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Citation: Zhong-Yan LI, Hai-Bo QIN, Hong-Yu ZHU, Xu FAN, Lin YUAN. Three Salicylaldehyde Schiff Base Fluorescent Probes: Synthesis and Recognition of Zn2+[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(7): 1291-1298. doi: 10.11862/CJIC.2022.137 shu

Three Salicylaldehyde Schiff Base Fluorescent Probes: Synthesis and Recognition of Zn2+

  • School of Chemical and Biological Engineering, Hunan University of Science and Engineering, Yongzhou, Hunan 425199, China

  • Corresponding author: Lin YUAN, tcyl431102@163.com
  • Received Date: 12 December 2021
    Revised Date: 24 April 2022

Figures(11)

  • Three novel Schiff-base fluorescent probes, 2-((2-hydroxybenzylidene)amino)-2-(hydroxymethyl)propane- 1, 3-diol (L1), 2-((5-chloro-2-hydro-xybenzylidene)amino)-2-(hydroxymethyl)-propane-1, 3-diol (L2), and 2-((2-hydroxy-4-methoxy-benzylidene)amino)-2-(hydroxymethyl)propane-1, 3-diol (L3), were designed and synthesized, and characterized by 1H NMR, 13C NMR, elemental analysis, and HRMS. The results of the spectral analysis showed that probe L2 was more selective and sensitive to Zn2+ than probes L1 and L3. The detection limit of L2 was found to be 11.96 nmol·L-1, which was far lower than the limit value of Zn2+ in drinking water, 1.0 mg·L-1 (about 15 μmol· L-1), stipulated in the national standard GB5749-2006. There was a good linear relationship between the fluorescence intensity of probe L2 and the concentration of Zn2+ in a range of 0 to 10 μmol·L-1. Meanwhile, the singlecrystal structure of complex[Zn(C11H13ClNO4)2] (L2-Zn2+) and the Job's plot revealed a 2:1 L2-Zn2+ identification. Moreover, probe L2 could detect Zn2+ in actual water samples.
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