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Citation: Yue-Jiao JIA, Xiao-Yu LIANG, Ming HU. A Water Stable Luminescent Zn-Complex Sensor for Detection of PO43- Ion, Fe3+ Ion, and Nitroaromatic Explosives[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(6): 1146-1158. doi: 10.11862/CJIC.2022.108 shu

A Water Stable Luminescent Zn-Complex Sensor for Detection of PO43- Ion, Fe3+ Ion, and Nitroaromatic Explosives

  • School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China

  • Corresponding author: Ming HU, hm988@126.com
  • Received Date: 11 December 2021
    Revised Date: 31 March 2022

Figures(7)

  • A luminescent Zn-complex based on the 3-(2, 4-dicarboxylphenyl)-6-carboxylpyridine (H3dpcp), namely [Zn(H2dpcp)2(H2O)2]·H2O (1), was successfully fabricated by the solvothermal process. Complex 1 features a mono-nuclear butterfly-like structure, which further extends to the 3D supramolecular architecture via π…π interactions. It is found that complex 1 exhibited excellent luminescent stability in a pH range of 1-10 in an aqueous solution. It should be noted that complex 1 can not only detect PO43- ion based on the turn-on effect with high selectivity and recyclability but also serve as a remarkably selective sensing material with the fluorescence quenching for Fe3+ ion. The examination of nitroaromatic compounds demonstrated that complex 1 also behaved as a functional probe with high selectivity, sensitivity, and the low detection limit of 2, 4, 6-trinitrophenol (TNP). Furthermore, the luminescent sensing mechanisms for the above analytes were also investigated in detail. CCDC: 2010615.
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