Citation: Zi-Xuan WANG, Yuan-Yuan JIANG, Ru-Ru ZHOU, Ping CHEN, Zhao-Yin HOU. Preparation and Application of the Bifunctional Pd/ZrHP Catalyst for Selective Hydrogenation of Phenol[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 812-820. doi: 10.11862/CJIC.2022.087 shu

Preparation and Application of the Bifunctional Pd/ZrHP Catalyst for Selective Hydrogenation of Phenol

Department of Chemistry, Zhejiang University, Hangzhou 310028, China

Corresponding author: Ping CHEN, zyhou@zju.edu.cn Zhao-Yin HOU, c224@zju.edu.cn
Received Date: 4 November 2021
Revised Date: 11 March 2022

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Hydrogenation of phenol to cyclohexanone is a vital step in the production of synthetic fiber (nylon). In this work, a layered-structured solid acid (zirconium hydrogen phosphate, ZrHP) supported Pd catalyst was synthe- sized in a microwave method. The structure and property of Pd/ZrHP catalyst were characterized via X-ray diffrac- tion (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), nitro- gen adsorption- desorption, X-ray photoelectron spectroscopy (XPS), and temperature-programmed desorption (TPD) technologies. It was found that Pd/ZrHP catalyst exhibited better performance than the Pd-based catalysts supported by traditional oxide (Al₂O₃, SiO₂, MgO), molecular sieve (H-Beta), and active carbon (XC-72) under the mild condi- tion (100 ℃, 1.0 MPa H₂). The specific activity of the surface Pd atom in Pd/ZrHP reached 612.2 h^-1, and it could be recycled five times without obvious deactivation. The synergistic effect between Pd metal and the acidic sites on ZrHP surface might be the main reason for the selective formation of cyclohexanone.
- phenol,
- cyclohexanone,
- hydrogenation,
- zirconium phosphate,
- Pd
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