Citation: Shao-Kuan ZHU, Ya SONG, Xiang LONG, Quan-Sheng OUYANG, Jiao-Jing SHAO, Bin SHI. La-Doped BaSnO₃/Multi-walled Carbon Nanotube Modified Separator: Synthesis and Application in Lithium-Sulfur Battery[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(7): 1433-1440. doi: 10.11862/CJIC.2022.138 shu

La-Doped BaSnO₃/Multi-walled Carbon Nanotube Modified Separator: Synthesis and Application in Lithium-Sulfur Battery

1.
School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
2.
Advanced Batteries and Materials Engineering Research Center, Guizhou Light Industry Technical College, Guiyang 550025, China
3.
State Key Laboratory of Advanced Chemical Power Sources, Zunyi, Guizhou 563003, China

Corresponding author: Jiao-Jing SHAO, shaojiao_jing@163.com Bin SHI, xjshao@gzu.edu.cn
Received Date: 1 February 2022
Revised Date: 29 April 2022

Figures(5)

Herein, an interlayer was constructed on the commercial separator Celgard 2500 (PP) by doctor blade coating a mixture slurry of perovskite oxide lanthanum doped barium stannate (LBSO) that was prepared by coprecipitation method and multi-walled carbon nanotubes (MCNT). The as-obtained modified separator was named LBSO/MCNT/PP. The lithium-sulfur battery using the modified separator delivered an initial discharge specific capacity up to 1 433 mAh·g^-1 at 0.1C and a capacity decay rate of 0.114% per cycle over 300 cycles at 1C. As the current density was increased to a 3C rate, a discharge specific capacity of 764 mAh·g^-1 can still be maintained, showing excellent rate capability and cycling stability, which is ascribed to the effective inhibition of the interlayer towards the shuttle of polysulfides.
- lithium batteries,
- high energy storage,
- lanthanum doped barium stannate,
- shuttle effect,
- interlayer
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

La-Doped BaSnO3/Multi-walled Carbon Nanotube Modified Separator: Synthesis and Application in Lithium-Sulfur Battery

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通讯作者: 陈斌, bchen63@163.com

La-Doped BaSnO₃/Multi-walled Carbon Nanotube Modified Separator: Synthesis and Application in Lithium-Sulfur Battery