Citation: Bo YANG, Gong-Xuan LÜ, Xu-Qiang ZHANG, Jian-Tai MA. Nickel Phosphide Corrosion Induced by Water and Corrosion Inhibition[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(7): 1337-1349. doi: 10.11862/CJIC.2022.106 shu

Nickel Phosphide Corrosion Induced by Water and Corrosion Inhibition

Bo YANG ^{1, 2, 3} ,
Gong-Xuan LÜ ^1,, ,
Xu-Qiang ZHANG ¹ ,
Jian-Tai MA ³

1.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Gong-Xuan LÜ, gxlu@lzb.ac.cn
Received Date: 28 December 2021
Revised Date: 30 March 2022

Figures(12)

Transition metal phosphides as cocatalysts have been widely used in electrocatalysis, photoelectrocatalysis, and electrochemical energy storage. But its stability in water medium is seldom studied. Nickel phosphide (Ni_xP) was synthesized and the reaction of Ni_xP with H₂O was studied in detail. The results showed that serious corrosion of Ni_xP occurred when Ni_xP was dispersed in the water while H₂ was generated. At the same time, the corrosion products of PO₄^3- and Ni²⁺ ions were detected. Such Ni_xP corrosion in water is highly dependent on Ni_xP crystal structure and components. The deposition of NiO, ZnO, and TiO₂ metal oxide protective layer on Ni_xP can improve the anticorrosion ability of Ni_xP in the aqueous medium.
- transition metal phosphide,
- corrosion,
- metal oxide protective layer,
- stability
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