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Citation: Song QIU, Wen-Ning YAN, Li WANG, Lian-Shan ZHANG, Chao CHEN, Li-Juan MU, Shi-Gang MU. Facile Synthesis of Si@LiAlO2 Nanocomposites as Anode for Lithium-Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1655-1662. doi: 10.11862/CJIC.2022.154 shu

Facile Synthesis of Si@LiAlO2 Nanocomposites as Anode for Lithium-Ion Battery

  • 1.

    School of Energy and Machinery, Dezhou University, Dezhou, Shandong 253023, China

  • 2.

    Experiment Management Centre, Dezhou University, Dezhou, Shandong 253023, China

  • Corresponding author: Song QIU, qiusong0307@163.com
  • Received Date: 20 March 2022
    Revised Date: 28 May 2022

Figures(6)

  • The nanocomposites of LiAlO2 coated Si nanoparticles (Si@LiAlO2) have been successfully synthesized by the solvothermal method and heat treatment. Si@LiAlO2 formed a dendritic structure with openings and channels between the dendrites. As anode material for lithiumion batteries, electrochemical results showed that as-prepared Si@LiAlO2 nanocomposite achieved a reversible capacity of 364.1 mAh·g-1 after 100 cycles at a current density of 100 mA·g-1. The superior cycling performance is attributed to the nanocomposite dendritic structure, in which nanosized Si particles shorten the diffusion path of lithium ions and the LiAlO2 coating, the voids, and openings between the dendrites help buffer volume changes during charging and discharging.
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