Citation: Feng-Qian YAN, Xin-Guo JING, Ting-Yun FAN, He-Sheng ZHU, Shan LIU, Cheng-Xu LIU, Xi WU, Guo-Yu DING, Wei-Wei JIANG, Chang-Xin TANG, Fu-Gen SUN. Preparation and Electrochemical Performance of Selenium/Sulfur/Carbon Composite Cathode Materials Based on Chain-like Small Se_mS_n (2≤m+n≤4) Molecules[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(4): 645-653. doi: 10.11862/CJIC.2022.078 shu

Preparation and Electrochemical Performance of Selenium/Sulfur/Carbon Composite Cathode Materials Based on Chain-like Small Se_mS_n (2≤m+n≤4) Molecules

Institute of Photovoltaics, Nanchang University, Nanchang 330031, China

Corresponding author: Chang-Xin TANG, tcx@ncu.edu.cn Fu-Gen SUN, sunfugen@ncu.edu.cn
Received Date: 1 November 2021
Revised Date: 25 February 2022

Figures(5)

Chain-like small Se_mS_n (2≤m +n≤4) molecules were successfully constructed in the ultra-microporous car- bons (UMC) by the incorporation of Se into the chain - like small S_2-4 molecules and space - confining of UMC, and then used as cathode materials for lithium-sulfur (Li-S) batteries. Compared with the chain-like small S_2-4 molecules, the chain - like small Se_mS_n (2≤m+n≤4) molecules have higher electronic conductivity, lower lithiation energy, and higher electrochemical activity. Moreover, the obtained UMC/Se_mS_n (2≤m+n≤4) composites exhibited a one -step sol- id conversion behavior during the discharge process, which could effectively prohibit the shuttle and loss of active materials in Li - S batteries. Compared with UMC/S_2-4 composites, UMC/Se_mS_n (2≤m+n≤4) composites deliver lower charge-transfer resistance and higher discharge specific capacity. Therefore, UMC/Se_mS_n-40 (2≤m+n≤4, w_SeS₂∶w_UMC=4∶6) composites maintained a high reversible specific capacity of 844 mAh·g^-1 at the current rate of 0.1C after 100 cycles and long-term cycling stability over 500 cycles with the capacity decay rate of about 0.07% per cycle at the current rate of 0.5C.
- lithium-sulfur battery,
- sulfur cathode,
- selenium-sulfur solid solution,
- small sulfur molecule,
- selenium/sulfur/carbon composites
1. [1]
  Ji X L, Lee K T, Nazar L F. A Highly Ordered Nanostructured CarbonSulphur Cathode for Lithium-Sulphur Batteries[J]. Nat. Mater., 2009,8:500-506. doi: 10.1038/nmat2460
2. [2]
  Yang Y, Zheng G Y, Cui Y. Nanostructured Sulfur Cathodes[J]. Chem. Soc. Rev., 2013,42:3018-3032. doi: 10.1039/c2cs35256g
3. [3]
  Li N, Wang Y R, Tang D M, Zhou H S. Integrating a Photocatalyst into a Hybrid Lithium-Sulfur Battery for Direct Storage of Solar Energy[J]. Angew. Chem., 2015,127:9403-9406. doi: 10.1002/ange.201503425
4. [4]
  Li C X, Yin L W. Sulfur Immobilized in Hierarchically Porous Structured Carbon as Cathodes for Lithium - Sulfur Battery with Improved Electrochemical Performance[J]. Part. Part. Syst. Charact., 2015,32:756-763. doi: 10.1002/ppsc.201400259
5. [5]
  Zhou J, Lin N, Cai W L, Guo C, Zhang K L, Zhou J B, Zhu Y C, Qian Y T. Synthesis of S/CoS₂ Nanoparticles-Embedded N-Doped Carbon Polyhedrons from Polyhedrons ZIF-67 and Their Properties in Lithium-Sulfur Batteries[J]. Electrochim. Acta, 2016,218:243-251. doi: 10.1016/j.electacta.2016.09.130
6. [6]
