Citation: Xiao-Juan CHEN, Hong-Ren RONG, Li-Li YU, Mei-Ling CHENG, Guang-Chi SUN, Qi LIU. A Cadmium-Based Coordination Polymer Including No Solvent as an Anode Material for Li-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(7): 1367-1374. doi: 10.11862/CJIC.2022.140 shu

A Cadmium-Based Coordination Polymer Including No Solvent as an Anode Material for Li-Ion Batteries

School of Petrochemical Engineering, Jiangsu Provincial Key Laboratory of Fine Petrochemicals, Changzhou University, Changzhou, Jiangsu 213164, China

Corresponding author: Qi LIU, liuqi62@163.com
Received Date: 18 February 2022
Revised Date: 6 April 2022

Figures(4)

For developing lithium-ion batteries (LIBs) with higher energy density, coordination polymers (CPs), as the electrode materials for LIBs, have attracted considerable attention from researchers. Herein, [Cd(tfbdc) (Im)₄] (Cd-TBI), a one-dimensional (1D) CP, was synthesized by the reaction of CdCl₂, imidazole (Im), and tetrafluoroterephthalic acid (H₂tfbdc), and characterized by single-crystal X-ray diffraction, IR spectrum, and thermogravimetric analysis. In Cd-TBI, tfbdc^2- anions bridged Cd(Ⅱ) ions to form a 1D chain structure. These 1D chains are linked to each other by the hydrogen bonds to produce a 3D supramolecular framework. The electrochemical performances of Cd-TBI as an anode material of LIBs were investigated for the first time. Cd-TBI electrode delivered the discharge capacity of 150 mAh·g^-1 at 50 mA·g^-1 after 50 cycles, along with the capacity retention of 95.7% and Coulombic efficiency of 99.2%, indicating it has excellent cycling stability. Even at 1 A·g^-1, the Cd-TBI electrode also kept the discharge capacity of 97 mAh·g^-1.
- cadmium,
- coordination polymer,
- lithium-ion battery,
- anode material,
- imidazole,
- tetrafluoroterephthalic acid
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