Medium[J]. Dyes Pigment., 2021,190109291. doi: 10.1016/j.dyepig.2021.109291
10. [10]
  Cheng W J, Xie Y T, Yang Z Y, Sun Y Q, Zhang M Z, Ding Y B, Zhang W H. General Strategy for In Situ Generation of a Coumarin-Cu²⁺ Complex for Fluorescent Water Sensing[J]. Anal. Chem., 2019,9(19):5817-5823.
11. [11]
  Wei W C, Liu Z, Wei R Z, Liang C X, Feng X Z, Han G C. Synthe-sis, Crystal Structure and Anticorrosion Performance of Zn (II) and Ni(II) Complexes[J]. J. Mol. Struct., 2021,1228129452. doi: 10.1016/j.molstruc.2020.129452
12. [12]
  Wei W C, Liu Z, Liang C X, Han G C, Li Y K, Li Q W, Han J X, Zhang S F. Corrosion Inhibition Performance of Nitrogen-Containing Metal Organic Framework Compounds on Copper Flakes in Dilute HCl Medium[J]. Prot. Met. Phys. Chem. Surf., 2020,56(3):638-650. doi: 10.1134/S2070205120030302
13. [13]
  Wang G, Yang G, Jiang M, Wang R, Liang Y, Zhou G. Poly(propyl-ene naphthalate-co-propylene 2, 5-thiophenedicarboxylate)s Derived from Bio-based 2, 5-Thiophenedicarboxylic Acid (TDCA): Synthesis and Properties[J]. Polym. Test., 2020,93106955.
14. [14]
  Feng X, Li R F, Ng S W, Qin G Z, Ma L F. A Series of Homonuclear Lanthanide Coordination Polymers Based on a Fluorescent Conjugat-ed Ligand: Syntheses, Luminescence and Sensor for Pollutant Chro-mate Anion[J]. CrystEngComm, 2015,17:7878-7887.
15. [15]
  Hamidi Z, Mosavian S Y, Sabbaghi N, Zarchi M A K, Noroozifar M. Cross-Linked Poly(N-alkyl-4-vinylpyridinium) Iodides as New Eco-Friendly Inhibitors for Corrosion Study of St-37 Steel in 1 M H₂SO₄[J]. Iran. Polym. J., 2020,29(3):225-239. doi: 10.1007/s13726-020-00787-8
16. [16]
  Abdolmaleki S, Ghadermazi M, Ashengroph M, Saffari A, Sabzkohi S M. Cobalt(II), Zirconium(IV), Calcium(II) Complexes with Dipicolinic Acid and Imidazole Derivatives: X -ray Studies, Thermal Analyses, Evaluation as In Vitro Antibacterial and Cytotoxic Agents[J]. Inorg. Chim. Acta, 2018,480:70-82. doi: 10.1016/j.ica.2018.04.047
17. [17]
  Zhao J H, Wang S, Lu S S, Sun J, Yang X R. A Luminescent Europium-Dipicolinic Acid Nanohybrid for the Rapid and Selective Sensing of Pyrophosphate and Alkaline Phosphatase Activity[J]. Nanoscale, 2018,10:7163-7170. doi: 10.1039/C8NR00223A
18. [18]
  Răducă M, Ene C D, Ionescu S, Florea M, Mădălan A M. Coordina-tion Polymers and a Dinuclear Complex Constructed from Zinc (II) Ions and Fluorescein: Iodine Adsorption and Optical Properties[J]. J. Coord. Chem., 2019,72(8):1222-1237. doi: 10.1080/00958972.2019.1605442
19. [19]
  Zhu Y L, Zhou S Y, Kan Y H, Su Z M. Theoretical Investigation of Electronic Structures and Excitation Energies of Hexaphyrin and Its Group 11 Transition Metal (III) Complexes[J]. J. Organomet. Chem., 2009,694(18):3012-3018.
20. [20]
  LI H D, ZHAI L J, SONG Y B, NIU Y L. Two Nitronyl Nitroxide Biradical -Bridged Lanthanide One -Dimensional Chains: Crystal Structure, Magnetic Properties and Luminescent Behavior[J]. Chinese J. Inorg. Chem., 2021,37(5):914-920.
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