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Citation: Zi-Wei WANG, Hao-Dong WU, Yaseen Muhammad, Ai-Lin LIANG, He LIU, Zi-Ang NING, Shuai WANG, Gang WANG, Wei QUAN, Hao WANG. Two-Dimensional Coordination Polymer [Tb(1, 4-bdc)1.5(phen)(H2O)]n: Synthesis, Crystal Structure and Luminescent Detection of Fe3+[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(3): 551-558. doi: 10.11862/CJIC.2022.056 shu

Two-Dimensional Coordination Polymer [Tb(1, 4-bdc)1.5(phen)(H2O)]n: Synthesis, Crystal Structure and Luminescent Detection of Fe3+

  • 1.

    Beijing Key Lab of Special Elastomer Composite Materials, College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China

  • 2.

    Institute of Chemical Sciences, University of Peshawar, Peshawar 25120, Pakistan

  • Corresponding author: Hao WANG, wangh@bipt.edu.cn
  • Received Date: 14 September 2021
    Revised Date: 20 November 2021

Figures(8)

  • Two-dimensional coordination polymer of [Tb(1, 4-bdc)1.5(phen)(H2O)]n (1) (1, 4-H2bdc=terephthalic acid, phen=1, 10-phenanthroline) was synthesized by solvothermal approach. Complex 1 was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy, elemental analysis, and fluorescence spectra. X-ray diffraction crystallographic analyses show that complex 1 crystallizes in the triclinic crystal system P1 space group; two adjacent Tb(Ⅲ) ions are bridged by —O—C—O— from four 1, 4-bdc2- into a binuclear unit, and further bridged by 1, 4-bdc2- into an infinite 2D layered structure. The fluorescence experiment proved that the complex 1 can detect Fe3+ through the fluorescence quenching mechanism with Ksv=8.39×103 L·mol-1 and limit of detection of 0.017 μmol·L-1.
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