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Citation: Yang WU, Jia-Le LIAN, Yi-Chuan GUO, Dong-Liang CHEN, Xu WANG, Zhi-Zhen YE, Jian-Guo LÜ. 2D-Layered Ti3C2Tx-MXene@VS2 as Anodes for High-Performance Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(4): 675-684. doi: 10.11862/CJIC.2022.080 shu

2D-Layered Ti3C2Tx-MXene@VS2 as Anodes for High-Performance Lithium-Ion Batteries

  • School of Materials Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China

  • Corresponding author: Jian-Guo LÜ, lujianguo@zju.edu.cn
  • Received Date: 12 November 2021
    Revised Date: 25 February 2022

Figures(8)

  • To explore a high-performance anode for lithium-ion batteries, 2D-layered Ti3C2Tx with high conductivity and stability was prepared by acid etching, and petal-shaped VS2 nanosheets with high theoretical specific capacity were prepared by solvothermal method. Then the 2D-layered Ti3C2Tx-MXene@VS2 hybrid was obtained by a simple liquid-phase mixing method. The morphology and structure of this hybrid were systematically characterized by scanning electron microscope, transmission electron microscope, X-ray photoelectron spectroscopy, X-ray diffraction, and energy-dispersive X-ray diffraction, while the electrochemical properties were studied by cyclic voltammetry, galvanostatic charge/discharge, long cycle life, and AC impedance spectroscopy. The results indicate that VS2 nanosheets are uniformly distributed between the layers and on the surface of Ti3C2Tx. The hybrid had a high reversible capacity (610.5 mAh·g-1 at 0.1 A·g-1), good rate performance (197.1 mAh·g-1 at 2 A·g-1), and good cycle stability (874.9 mAh·g-1 at 0.2 A·g-1 after 600 cycles; 115.9 mAh·g-1 at 2 A·g-1 after 1 500 cycles).
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