Citation: Shi-Xiong LI, An-Qi FENG, Yuan HU, Gui-Chun LIANG, Li-Fei LU, Hui-Ping LU. Two-Dimensional Copper-Based Coordination Polymer: Synthesis, Structure and Ion Effect on Adsorption of Cr(Ⅵ)[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 941-950. doi: 10.11862/CJIC.2022.092 shu

Two-Dimensional Copper-Based Coordination Polymer: Synthesis, Structure and Ion Effect on Adsorption of Cr(Ⅵ)

Shi-Xiong LI ^{1, 2,,} ,
An-Qi FENG ¹ ,
Yuan HU ¹ ,
Gui-Chun LIANG ¹ ,
Li-Fei LU ¹ ,
Hui-Ping LU ¹

1.
School of Mechanical and Resource Engineering, Wuzhou University, Wuzhou, Guangxi543002, China
2.
Wuzhou Resource Recycling Engineering Technology Research Center, Wuzhou University, Wuzhou, Guangxi 543002, China

Corresponding author: Shi-Xiong LI, lsx1324@163.com
Received Date: 9 October 2021
Revised Date: 18 February 2022

Figures(10)

Coordination polymers usually have the characteristics of large specific surface area and easy control of structure, which can effectively adsorb and remove Cr(Ⅵ) in water. A copper-based coordination polymer: {[Cu(bipy)₄ (1, 3-dab)][Cu(bipy)₂(ClO₄)₂] (ClO₄)₂· (1, 3 - dab)}_n (1), was successfully synthesized by the hydrothermal synthesis method using 4, 4'-bipyridine (bipy), 1, 3-isophthalonitrile (1, 3-dab), Cu(ClO₄)₂·6H₂O as raw materials. The structure of 1 was characterized by IR, X-ray single-crystal diffraction, elemental analysis, and X-ray photoelectron spectroscopy. The results show that 1 belongs to the orthorhombic crystal system, P222₁ space group, a=1.115 52(5) nm, b= 1.116 66(4) nm, c =3.116 84(15) nm, V=3.882 5(3) nm³. The performance study of adsorbing Cr(Ⅵ) showed that the optimal dosage of adsorbent 1 was 0.04 g·L^-1. It had good adsorption performance and pH adaptability in a pH range of 1-9. The adsorption performance was the best when pH=5, and the adsorption capacity could achieve 250 mg·g^-1. The ion coexistence experiments showed that the greater the ion concentration and the higher the valence, the more obvious their effect on the adsorption of Cr(Ⅵ) by 1, and the inhibition of anion was higher than that of metal cations, followed the order of PO₄3- > SO₄^2- > CO₃^2- > Cl^- > HCO₃^- > NO₃^-. CCDC: 2114736.
- coordination polymers,
- synthesis,
- structure,
- Cr(Ⅵ),
- adsorption
1. [1]
  Dai L C, Lu Q, Zhou H Q, Shen F, Liu Z G, Zhu W K, Huang H G. Tuning Oxygenated Functional Groups on Biochar for Water Pollution Control: A Critical Review[J]. J. Hazard. Mater., 2021126547.
2. [2]
  Chen H Z, Xu L L, Ai W, Lin B, Feng Q X, Cai K. Kernel Functions Embedded in Support Vector Machine Learning Models for Rapid Water Pollution Assessment via Near-infrared Spectroscopy[J]. Sci. Total Environ., 2020,714136765. doi: 10.1016/j.scitotenv.2020.136765
3. [3]
  Li S X, Mo Q L, Lai X X, Chen Y F, Lin C S, Lu Y, Liao B L. Inorganic Coordination Polymer Quantum Sheets@Graphene Oxide Composite Photocatalysts: Performance and Mechanism[J]. J. Mater. Res., 2019,34:3220-3230. doi: 10.1557/jmr.2019.207
4. [4]
  LI S X, HUANG F L, MO Q L, LIAO B L. Synthesis, Characterization and Photocatalytic Mechanism of Hydroxyl Modified MOFs[J]. Chinese J. Inorg. Chem., 2020,36(7):1401-1412.
