Citation: Zhen-Yu CAO, Yun WU, Jian-Hua GAO. Bi₉P₂O₁₈Cl: Phase Transition and Hydrogen Production by Photocatalytic Water-Splitting[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 969-976. doi: 10.11862/CJIC.2022.099 shu

Bi₉P₂O₁₈Cl: Phase Transition and Hydrogen Production by Photocatalytic Water-Splitting

School of Physics, Northwest University, Xi′an 710069, China

Corresponding author: Jian-Hua GAO, gaojh@nwu.edu.cn
Received Date: 20 December 2021
Revised Date: 18 March 2022

Figures(5)

Bi₉P₂O₁₈Cl crystals were prepared by the high-temperature molten salt method. Single-crystal X-ray diffraction data analyses demonstrated that Bi₉P ₂O₁₈Cl can undergo a crystal-to-crystal phase transition from room temperature to low temperature. At room temperature, this compound (α-phase) crystallizes in monoclinic space group P2₁/m (11) with unit cell parameters a=1.149 10(7) nm, b =0.540 64(4) nm, c=1.463 69(9) nm, β =93.741(6)°, V= 0.907 38(10) nm³. And at 100 K, it (β-phase) crystallizes in monoclinic space group P2₁/n (14) with unit cell parameters a=1.790 56(4) nm, b=0.538 870(10) nm, c=1.915 57(4) nm, β=103.693(2)°, V=1.795 76(6) nm³. Additionally, high pure powder samples of Bi₉P₂ O₁₈Cl were synthesized using solid -state reaction method, which exhibited promising performance in photocatalytic water splitting to produce H₂, the H₂ evolution rates reached 33.69 µmol·g^-1·h^-1. CCDC: 2128785, α-phase Bi₉P₂O₁₈Cl; 2145491, β-phase Bi₉P₂O₁₈Cl.
- Aurivillius,
- crystal structure,
- phase transition,
- photocatalytic hydrogen production
1. [1]
  WANG Q, XU R, WANG X S, LIU S D, HUANG Y B, CAO R. Plati-num Nanoparticle-Decorated Porous Porphyrin-Based Metal -Organic Framework for Photocatalytic Hydrogen Production[J]. Chinese J. Inorg. Chem., 2017,33(11):2038-2044. doi: 10.11862/CJIC.2017.240
2. [2]
  LU Y, SHANG G L, ZHANG H, WANG Y, TAN Y Y, SUN J H, LIU G X. Preparation of Carbon Self-Doping Graphic Carbon Nitride Nanosheets for Photocatalytic H₂ Evolution Performance under Visible-Light Irradiation[J]. Chinese J. Inorg. Chem., 2021,37(4):668-674.
3. [3]
  Chu J Y, Han X J, Yu Z, Du Y C, Song B, Xu P. Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production on CdS/Cu₇S₄/g-C₃N₄ Ternary Heterostructures[J]. ACS Appl. Mater. Interfaces, 2018,10(24):20404-20411. doi: 10.1021/acsami.8b02984
4. [4]
  Abe R. Recent Progress on Photocatalytic and Photoelectrochemical Water Splitting under Visible Light Irradiation[J]. J. Photochem. Photobiol. C, 2010,11(4):179-209. doi: 10.1016/j.jphotochemrev.2011.02.003
5. [5]
  Kato D, Hongo K, Maezono R, Higashi M, Kunioku H, Yabuuchi M, Suzuki H, Okajima H, Zhong C C, Nakano K, Abe R, Kageyama H. Valence Band Engineering of Layered Bismuth Oxyhalides toward Stable Visible-Light Water Splitting: Madelung Site Potential Analy-sis[J]. J. Am. Chem. Soc., 2017,139(51):18725-18731. doi: 10.1021/jacs.7b11497
6. [6]
  Lee Y, Terashima H, Shimodaira Y, Teramura K, Hara M, Kobayashi H, Domen K, Yashima M. Zinc Germanium Oxynitride as a Photocat-alyst for Overall Water Splitting under Visible Light[J]. J. Phys. Chem. C, 2007,111(2):1042-1048. doi: 10.1021/jp0656532
7. [7]
  Wang Q, Nakabayashi M, Hisatomi T, Sun S, Akiyama S, Wang Z, Pan Z H, Xiao X, Watanabe T, Yamada T, Shibata N, Takata T, Domen K. Oxysulfide Photocatalyst for Visible-Light-Driven Overall Water Splitting[J]. Nat. Mater., 2019,18(8):827-832. doi: 10.1038/s41563-019-0399-z
8. [8]
  Li J, Li H, Zhan G M, Zhang L Z. Solar Water Splitting and Nitrogen Fixation with Layered Bismuth Oxyhalides[J]. Acc. Chem. Res., 2017,50(1):112-121. doi: 10.1021/acs.accounts.6b00523
9. [9]
  Fujito H, Kunioku H, Kato D, Suzuki H, Higashi M, Kageyama H, Abe R. Layered Perovskite Oxychloride Bi₄ NbO₈Cl: A Stable Visible Light Responsive Photocatalyst for Water Splitting[J]. J. Am. Chem. Soc., 2016,138(7):2082-2085. doi: 10.1021/jacs.5b11191
