Citation: Jun-Li LI, Yi-Hang WEN, Le-Jia WANG, Xing LI, Xun-Wen XIAO. Photocurrent Response Properties of 2, 6-Bis(3′-pyridyl)-tetrathiafulvalene Based Zn/Co Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(4): 745-751. doi: 10.11862/CJIC.2022.071 shu

Photocurrent Response Properties of 2, 6-Bis(3′-pyridyl)-tetrathiafulvalene Based Zn/Co Coordination Polymer

Jun-Li LI ^{1, 2} ,
Yi-Hang WEN ^3,, ,
Le-Jia WANG ² ,
Xing LI ¹ ,
Xun-Wen XIAO ²

1.
School of Material Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China
2.
School of Material and Chemical Engineering, Ningbo University of Technology, Ningbo, Zhejiang 315211, China
3.
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: Yi-Hang WEN, wyh@zjnu.edu.cn
Received Date: 14 October 2021
Revised Date: 22 December 2021

Figures(6)

This is the first time that coordination polymers (CPs) with the ligand 2, 6-bis(3′-pyridyl)-tetrathiafulva- lene(3′-py-TTF-3-py) has been reported. These two CPs are isostructural with formulated as [Zn(3′-py-TTF-3-py)₂ (TPA)] _n (1) and [Co(3′-py-TTF-3-py)₂(TPA)]_n (2), (H₂TPA=terephthalic acid). The X -ray single- crystal diffraction shows that 1 and 2 are 2D coordination polymers. The photoelectric experiment results show that the S…S interac- tions and the center metal in the CPs have an important impact on their photocurrent responses.
- coordination polymers,
- tetrathiafulvalene,
- S…S interaction,
- photocurrent responsive
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沈阳化工大学材料科学与工程学院沈阳 110142