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Citation: Xiao-Li CHEN, Lu LIU, Lu SHANG, Miao CAI, Hua-Li CUI, Hua YANG, Ji-Jiang WANG. A Highly Sensitive and Multi-responsive Zn-MOF Fluorescent Sensor for Detection of Fe3+, 2, 4, 6-Trinitrophenol, and Ornidazole[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(4): 735-744. doi: 10.11862/CJIC.2022.063 shu

A Highly Sensitive and Multi-responsive Zn-MOF Fluorescent Sensor for Detection of Fe3+, 2, 4, 6-Trinitrophenol, and Ornidazole

  • School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy & New Function Materials, Yan′an University, Yan′an, Shaanxi 716000, China

  • Corresponding author: Xiao-Li CHEN, chenxiaoli003@163.com
  • Received Date: 17 September 2021
    Revised Date: 22 November 2021

Figures(8)

  • A Zinc metal-organic framework (Zn-MOF) based on H4bta (1, 2, 3, 5-benzene tetracarboxylic acid) and bpy (4, 4′- dipyridine) ligands, namely {[Zn2(bta) (bpy) (H2O)2]·H2O}n (1), have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction analysis. MOF 1 shows a 3D network structure. The completely deprotonated (bta)4- ligand adopts a μ6 -η1 -η2 -η2 -η1 chelating and bridging coordination mode. Interestingly, 1 is a high sensitivity, good selectivity, and multi-response fluorescence sensor, which can be used for detection of Fe3+, 2, 4, 6-trinitrophenol, and ornidazole. In addition, the thermal stability of 1 was also studied.
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