5. [5]
  Li S X, Luo P, Wu H Z, Wei C H, Hu Y, Qiu G L. Strategies for Improving the Performance and Application of MOFs Photocatalysts[J]. ChemCatChem, 2019,11(13):2978-2993. doi: 10.1002/cctc.201900199
6. [6]
  Zhao G X, Li J X, Ren X M, Chen C L, Wang X K. Few-Layered Gra-phene Oxide Nanosheets as Superior Sorbents for Heavy Metal Ion Pollution Management[J]. Environ. Sci. Technol., 2011,45(24):10454-10462. doi: 10.1021/es203439v
7. [7]
  Vaiopoulou E, Gikas P. Regulations for Chromium Emissions to the Aquatic Environment in Europe and Elsewhere[J]. Chemosphere, 2020,254126876. doi: 10.1016/j.chemosphere.2020.126876
8. [8]
  Acharya K, Blackburn A, Mohammed J, Haile A T, Hiruy A M, Werner D. Metagenomic Water Quality Monitoring with a Portable Laboratory[J]. Water Res., 2020,184116112. doi: 10.1016/j.watres.2020.116112
9. [9]
  Li Y X, Han Y C, Wang C C. Fabrication Strategies and Cr(Ⅵ) Elimi-nation Activities of the MOF-Derivatives and Their Composites[J]. Chem. Eng. J., 2021,405126648.
10. [10]
  Bao S Y, Yang W W, Wang Y J, Yu Y S, Sun Y Y. Highly Efficient and Ultrafast Removal of Cr(Ⅵ) in Aqueous Solution to ppb Level by Poly(allylamine hydrochloride) Covalently Cross-Linked Amino-Modified Graphene Oxide[J]. J. Hazard. Mater., 2021,409124470. doi: 10.1016/j.jhazmat.2020.124470
11. [11]
  Zhang L, Niu W Y, Sun J, Zhou Q. Efficient Removal of Cr(Ⅵ) From Water by the Uniform Fiber Ball Loaded with Polypyrrole: Static Adsorption, Dynamic Adsorption and Mechanism Studies[J]. Chemosphere, 2020,248126102. doi: 10.1016/j.chemosphere.2020.126102
12. [12]
  Marghaki N S, Jonoush Z A, Rezaee A. Improving the Performance of Cr(Ⅵ) Removal by Electrochemical Process Using Microbial Cellu-lose/Magnetic Nanoparticles Electrode[J]. J. Cleaner Prod., 2020,277123195. doi: 10.1016/j.jclepro.2020.123195
13. [13]
  Liu H, Tian G P, Wang W Y, Zhang J X, Wu T S, Ni X Y, Wu Y H. Carbon Fiber-Based Flow-through Electrode System (FES) for Cr(Ⅵ) Removal at Near Neutral pHs via Cr(Ⅲ) Reduction and In- Situ Adsorption of Cr(Ⅵ) Precipitates[J]. Chem. Eng. J., 2021,420127622. doi: 10.1016/j.cej.2020.127622
14. [14]
  Sun W H, Zhang W B, Li H L, Su Q, Zhang P, Chen L H. Insight into the Synergistic Effect on Adsorption for Cr(Ⅵ) by a Polypyrrole-Based Composite[J]. RSC Adv., 2020,10(15):8790-8799. doi: 10.1039/C9RA08756G
15. [15]
  Guan Q Q, Gao K X, Ning P, Miao R R, He L. Value-Added Utiliza-tion of Paper Sludge: Preparing Activated Carbon for Efficient Adsorption of Cr(Ⅵ) and Further Hydrogenation of Furfural[J]. Sci. Total Environ., 2020,741140265. doi: 10.1016/j.scitotenv.2020.140265
16. [16]
  Mpouras T, Polydera A, Dermatas D, Verdone N, Vilardi G. Multi Wall Carbon Nanotubes Application for Treatment of Cr(Ⅵ) -Contaminated Groundwater; Modeling of Batch & Column Experi-ments[J]. Chemosphere, 2021,269128749. doi: 10.1016/j.chemosphere.2020.128749
17. [17]
  Li J X, Du Z X, Xiong L Y, Fu L L, Bo W B. Supramolecular Isomer-ism in Two Nickel Coordination Polymers Constructed with the Flexible 2-Carboxyphenoxyacetate Linker: Syntheses, Structure Analyses and Magnetic Properties[J]. J. Solid State Chem., 2021,293121799. doi: 10.1016/j.jssc.2020.121799