  Li G, Sun J H, Hou W P, Jiang S D, Huang Y, Geng J X. Three-Dimensional Porous Carbon Composites Containing High Sulfur Nanoparticle Content for High Performance Lithium-Sulfur Batteries[J]. Nat. Commun., 2016,7:10601-10608. doi: 10.1038/ncomms10601
7. [7]
  Sun F G, Wang J T, Long D H, Qiao W M, Ling L C, Lv C X, Cai R. A High-Rate Lithium-Sulfur Battery Assisted by Nitrogen-Enriched Mesoporous Carbons Decorated with Ultrafine La₂O₃ Nanoparticles[J]. J. Mater. Chem. A, 2013,1:13283-13289. doi: 10.1039/c3ta12846f
8. [8]
  Sun F G, Wang J T, Chen H C, Qiao W M, Ling L C, Long D H. Bottom Up Catalytic Approach towards Nitrogen-Enriched Mesoporous Carbons/Sulfur Composites for Superior Li-S Cathodes[J]. Sci. Rep., 2013,3:2823-2830. doi: 10.1038/srep02823
9. [9]
  Liang X, Hart C, Pang Q, Garsuch A, Weiss T, Nazar L F. A Highly Efficient Polysulfide Mediator for Lithium-Sulfur Batteries[J]. Nat. Commun., 2015,6:5682-5690. doi: 10.1038/ncomms6682
10. [10]
  Zhu T C, Pang Y, Wang Y G, Wang C X, Xia Y Y. S_0.87Se_0.13/CPAN Composites as High Capacity and Stable Cycling Performance Cathode for Lithium Sulfur Battery[J]. Electrochim. Acta, 2018,281:789-795. doi: 10.1016/j.electacta.2018.06.026
11. [11]
  Zhang Z A, Jiang S F, Lai Y Q, Li J M, Song J X, Li J. Selenium Sulfifide@Mesoporous Carbon Aerogel Composite for Rechargeable Lithium Batteries with Good Electrochemical Performance[J]. J. Power Sources, 2015,284:95-102. doi: 10.1016/j.jpowsour.2015.03.019
12. [12]
  Zhao-Karger Z R, Lin X M, Minella C B, Di W, Diemant T, Behm R J, Fichtner M. Selenium and Selenium-Sulfur Cathode Materials for High-Energy Rechargeable Magnesium Batteries[J]. J. Power Sources, 2016,323:213-219. doi: 10.1016/j.jpowsour.2016.05.034
13. [13]
  Dua H, Feng S H, Luo W, Zhou L, Mai L Q. Advanced Li-Se_xS_y Battery System: Electrodes and Electrolytes[J]. J. Mater. Sci. Technol., 2020,55:1-15. doi: 10.1016/j.jmst.2020.01.001
14. [14]
  Abouimrane A, Dambournet D W, Chapman K J, Chupas P, Weng W, Amine K. A New Class of Lithium and Sodium Rechargeable Batteries Based on Selenium and Selenium-Sulfur as a Positive Electrode[J]. J. Am. Chem. Soc., 2012,134:4505-4508. doi: 10.1021/ja211766q
15. [15]
  ZHUANG L. Design of Cathode Materials for Lithium-Selenium Batteries[J]. Acta Phys. -Chim. Sin., 2019,35(7):665-666.
16. [16]
  LIU S, YAO L, ZHANG Q, LI L L, HU N T, WEI L M, WEI H. Advances in High-Performance Lithium-Sulfur Batteries[J]. Acta Phys.- Chim. Sin., 2017,33:2339-2358. doi: 10.3866/PKU.WHXB201706021
17. [17]
  Zhang H W, Zhou L, Huang X D, Song H, Yu C Z. Encapsulation of Selenium Sulfide in Double-Layered Hollow Carbon Spheres as Advanced Electrode Material for Lithium Storage[J]. Nano Res., 2016,9(12):3725-3734. doi: 10.1007/s12274-016-1243-2
18. [18]
  Zhang B, Qin X, Lia G R, Gao X P. Enhancement of Long Stability of Sulfur Cathode by Encapsulating Sulfur into Micropores of Carbon Spheres[J]. Energy Environ. Sci., 2010,3:1531-1537. doi: 10.1039/c002639e
19. [19]
  Xin S, Gu L, Zhao N H, Yin Y X, Zhou L J, Guo Y G, Wan L J. Smaller Sulfur Molecules Promise Better Lithium-Sulfur Batteries[J]. J. Am. Chem. Soc., 2012,134(45):18510-18513. doi: 10.1021/ja308170k
20. [20]
