Citation: Jun-Li LI, Yi-Hang WEN, Le-Jia WANG, Xing LI, Xun-Wen XIAO. Photocurrent Response Properties of 2, 6-Bis(3′-pyridyl)-tetrathiafulvalene Based Zn/Co Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(4): 745-751. doi: 10.11862/CJIC.2022.071 shu

Photocurrent Response Properties of 2, 6-Bis(3′-pyridyl)-tetrathiafulvalene Based Zn/Co Coordination Polymer

  • Corresponding author: Yi-Hang WEN, wyh@zjnu.edu.cn
  • Received Date: 14 October 2021
    Revised Date: 22 December 2021

Figures(6)

  • This is the first time that coordination polymers (CPs) with the ligand 2, 6-bis(3′-pyridyl)-tetrathiafulva- lene(3′-py-TTF-3-py) has been reported. These two CPs are isostructural with formulated as [Zn(3′-py-TTF-3-py)2 (TPA)] n (1) and [Co(3′-py-TTF-3-py)2(TPA)]n (2), (H2TPA=terephthalic acid). The X -ray single- crystal diffraction shows that 1 and 2 are 2D coordination polymers. The photoelectric experiment results show that the S…S interac- tions and the center metal in the CPs have an important impact on their photocurrent responses.
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