Citation: Yong-Lan FENG, Wu-Jiu JIANG, Fu-Xing ZHANG, Dai-Zhi KUANG. Solvothermal Synthesis, Structure, and Fluorescence Properties of Four Organotin Complexes Based on m-Phthaloyl Bis(substituted salicylaldehyde acylhydrazone)[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(6): 1171-1179. doi: 10.11862/CJIC.2022.105 shu

Solvothermal Synthesis, Structure, and Fluorescence Properties of Four Organotin Complexes Based on m-Phthaloyl Bis(substituted salicylaldehyde acylhydrazone)

Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Organometallic New Materials of College of Hunan Province, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: Dai-Zhi KUANG, hnkcq@qq.com
Received Date: 18 December 2021
Revised Date: 11 March 2022

Figures(2)

Four new organotin complexes based on m-phthaloyl bis(substituted salicylaldehyde acylhydrazone) (H₄L), (SnR²)₂L (1-4), were synthesized by solvothermal reaction of H₄L with R₃²SnOH, or one-pot solvothermal reaction of m-phthaloyl hydrazide, 3-tert-butyl salicylaldehyde, and tricyclohexyltin hydroxide, where H₄L=m-Ph (CONH—N=CH(o-OH)PhR¹)₂; R¹=NEt₂, R²=Ph (1); R¹=3, 5-di-tert-butyl=3, 5-t-2Bu, R²=Ph (2); R¹=3, 5-t-2Bu, R²=Cy (3); R¹=3-tert-butyl=3-t-Bu, R²=Cy (4). And they were characterized by elemental analysis, IR, and (¹H, ¹³C, and ¹¹⁹Sn) NMR. The structures of complexes 1-4 were confirmed by X-ray diffraction. Three"inward E-type"complexes 1-3 were formed by the inward orientation of two substituted salicylaldehyde acylhydrazone chains of H₄L and coordination with tin atoms. And two substituted salicylaldehyde acylhydrazone chains were oriented outward and coordinated with tin atoms to form an"outward E-type"complex 4. Complexes 1, 2, and 4 belong to the triclinic P1 space group and complex 3 belongs to the monoclinic P2₁/c space group. The central tin and the coordination atom form a five-coordinate distorted triangular bipyramids configuration. The fluorescence properties of the ligands and the complexes-chloroform solution showed that when free ligand m-Ph(CONH—N=CH(o-OH)PhNEt²)₂ (H₄L¹) with weak fluorescence and ligand m-Ph(CONH—N=CH(o-OH)Ph(3, 5-t-2Bu))₂ (H₄L²) without fluorescence coordinated with phenyltin or cyclohexyltin, the chloroform solution of the complexes emitted strong fluorescence.
- m-phthaloyl bis(substituted salicylaldehyde acylhydrazone),
- organotin complex,
- solvothermal synthesis,
- crystal structure,
- fluorescence properties
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