Citation: Shi-Zhao WU, Han-Lu GAO, Xiao-Feng LU, Shi-Tao ZHENG, Jing GAO, Guo-Hua LI. Mesoporous Tungsten Carbide Nanoflakes Globular Clusters: Preparation and Electrocatalytic Properties for Hydrogen Evolution[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(3): 459-468. doi: 10.11862/CJIC.2022.051 shu

Mesoporous Tungsten Carbide Nanoflakes Globular Clusters: Preparation and Electrocatalytic Properties for Hydrogen Evolution

Shi-Zhao WU ¹ ,
Han-Lu GAO ¹ ,
Xiao-Feng LU ¹ ,
Shi-Tao ZHENG ¹ ,
Jing GAO ¹ ,
Guo-Hua LI ^{1, 2,,}

1.
School of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
2.
State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou 310032, China

Corresponding author: Guo-Hua LI, nanozjut@zjut.edu.com
Received Date: 23 September 2021
Revised Date: 7 January 2022

Figures(11)

Tungsten carbide nanoflakes globular clusters (WC NFs) with the typical mesoporous structure were prepared by controlled breakdown anodization by a gas-solid carburization process. The crystal phase, microstructure, and pore size distribution of the nanoflowers were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and N₂ adsorption-desorption test. The electrochemical properties were evaluated using linear sweep voltammetry, cyclic voltammetry, chronoamperometry, and electro-chemical impedance spectroscopy in 1 mol·L^-1 H₂SO₄ solution. The results showed that as-prepared WC NFs exhibited enhanced superior hydrogen evolution performance in terms of a small η₁₀ (overpotential to obtain a current density of 10 mA·cm^-2) of 150 mV, a Tafel slope of 56 mV·dec^-1, and outstanding long-term cycling stability.
- mesoporous nanoflower,
- anodization,
- electrocatalysis,
- hydrogen evolution reaction
1. [1]
  Li H, Hu M H, Zhang L Y, Huo L L, Jing P, Liu B C, Gao R, Zhang J, Liu B. Hybridization of Bimetallic Molybdenum-Tungsten Carbide with Nitrogen-Doped Carbon: A Rational Design of Super Active Porous Composite Nanowires with Tailored Electronic Structure for Boosting Hydrogen Evolution Catalysis[J]. Adv. Funct. Mater., 2020,30(40)2003198. doi: 10.1002/adfm.202003198
2. [2]
  Chen D, Zhu J W, Pu Z H, Mu S C. Anion Modulation of Pt-Group Metals and Electrocatalysis Applications[J]. Chem. Eur. J., 2021,27(48):12257-12271. doi: 10.1002/chem.202101645
3. [3]
  Lei Y P, Wang Y C, Liu Y, Song C Y, Li Q, Wang D S, Li Y D. Designing Atomic Active Centers for Hydrogen Evolution Electrocata-lysts[J]. Angew. Chem. Int. Ed., 2020,59(16):20794-20812.
4. [4]
  Zhang Q Q, Guan J Q. Single-Atom Catalysts for Electrocatalytic Applications[J]. Adv. Funct. Mater., 2020,30(31)2000768. doi: 10.1002/adfm.202000768
5. [5]
  She Z W, Kibsgaard J, Dickens C F, Chorkendorff I B, Norskov J K, Jaramillo T F. Combining Theory and Experiment in Electrocatalysis: Insights into Materials Design[J]. Science, 2017,355(6321)eaad4998. doi: 10.1126/science.aad4998
6. [6]
  Qin T C, Wang Z G, Wang Y Q, Besenbacher F, Otyepka M, Dong M D. Recent Progress in Emerging Two-Dimensional Transition Metal Carbides[J]. Nano-Micro Lett., 2021,13(1)183. doi: 10.1007/s40820-021-00710-7
7. [7]
  Eftekhari A. Electrocatalysts for Hydrogen Evolution Reaction[J]. Int. J. Hydrogen Energy, 2017,42(16):11053-11077. doi: 10.1016/j.ijhydene.2017.02.125
8. [8]
  Yang X F, Kimmel Y C, Fu J, Koel B E, Chen J G. Activation of Tung-sten Carbide Catalysts by Use of an Oxygen Plasma Pretreatment[J]. ACS Catal., 2012,2(5):765-769. doi: 10.1021/cs300081t
9. [9]
  Zhang L N, Ma Y Y, Lang Z L, Wang Y H, Khan S U, Yan G, Tan H Q, Zang H Y, Li Y G. Ultrafine Cable-like WC/W₂C Heterojunction Nanowires Covered by Graphitic Carbon Towards Highly Efficient Electrocatalytic Hydrogen Evolution[J]. J. Mater. Chem. A, 2018,6(31):15395-15403. doi: 10.1039/C8TA05007D
10. [10]
  Garcia-Esparza A T, Cha D, Ou Y W, Kubota J, Domen K, Takanabe K. Tungsten Carbide Nanoparticles as Efficient Cocatalysts for Pho-tocatalytic Overall Water Splitting[J]. ChemSusChem, 2013,6(1):168-181. doi: 10.1002/cssc.201200780
11. [11]
  Zhang H F, Pan Q, Sun Z P, Cheng C W. Three-Dimensional Macro-porous W₂C Inverse Opal Arrays for the Efficient Hydrogen Evolu- tion Reaction[J]. Nanoscale, 2019,11(24):11505-11512. doi: 10.1039/C9NR03548F
12. [12]
  Ko Y J, Cho J M, Kim I, Jeong D S, Lee K S, Park J K, Balk Y J, Choi H J, Lee W S. Tungsten Carbide Nanowalls as Electrocatalyst for Hydrogen Evolution Reaction: New Approach to Durability Issue[J]. Appl. Catal. B, 2017,203:684-691. doi: 10.1016/j.apcatb.2016.10.085
13. [13]
  Chen Z Y, Duan L F, Sheng T, Lin X, Chen Y F, Chu Y Q, Sun S G, Lin W F. Dodecahedral W@WC Composite as Efficient Catalyst for Hydrogen Evolution and Nitrobenzene Reduction Reactions[J]. ACS Appl. Mater. Interfaces, 2017,9(24):20594-20602. doi: 10.1021/acsami.7b04419