18. [18]
  Li J X, Du Z X. A Binuclear Cadmium Cluster Based on π … π Stacking and Halogen…Halogen Interactions: Synthesis, Crystal Analysis and Fluorescent Properties[J]. J. Cluster Sci., 2020,31(2):507-511. doi: 10.1007/s10876-019-01666-w
19. [19]
  Li J X, Du Z X, Pan Q Y, Zhang L L, Liu D L. The First 3, 5, 6-Trichloropyridine-2-oxyacetate Bridged Manganese Coordination Polymer with Features of π … π Stacking and Halogen…Halogen Interactions: Synthesis, Crystal Analysis and Magnetic Properties[J]. Inorg. Chim. Acta, 2020,509119677. doi: 10.1016/j.ica.2020.119677
20. [20]
  Pang W, Shao B, Chen X, Gu Q X, Yang F J, Li S, Huang J. Enhanc-ing the Activity of Metal-Organic Nanosheets for Oxygen Evolution Reaction by Substituent Effects[J]. J. Colloid Interface Sci., 2022,608:306-312. doi: 10.1016/j.jcis.2021.09.115
21. [21]
  Li S X, Qiang J W, Liao B L. Structure, Magnetism and Oxygen Reduction Reaction in Mixed-Valent Cu …Cu Complex Sup-ported by Benzimidazole Derivative[J]. Inorg. Chim. Acta, 2021,521120356. doi: 10.1016/j.ica.2021.120356
22. [22]
  Wang S T, Zheng X, Zhang S H, Li G Z, Xiao Y. Study of GUPT-2, a Water-Stable Zinc -Based Metal -Organic Framework as a Highly Selective and Sensitive Fluorescence Sensor in the Detection of Al³⁺ and Fe³⁺ Ions[J]. CrystEngComm, 2021,23:4059-4068. doi: 10.1039/D1CE00323B
23. [23]
  Lu Y, Li S X, Xu S H, Chen Y F, Liang J F, Liao B L. Solvent-Induced a Series of Dysprosium Complexes with Different Slow Relaxation Behavior[J]. J. Solid State Chem., 2020,289121475. doi: 10.1016/j.jssc.2020.121475
24. [24]
  Li Y Z, Ji C M, Li L N, Wang S S, Han S G, Peng Y, Zhang S H, Luo J H. (γ-Methoxy Propyl Amine)₂PbBr₄: A Novel Two -Dimensional Halide Hybrid Perovskite with Efficient Bluish White-Light Emis-sion[J]. Inorg. Chem. Front., 2021,8:2119-2124. doi: 10.1039/D0QI01446J
25. [25]
  Li S X, Liu L M, Deng Y, Huang Y H, Chen Y F, Liao B L. Terminal Anion Induced Zinc Mononuclear Complexes trans-to-cis Isomeri-zation Regulate Photoluminescence Properties and Its Solution Behavior[J]. Polyhedron, 2019,174114158. doi: 10.1016/j.poly.2019.114158
26. [26]
  Li S X, Sun S L, Wu H Z, Wei C H, Hu Y. Effects of Electron-Donating Groups on the Photocatalytic Reaction of MOFs[J]. Catal. Sci. Technol., 2018,8(6):1696-1703. doi: 10.1039/C7CY02622F
27. [27]
  Li S X, Wei C H, Hu Y, Wu H Z, Li F S. In Situ Synthesis and Photo-catalytic Mechanism of a Cyano Bridged Cu Polymer[J]. Inorg. Chem. Front., 2018,5(6):1282-1287. doi: 10.1039/C8QI00205C
28. [28]
  Li S X, Feng Z T, Hu Y, Wei C H, Wu H Z, Huang J. In‑Situ Synthe-sis and High -Efficiency Photocatalytic Performance of Cu/Cu Inorganic Coordination Polymer Quantum Sheets[J]. Inorg. Chem., 2018,57(21):13289-13295. doi: 10.1021/acs.inorgchem.8b01795
29. [29]
  LI S X, HUANG F L, BIN Y J, WEI Y C, TANG X L, LIAO B L. Effect of Ions on Photocatalytic Performance of UIO-66-2OH[J]. Chinese J. Inorg. Chem., 2021,37(8):1465-1474.
