Citation: Xiao-Dong HUANG, Jiong-Jia CHENG, Cheng-Long TAO, Jian WANG, Xiao-Feng WANG, Gang WU, Guang-Xiang LIU. Barium Complex In Situ Synthesized from 1, 4, 5, 8-Naphthalene Tetracarboxylic Acid: Structure, Detection of Aromatic Amines, and Use as a Precursor of Nano BaCO₃[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(3): 559-568. doi: 10.11862/CJIC.2022.053 shu

Barium Complex In Situ Synthesized from 1, 4, 5, 8-Naphthalene Tetracarboxylic Acid: Structure, Detection of Aromatic Amines, and Use as a Precursor of Nano BaCO₃

1.
School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China
2.
College of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China
3.
College of Material and Chemical Engineering, Chuzhou University, Chuzhou, Anhui 239012, China

Corresponding author: Xiao-Feng WANG, wangxf0215@163.com
Received Date: 24 September 2021
Revised Date: 27 December 2021

Figures(14)

Using 1, 4, 5, 8-naphthalene tetracarboxylic acid as a raw material, a luminescent barium-based metalorganic framework (MOF), [Ba(dna)(H₂O)₂]_n (1, H₂dna=1, 8-naphthalic anhydride-4, 5-dicarboxylic), with a 3D topological structure was synthesized by in situ reaction under solvothermal conditions, and characterized by single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and powder X-ray diffraction. The structural analysis demonstrates that it has the underlying 3D topology, encompassing a π-conjugated organic ligand with an anhydride group. It exhibited a low detection limit for aromatic amines in an aqueous solution, which may be driven by an anhydride amine reaction between the ligand and the hosted amines, with a significant enhancement of the emission intensity and visual color change. Furthermore, micro-crystalline BaCO₃ particles can be prepared through direct calcination of complex 1 as a precursor at moderately elevated temperatures.
- Ba(Ⅱ) complex,
- carboxylate group,
- luminescent property,
- BaCO₃ particles
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Barium Complex In Situ Synthesized from 1, 4, 5, 8-Naphthalene Tetracarboxylic Acid: Structure, Detection of Aromatic Amines, and Use as a Precursor of Nano BaCO3

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通讯作者: 陈斌, bchen63@163.com

Barium Complex In Situ Synthesized from 1, 4, 5, 8-Naphthalene Tetracarboxylic Acid: Structure, Detection of Aromatic Amines, and Use as a Precursor of Nano BaCO₃