14. [14]
  Fei H L, Yang Y, Fan X J, Wang G, Ruan G D, Tour J M. Tungsten-Based Porous Thin-Films for Electrocatalytic Hydrogen Generation[J]. J. Mater. Chem. A, 2015,3(11):5798-5804. doi: 10.1039/C4TA06938B
15. [15]
  Kang J S, Kim J, Lee M J, Son Y J, Jeong J, Chung D Y, Lim A, Choe H, Park H S, Sung Y E. Electrochemical Synthesis of Nanopo-rous Tungsten Carbide and Its Application as Electrocatalysts for Photoelectrochemical Cells[J]. Nanoscale, 2017,9(17):5413-5424. doi: 10.1039/C7NR00216E
16. [16]
  Narges F F, Tohru S. A Novel Method for Synthesis of Titania Nano-tube Powders Using Rapid Breakdown Anodization[J]. Chem. Mater., 2009,21(9):1967-1979. doi: 10.1021/cm900410x
17. [17]
  Hanna S, Veronika P, Ludek H, Jan M M. Preparation of Porcupine-like Bi₂O₃ Needle Bundles by Anodic Oxidation of Bismuth[J]. Eletrochem. Commun., 2017,84:6-9. doi: 10.1016/j.elecom.2017.09.013
18. [18]
  Hanna S, Zdenek S, Jan M, Ludek H, Roman B, Tomas W, Jan M M. Bismuth Oxychloride Nanoplatelets by Breakdown Anodization[J]. ChemElectroChem, 2019,6(2):336-341. doi: 10.1002/celc.201801280
19. [19]
  Weidman M C, Esposito D V, Hsu Y C, Chen J C. Comparison of Electrochemical Stability of Transition Metal Carbides (WC, W₂C, Mo₂C) Over a Wide pH Range[J]. J. Power Sources, 2012,202:11-17. doi: 10.1016/j.jpowsour.2011.10.093
20. [20]
  Zeng M Q, Chen Y X, Li J X, Xue H F, Mendes R G, Liu J X, Zhang T, Rümmeli M H, Fu L. 2D WC Single Crystal Embedded in Gra-phene for Enhancing Hydrogen Evolution Reaction[J]. Nano Energy, 2017,33:356-362. doi: 10.1016/j.nanoen.2017.01.057
21. [21]
  Emin S, Altinkaya C, Semerci A, Okuyucu H, Yildiz A, Stefanov P. Tungsten Carbide Electrocatalysts Prepared from Metallic Tungsten Nanoparticles for Efficient Hydrogen Evolution[J]. Appl. Catal. B, 2018,236:147-153. doi: 10.1016/j.apcatb.2018.05.026
22. [22]
  Wang Y N, Zhang L P, Meng X X, Feng L, Wang T, Zhang W M, Yang N T. Scalable Processing Hollow Tungsten Carbide Spherical Superstructure as an Enhanced Electrocatalyst for Hydrogen Evolu-tion Reaction over a Wide pH Range[J]. Electrochim. Acta, 2019,319:775-782. doi: 10.1016/j.electacta.2019.07.038
23. [23]
  Zhao T, Gao J K, Wu F, He P P, Li Y W, Yao J M. Highly Active Cobalt/Tungsten Carbide@N-Doped Porous Carbon Nanomaterials Derived from Metal-Organic Frameworks as Bifunctional Catalysts for Overall Water Splitting[J]. Energy Technol., 2019,7(4)1800969. doi: 10.1002/ente.201800969
24. [24]
  Wang F M, He P, Li Y C, Shifa A, Deng S F, Liu K L, Wang Q S, Wang F, Wen Y, Wang Z X, Zhan X Y, Sun L F, He J. Interface Engineered W_xC@WS₂ Nanostructure for Enhanced Hydrogen Evolu-tion Catalysis[J]. Adv. Funct. Mater., 2017,27(7)1605802. doi: 10.1002/adfm.201605802
25. [25]
  Kim I, Park S W, Kim D W. Carbon-Encapsulated Multi-phase Nanocomposite of W₂C@WC_1-x as a Highly Active and Stable Elec-trocatalyst for Hydrogen Generation[J]. Nanoscale, 2018,10(45):21123-21131. doi: 10.1039/C8NR07221C
26. [26]
  Hu Y, Yu B, Li W X, Ramadoss M, Chen Y F. W₂C Nanodot-Decorated CNT Networks as a Highly Efficient and Stable Electrocatalyst for Hydrogen Evolution in Acidic and Alkaline Media[J]. Nanoscale, 2019,11(11):4876-4884. doi: 10.1039/C8NR10281C
1. [1]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
2. [2]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
3. [3]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
4. [4]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
5. [5]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
6. [6]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
7. [7]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
8. [8]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
9. [9]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
10. [10]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
11. [11]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
12. [12]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
13. [13]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
14. [14]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
15. [15]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
16. [16]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
17. [17]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
18. [18]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
19. [19]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
20. [20]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(448)
HTML views(92)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142