Citation: Qi ZHOU, You‐Cheng LUO. Three Dimensional Ni(OH)₂/Ni@N-Doped Reduced Graphene Oxide Composite Electrodes as an Electrocatalyst for Hydrogen Evolution Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1541-1548. doi: 10.11862/CJIC.2022.148 shu

Three Dimensional Ni(OH)₂/Ni@N-Doped Reduced Graphene Oxide Composite Electrodes as an Electrocatalyst for Hydrogen Evolution Reaction

Qi ZHOU ^{1, 2,,} ,
You‐Cheng LUO ²

1.
State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
2.
School of Materials and Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: Qi ZHOU, zhouxq301@sina.com
Received Date: 9 March 2022
Revised Date: 23 May 2022

Figures(8)

In this work, 3D flower - like Ni(OH)₂/Ni@NG composite electrodes were prepared by combining 3D Ni(OH)₂/Ni with nitrogen-doped reduced graphene oxide(rGO)using de-alloying and two-step hydrothermal synthesis.Characterization of the phase, valence distribution, and microstructure of electrodes by X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS), scanning electron microscopy(SEM), and transmission electron microscopy(TEM).In addition, the electrocatalytic hydrogen evolution reaction(HER)performance was tested in 1 mol·L^-1 KOH solution.The results showed that the three-dimensional structure of Ni(OH)₂/Ni increased the active area of the electrode, and the complexation with N-doped rGO significantly improved the electron/ion transport rate with an overpotential of 108 mV(η₁₀)and a Tafel slope of 114.9 mV·dec^-1, which exhibited good HER catalytic activity.The Ni(OH)₂/Ni@NG electrode showed good stability by both the 1 000-turn cyclic voltammetry method and the chronopotentiometry test.
- de-alloying,
- two-step hydrothermal synthesis,
- electrocatalytic hydrogen evolution
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Three Dimensional Ni(OH)2/Ni@N-Doped Reduced Graphene Oxide Composite Electrodes as an Electrocatalyst for Hydrogen Evolution Reaction

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通讯作者: 陈斌, bchen63@163.com

Three Dimensional Ni(OH)₂/Ni@N-Doped Reduced Graphene Oxide Composite Electrodes as an Electrocatalyst for Hydrogen Evolution Reaction