Citation: Da-Ze NING, Hong-Guang SUN. Performance of the Inward Radial Hollow TiN Particles as Cathodes for Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(7): 1375-1381. doi: 10.11862/CJIC.2022.143 shu

Performance of the Inward Radial Hollow TiN Particles as Cathodes for Lithium-Sulfur Batteries

Da-Ze NING ,
Hong-Guang SUN ^,

School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266044, China

Corresponding author: Hong-Guang SUN, hgsun816@qust.edu.cn
Received Date: 18 March 2022
Revised Date: 17 May 2022

Figures(5)

The inward radially hollow structure TiN particles (IRHTiNs) was designed and synthesized by using the hard-template method and combined with sulfur (S) to prepare lithium-sulfur batteries (LSB) cathodes. Subsequently, the structure and composition of IRHTiNs and IRHTiNs/S composite cathodes were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). In the electrochemical test process, compared with the C cathodes, LSB using the IRHTiNs cathodes exhibited a high original specific capacity of 1 256 mAh·g^-1, the capacity fading rate was significantly reduced, and the LSB performance was significantly improved.
- lithium-sulfur battery,
- titanium nitride,
- nanoparticles,
- shuttle effect
1. [1]
  Shi H D, Ren X M, Lu J M, Dong C, Liu J, Yang Q H, Chen J, Wu Z S. Dual-Functional Atomic Zinc Decorated Hollow Carbon Nanoreactors for Kinetically Accelerated Polysulfides Conversion and Dendrite Free Lithium Sulfur Batteries[J]. Energy Storage Mater., 2020,10(39)2002271.
2. [2]
  Wang W P, Zhang J, Chou J, Yin Y X, You Y, Xin S, Guo Y G. Solidifying Cathode-Electrolyte Interface for Lithium-Sulfur Batteries[J]. Energy Storage Mater., 2021,11(2)2000791.
3. [3]
  Ding B, Wang J, Fan Z J, Chen S, Lin Q Y, Lu X J, Dou H, Nanjundan A K, Yushin G, Zhang X G, Yamauchi Y. Solid-State Lithium-Sulfur Batteries: Advances, Challenges and Perspectives[J]. Mater. Today, 2020,40:114-131. doi: 10.1016/j.mattod.2020.05.020
4. [4]
  Lim J, Pyun J, Char K. Recent Approaches for the Direct Use of Elemental Sulfur in the Synthesis and Processing of Advanced Materials[J]. Angew. Chem. Int. Ed., 2015,54(11):3249-3258. doi: 10.1002/anie.201409468
5. [5]
  Son Y, Lee J S, Son Y, Jang J H, Cho J. Recent Advances in Lithium Sulfide Cathode Materials and Their Use in Lithium Sulfur Batteries[J]. Adv. Energy Mater., 2015,5(16)1500110. doi: 10.1002/aenm.201500110
6. [6]
  Zhou L, Danilov D L, Eichel R A, Notten P H L. Host Materials Anchoring Polysulfides in Li-S Batteries Reviewed[J]. Adv. Energy Mater., 2020,11(15)2001304.
7. [7]
  Zheng M B, Chi Y, Hu Q, Tang H, Jiang X L, Zhang L, Zhang S T, Pang H, Xu Q. Carbon Nanotube-Based Materials for Lithium-Sulfur Batteries[J]. J. Mater. Chem. A, 2019,7(29):17204-17241. doi: 10.1039/C9TA05347F
8. [8]
  Zeng W D, Cheng M M C, Ng K Y S. Cathode Framework of Nanostructured Titanium Nitride/Graphene for Advanced Lithium-Sulfur Batteries[J]. ChemElectroChem, 2019,6(10):2796-2804. doi: 10.1002/celc.201900364
9. [9]
  Li H T, Li Y G, Zhang L. Designing Principles of Advanced Sulfur Cathodes toward Practical Lithium-Sulfur Batteries[J]. SusMat, 2022,2(1):34-64. doi: 10.1002/sus2.42
10. [10]
  Cui Z Q, Yao J, Mei T, Zhou S Y, Hou B F, Li J, Li J H, Wang J Y, Qian J W, Wang X B. Strong Lithium Polysulfides Chemical Trapping of TiC-TiO₂/S Composite for Long-Cycle Lithium-Sulfur Batteries[J]. Electrochim. Acta, 2019,298(1):43-51.
11. [11]
  Yang J H, Yang X F, Cheong J L, Zaghib K, Trudeau M L, Ying J Y. Nanoboxes with a Porous MnO Core and Amorphous TiO₂ Shell as a Mediator for Lithium-Sulfur Batteries[J]. J. Mater. Chem. A, 2021,9(8):4952-4961. doi: 10.1039/D0TA09700D
12. [12]
  Gao B, Li X X, Ding K, Huang C, Li Q W, Chu P K, Huo K. Recent Progress in Nanostructured Transition Metal Nitrides for Advanced Electrochemical Energy Storage[J]. J. Mater. Chem. A, 2019,7(1):14-37. doi: 10.1039/C8TA05760E
13. [13]