30. [30]
  MA A Q, ZHU L G. Structural Diversity, Supramolecular Assembly, and Electronic Spectra of Four Silver Coordination Polymers with Same Components of 2-Nitro-1, 4-benzenedicarboxylate and 4, 4'-Bipyridine[J]. Chinese J. Inorg. Chem., 2015,31(8):1651-1660.
31. [31]
  YE W P, CHEN M, YANG Y, ZHA L Q, MA Y S, YUAN R X. Syn-theses, Structures and Magnetic Properties of Three Copper Phospho-nates Bearing 4, 4'-Bipyridine Bridge[J]. Chinese J. Inorg. Chem., 2016,32(8):1487-1494.
32. [32]
  WU G, WANG X F, XIAN H, GUO X L. Synthesis, Crystal Structure and Cyclic Voltametric Property of Cu Complex with 4, 4'-Bipy and α-Pyridine Carboxylate[J]. Chinese J. Inorg. Chem., 2010,26(7):1315-1318.
33. [33]
  LI R X, ZHONG W B, XIE L H, XIE Y B, LI J R. Recent Advances in Adsorptive Removal of Cr(Ⅵ) Ions by Metal-Organic Frameworks[J]. Chinese J. Inorg. Chem., 2021,37(3):385-400.
34. [34]
  Jamshidifard S, Koushkbaghi S, Hosseini S, Rezaei S, Karamipour A, Rad J A, Irani M. Incorporation of UiO-66-NH₂ MOF into the PAN/Chitosan Nanofibers for Adsorption and Membrane Filtration of Pb, Cd and Cr(Ⅵ) Ions from Aqueous Solutions[J]. J. Hazard. Mater., 2019,368:10-20. doi: 10.1016/j.jhazmat.2019.01.024
1. [1]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
2. [2]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
5. [5]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
6. [6]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
7. [7]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
8. [8]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
9. [9]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
10. [10]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
11. [11]
  Qiuyu Ming , Huijun Jiang , Zhihao Zhang . A Sightseeing Tour of Folic Acid Processing Plant. University Chemistry, 2024, 39(9): 11-15. doi: 10.12461/PKU.DXHX202404092
12. [12]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
13. [13]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
14. [14]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
15. [15]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
16. [16]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
17. [17]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
18. [18]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
19. [19]
  Qiaowen CHANG , Ke ZHANG , Guangying HUANG , Nuonan LI , Weiping LIU , Fuquan BAI , Caixian YAN , Yangyang FENG , Chuan ZUO . Syntheses, structures, and photo-physical properties of iridium phosphorescent complexes with phenylpyridine derivatives bearing different substituting groups. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 235-244. doi: 10.11862/CJIC.20240311
20. [20]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(718)
HTML views(111)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142