Citation: Xiu-Dong CHEN, Jiang-Nan KE, Ping YAN, Jin-Hang LIU, Ya-Wei WANG, Chang-Chao ZHAN, Xiao-Duo JIANG. Core-Shell Nanosphere Cobalt-Based Metal-Organic Polymer: Preparation and Lithium Storage Performance[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 836-842. doi: 10.11862/CJIC.2022.089 shu

Core-Shell Nanosphere Cobalt-Based Metal-Organic Polymer: Preparation and Lithium Storage Performance

Xiu-Dong CHEN ¹ ,
Jiang-Nan KE ¹ ,
Ping YAN ^{1, 2,,} ,
Jin-Hang LIU ^{1, 3} ,
Ya-Wei WANG ¹ ,
Chang-Chao ZHAN ^{1, 3} ,
Xiao-Duo JIANG ^2,,

1.
School of Chemistry and Chemical Engineering, Jiujiang University, Jiujiang, Jiangxi 332005, China
2.
Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang, Jiangxi 332005, China
3.
Jiujiang Key Laboratory of Organosilicon Chemistry and Application, Jiujiang, Jiangxi 332005, China

Corresponding author: Ping YAN, ypjjtu@126.com Xiao-Duo JIANG, 568666967@qq.com
Received Date: 29 November 2021
Revised Date: 3 March 2022

Figures(8)

Using trimellitic acid and cobalt nitrate hexahydrate as raw materials, two cobalt-based metal-organic polymers (Co-MOP) with different reaction times were synthesized by the hydrothermal method. The structure and morphology of Co-MOP were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and N₂ adsorption-desorption test. Two cobalt-based metal-organic polymer materials were used as anode materials for lithium-ion batteries, and the electrochemical performance tests were carried out. The results showed that Co-MOP-12 (hydrothermal reaction for 12 h) exhibited excellent electrochemical performance. The first-cycle reversible specific capacity the of Co-MOP-12 electrode reached 979 mAh·g^-1 at a current density of 100 mA·g^-1. The specific capacity was as high as 1 345 mAh·g^-1 after 100 cycles.
- metal-organic polymers,
- anode material,
- lithium-ion batteries,
- electrochemical properties
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