  Lim W G, Jo C S, Cho A, Hwang J, Kim S, Han J W, Lee J. Approaching Ultrastable High-Rate Li-S Batteries through Hierarchically Porous Titanium Nitride Synthesized by Multiscale Phase Separation[J]. Adv. Mater., 2019,31(3)1806547. doi: 10.1002/adma.201806547
14. [14]
  Wang Y K, Zhang R F, Pang Y C, Chen X, Lang J X, Xu J J, Xiao C H, Li H L, Xi K, Ding S J. Carbon@Titanium Nitride Dual Shell Nanospheres as Multi-functional Hosts for Lithium Sulfur Batteries[J]. Energy Storage Mater., 2019,16:228-235. doi: 10.1016/j.ensm.2018.05.019
15. [15]
  Li H X, Ma S, Li J W, Liu F Y, Zhou H H, Huang Z Y, Jiao S Q, Kuang Y. Altering the Reaction Mechanism to Eliminate the Shuttle Effect in Lithium-Sulfur Batteries[J]. Energy Storage Mater., 2020,26:203-212. doi: 10.1016/j.ensm.2020.01.002
16. [16]
  Polshettiwar V, Cha D, Zhang X, Basset J M. High-Surface-Area Silica Nanospheres (KCC-1) with a Fibrous Morphology[J]. Angew. Chem. Int. Ed., 2010,122(50):9846-9850. doi: 10.1002/ange.201003451
17. [17]
  Liang X, Garsuch A, Nazar L F. Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries[J]. Angew. Chem. Int. Ed., 2015,127(13):3979-3983. doi: 10.1002/ange.201410174
18. [18]
  Zhou S Y, Hu J Y, Liu S G, Lin J X, Cheng J, Mei T, Wang X B, Liao H G, Huang L, Sun S G. Biomimetic Micro Cell Cathode for High Performance Lithium-Sulfur Batteries[J]. Nano Energy, 2020,72104680. doi: 10.1016/j.nanoen.2020.104680
19. [19]
  Wu Q P, Yao Z G, Zhou X J, Xu J, Cao F H, Li C L. Built-In Catalysis in Confined Nanoreactors for High-Loading Li-S Batteries[J]. ACS Nano, 2020,14(3):3365-3377. doi: 10.1021/acsnano.9b09231
20. [20]
  Jin Z S, Lin T N, Jia H F, Liu B Q, Zhang Q, Li L, Zhang L Y, Su Z M, Wang C G. Expediting the Conversion of Li₂S₂ to Li₂S Enables High-Performance Li-S Batteries[J]. ACS Nano, 2021,15(4):7318-7327. doi: 10.1021/acsnano.1c00556
21. [21]
  Cai D, Liu B K, Zhu D H, Chen D, Lu M J, Cao J M, Wang Y H, Huang W H, Shao Y, Tu H, Han W. Ultrafine Co₃Se₄ Nanoparticles in Nitrogen-Doped 3D Carbon Matrix for High-Stable and Long-Cycle-Life Lithium Sulfur Batteries[J]. Adv. Energy Mater., 2020,10(19)1904273. doi: 10.1002/aenm.201904273
22. [22]
  Yang X F, Gao X J, Sun Q, Jand S P, Yu Y, Zhao Y, Li X, Adair K, Kuo L Y, Rohrer J, Liang J N, Lin X T, Banis M N, Hu Y F, Zhang H Z, Li X F, Li R Y, Zhang H M, Kaghazchi P, Sham T K, Sun X L. Promoting the Transformation of Li₂S₂ to Li₂S: Significantly Increasing Utilization of Active Materials for High-Sulfur-Loading Li-S Batteries[J]. Adv. Mater., 2019,31(25)1901220. doi: 10.1002/adma.201901220
1. [1]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
2. [2]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
3. [3]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
4. [4]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
5. [5]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
6. [6]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
7. [7]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
8. [8]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
9. [9]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
10. [10]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
11. [11]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
12. [12]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
13. [13]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
14. [14]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
15. [15]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
16. [16]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
17. [17]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
18. [18]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
19. [19]
  Hongyao Li , Youyan Liu , Luwei Dai , Min Yang , Qihui Wang . The Blessing of Indium Sulfide：Confronting the Narrow Path with Uric Acid. University Chemistry, 2024, 39(5): 325-335. doi: 10.3866/PKU.DXHX202311104
20. [20]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(781)
HTML views(139)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142