Citation: Ming-Feng SHI, Jiang-Hong GU, Yi WAN, Zhong-Xuan XU. Three Zn(Ⅱ)-MOFs Based on Imidazole Derivatives and 2, 5-Dimethoxyterephthalic Acid: Syntheses, Crystal Structures, and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(6): 1180-1188. doi: 10.11862/CJIC.2022.121 shu

Three Zn(Ⅱ)-MOFs Based on Imidazole Derivatives and 2, 5-Dimethoxyterephthalic Acid: Syntheses, Crystal Structures, and Fluorescence Properties

Ming-Feng SHI ^{1, 2} ,
Jiang-Hong GU ¹ ,
Yi WAN ¹ ,
Zhong-Xuan XU ^1,,

1.
School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China
2.
School of Chemistry and Environment, Yunnan Minzu University, Kunming 650504, China

Corresponding author: Zhong-Xuan XU, xuzhongxuan4201@163.com
Received Date: 19 December 2021
Revised Date: 29 March 2022

Figures(6)

In the presence of 2, 5-dimethoxyterephthalic acid (H₂DTA), three 3D metal-organic frameworks, namely {[Zn(DTA)(1, 2, 4, 5-TIB)_0.5]·1.5H₂O}_n (1), [Zn(DTA)(1, 4-BMIB)_0.5(H₂O)]_n (2), and {[Zn(DTA)(1, 4-BMIN)]·H₂O}_n (3), have been synthesized by using imidazole derivatives 1, 2, 4, 5-tetra(1H-imidazol-1-yl)benzene (1, 2, 4, 5-TIB), 1, 4-bis(4-methyl-1H-imidazol-1-yl)benzene (1, 4-BMIB), and 1, 4-bis(4-methyl-1H-imidazol-1-yl)naphthalene (1, 4-BMIN) as ligands to react to zinc ions, respectively. Their structures and fluorescent properties were studied. Single crystal X-ray diffraction analysis reveals that all complexes belong to the monoclinic crystal system. Among them, complex 1 based on four-coordinated 1, 2, 4, 5-TIB is a four-connected framework with a point symbol of (6².8⁴). Compared with complex 1, slim 1, 4-BMIB and 1, 4-BMIN ligands with low coordination numbers caused that complexes 2 and 3 are 2-fold interpenetration pcu-type and 3-fold interpenetration dia-type networks, respectively. Furthermore, the fluorescent properties of complexes 1-3 were also studied, and their emission spectra had a significant enhancement and blue shift compared to the emission peak of the ligands.
- metal-organic framework,
- imidzaole derivationves ligands,
- 2, 5-dimethoxyterephthalic acid,
- interpenetration network,
- fluorescent property
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