10. [10]
  Zhong C C, Kato D, Ogawa K, Tassel C, Izumi F, Suzuki H, Kawaguchi S, Saito T, Saeki A, Abe R, Kageyama H. Bi₄AO₆Cl₂ (A=Ba, Sr, Ca) with Double and Triple Fluorite Layers for Visible-Light Water Split-ting[J]. Inorg. Chem., 2021,60(20):15667-15674. doi: 10.1021/acs.inorgchem.1c02344
11. [11]
  Kumar J P, Sekhar K S K R C, Rao T D, Babu P D, Tirupathi P. Effect of Sintering Temperature on Structural, Dielectric, and Elec-trical Property Studies of Bi₄NdTi₃FeO₁₅ Aurivillius Ceramics[J]. J. Mater. Sci.: Mater. Electron., 2021,32(7):9675-9684. doi: 10.1007/s10854-021-05628-9
12. [12]
  Kusainova A M, Zhou W Z, Irvine J T S, Lightfoot P. Layered Inter-growth Phases Bi₄MO ₈X (X=Cl, M=Ta and X=Br, M=Ta or Nb): Structural and Electrophysical Characterization[J]. J. Solid State Chem., 2002,166(1):148-157. doi: 10.1006/jssc.2002.9572
13. [13]
  Shivani V, Harish S, Archana J, Navaneethan M, Ponnusamy S, Hayakawa Y. Highly Efficient 3-D Hierarchical Bi₂WO₆ Catalyst for Environmental Remediation[J]. Appl. Surf. Sci., 2019,488:696-706. doi: 10.1016/j.apsusc.2019.05.072
14. [14]
  Li W Q, Ding X G, Wu H T, Yang H. Bi₂Mo_xW_1-xO₆ Solid Solutions with Tunable Band Structure and Enhanced Visible-Light Photocata-lytic Activities[J]. Appl. Surf. Sci., 2018,447:636-647. doi: 10.1016/j.apsusc.2018.04.039
15. [15]
  Wei Z, Zhu Y F. Synthesis and Performance Enhancement for Bi₂WO₆ as High-Activity Visible -Light -Driven Photocatalysts//Yamashita H, Li H X[J]. Nanostructured Photocatalysts: Advanced Functional Materials. Switzerland: Springer, 2016:359-389.
16. [16]
  Jiang L, Ni S, Liu G, Xu X X. Photocatalytic Hydrogen Production over Aurivillius Compound Bi₃TiNbO₉ and Its Modifications by Cr/Nb Co-Doping[J]. Appl. Catal. B, 2017,217:342-352. doi: 10.1016/j.apcatb.2017.06.012
17. [17]
  Lu Y T, Pu Y F, Wang J, Qin C X, Chen C L, Seo H J. On Structure and Methylene Blue Degradation Activity of an Aurivillius -Type Photocatalyst of Bi₄V ₂O₁₁ Nanoparticles[J]. Appl. Surf. Sci., 2015,347:719-726. doi: 10.1016/j.apsusc.2015.04.164
18. [18]
  Xu L, Wan Y P, Xie H D, Huang Y L, Qiao X B, Qin L, Seo H J. On Structure, Optical Properties and Photodegradated Ability of Aurivillius-Type Bi₃TiNbO₉ Nanoparticles[J]. J. Am. Ceram. Soc., 2016,99(12):3964-3972. doi: 10.1111/jace.14423
19. [19]
  Ji X H, Wang Q, Lu J F, Zhang D. Optical and Photochemical Char-acteristics of Aurivillius -like Semiconductor Bi₉P₂O₁₈Cl Synthe-sized via Sol-Gel-Assisted Solid-Sate Reaction[J]. Ceram. Int., 2020,46(16):25766-25774. doi: 10.1016/j.ceramint.2020.07.055
20. [20]
  Mentre O, Abraham F. Synthesis, Crystal Structure, Infrared Charac-terization, and Electrical Properties of the New Bi₉(V_1-xP_x)₂ClO₁₈ Series (0 ≤ x ≤ 1)[J]. J. Solid State Chem., 1998,136(1):34-45. doi: 10.1006/jssc.1997.7644
21. [21]
  Sheldrick G M. A Short History of SHELX[J]. Acta Crystallogr. Sect. A, 2008,A64(1):112-122.
22. [22]
  Spek A L. Single-Crystal Structure Validation with the Program PLATON[J]. J. Appl. Crystallogr., 2003,36:7-13. doi: 10.1107/S0021889802022112
23. [23]
  Kresse G, Furthmüller J. Efficiency of Ab‑Initio Total Energy Calcu-lations for Metals and Semiconductors Using a Plane Wave Basis Set[J]. Comput. Mater. Sci., 1996,6(1):15-50. doi: 10.1016/0927-0256(96)00008-0
24. [24]
  Blöchl P E. Projector Augmented-Wave Method[J]. Phys. Rev. B, 1994,50(24):17953-17979. doi: 10.1103/PhysRevB.50.17953
25. [25]
  Perdew J P, Burke K, Ernzerhof M. Generalized Gradient Approxi-mation Made Simple[J]. Phys. Rev. Lett., 1996,77(18):3865-3868. doi: 10.1103/PhysRevLett.77.3865
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Bi₉P₂O₁₈Cl: Phase Transition and Hydrogen Production by Photocatalytic Water-Splitting