  Guo B S, Yang T T, Du W Y, Ma Q R, Zhang L Z, Bao S J, Li X Y, Chen Y, Xu M W. Double-Walled N-Doped Carbon@NiCo₂S₄ Hollow Capsules as SeS₂ Hosts for Advanced Li-SeS₂ Batteries[J]. J. Mater. Chem. A, 2019,7:12276-12282. doi: 10.1039/C9TA02695A
21. [21]
  He J R, Lu W Q, Chen Y F, Xiong J, Wen K C, Chen X, Zhang W L, Li Y R, Qin W, He W D. Direct Impregnation of SeS₂ into a MOF-Derived 3D Nanoporous Co-N-C Architecture towards Superior Rechargeable Lithium Batterie[J]. J. Mater. Chem. A, 2018,6:10466-10473. doi: 10.1039/C8TA02434K
22. [22]
  Chen T, Kong W H, Fan M T, Zhang Z W, Wang L, Chen R P, Hu Y, Ma J, Jin Z. Chelation-Assisted Formation of Multi-Yolk-Shell Co₄N@Carbon Nanoboxes for Self-Discharge Suppressed High-Performance Li-SeS₂ Batterie[J]. J. Mater. Chem. A, 2019,7:20302-20309. doi: 10.1039/C9TA07127J
23. [23]
  Li Z, Zhang J T, Bu Y G, Xiong W L. Mesoporous Carbon@Titanium Nitride Hollow Spheres as an Efficient SeS₂ Host for Advanced Li-SeS₂ Batterie[J]. Angew. Chem. Int. Ed., 2017,56:16003-16007. doi: 10.1002/anie.201709176
24. [24]
  Xu G L, Liu J Z, Amine R, Chen Z H, Amine K. Selenium and Selenium-Sulfur Chemistry for Rechargeable Lithium Batteries: Interplay of Cathode Structures, Electrolytes, and Interfaces[J]. ACS Energy Lett., 2017,2:605-614. doi: 10.1021/acsenergylett.6b00642
25. [25]
  Zhang W C, Wang H Q, Zhang N, Liu H G, Chen Z, Zhang L J, Guo S P, Li D, Xu J Z. One-Step In Situ Preparation of Polymeric Selenium Sulfifide Composite as a Cathode Material for Enhanced Sodium/ Potassium Storage[J]. ACS Appl. Mater. Interfaces, 2019,11:9807-9443.
26. [26]
  Li S P, Zhang W, Zeng Z Q, Cheng S J, Xie J. Selenium or Tellurium as Eutectic Accelerators for High-Performance Lithium/Sodium-Sulfur Batteries[J]. Electrochem. Energy Rev., 2020,3:613-642. doi: 10.1007/s41918-020-00072-5
27. [27]
  Yang C P, Xin S, Yin Y X, Ye H, Zhang J, Guo Y G. An Advanced Selenium-Carbon Cathode for Rechargeable Lithium-Selenium Batteries[J]. Angew. Chem. Int. Ed., 2013,52:8363-8367. doi: 10.1002/anie.201303147
28. [28]
  Bucur C B, Bonnick P, Jones M, Muldoon J. The Evolution of Selenium Cathodes: From Infusion Melts to Particle Synthesis[J]. Sustainable Energy Fuels, 2018,2:759-762. doi: 10.1039/C8SE00017D
29. [29]
  Eftekhari A. The Rise of Lithium-Selenium Batteries[J]. Sustainable Energy Fuels, 2017,1:14-29. doi: 10.1039/C6SE00094K
30. [30]
  Li X N, Liang J W, Zhang K H, Zhang W Q, Zhu Y C, Qian Y T. Amorphous S-Rich S_1-xSe_x /C (x≤0.1) Composites Promise Better Lithium-Sulfur Batteries in a Carbonate-Based Electrolyte[J]. Energy Environ. Sci., 2015,8:3181-3186. doi: 10.1039/C5EE01470K
31. [31]
  Sun F G, Cheng H Y, Chen J Z, Zheng N, Li Y S, Shi J L. Heteroatomic Se_nS_8-n Molecules Confifined in Nitrogen-Doped Mesoporous Carbons as Reversible Cathode Materials for High Performance Lithium Batteries[J]. ACS Nano, 2016,10:8289-8298. doi: 10.1021/acsnano.6b02315
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Preparation and Electrochemical Performance of Selenium/Sulfur/Carbon Composite Cathode Materials Based on Chain-like Small SemSn (2≤m+n≤4) Molecules

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Preparation and Electrochemical Performance of Selenium/Sulfur/Carbon Composite Cathode Materials Based on Chain-like Small Se_mS_n (2≤m+n≤4) Molecules