Citation: Wen-Jing DONG, Hai-Shen REN, Tian-Yi XIE, Hui-Xing LIN. In-Situ Synthesis and Performance of Oxygen Vacancy-Rich BiOCl Photocatalytic Material Derived from Bismuth-Based Glass[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(3): 501-509. doi: 10.11862/CJIC.2022.047 shu

In-Situ Synthesis and Performance of Oxygen Vacancy-Rich BiOCl Photocatalytic Material Derived from Bismuth-Based Glass

Wen-Jing DONG ^{1, 2} ,
Hai-Shen REN ² ,
Tian-Yi XIE ^2,, ,
Hui-Xing LIN ^{1, 2,,}

1.
College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China
2.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China

Corresponding author: Tian-Yi XIE, xietianyi@mail.sic.ac.cn Hui-Xing LIN, huixinglin@mail.sic.ac.cn
Received Date: 1 November 2021
Revised Date: 15 December 2021

Figures(9)

Oxygen vacancies enact a vital role on the visible light absorption range and electron-hole separation efficiency of the photocatalytic material. Bismuth-based glass is rich in oxygen vacancy defects. BiOCl photocatalytic material was synthesized in-situ by hydrochloric acid corrosion of bismuth-based glass, and the influence of the outer body of the glass network on the oxygen vacancy concentration was studied. X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM) and electron paramagnetic resonance (EPR) were used to characterize the structure, morphology, and oxygen vacancy concentration of the synthesized BiOCl material. The results showed that the number of oxygen vacancies of the Bi₂O₃-B₂O₃-ZnO bismuth-based glass increased with the increase of the external body composition of the network. The in-situ synthesized BiOCl will "inherit"a large number of oxygen vacancies in the glass. The degradation rate of rhodamine B was as high as 93.1% under visible light for 100 min.
- photocatalytic materials,
- BiOCl,
- bismuth-based glass,
- oxygen-rich vacancies
1. [1]
  Li G B, Huang S Q, Zhu N W, Yuan H P, Ge D D, Wei Y C. Defect-Rich Heterojunction Photocatalyst Originated from the Removal of Chloride Ions and Its Degradation Mechanism of Norfloxacin[J]. Chem. Eng. J., 2021,421:127852-127864. doi: 10.1016/j.cej.2020.127852
2. [2]
  Kuila A, Saravanan P, Bahnemann D, Wang C. Novel Ag Decorated, BiOCl Surface Doped AgVO₃ Nanobelt Ternary Composite with Z-Scheme Homojunction-Heterojunction Interface for High Prolific Photo Switching, Quantum Efficiency and Hole Mediated Photocatalysis[J]. Appl. Catal. B, 2021,293(15):120224-120240.
3. [3]
  Zhang L, Li Y H, Li Q, Fan J J, Carabineiro S, Lv K. Recent Advances on Bismuth-Based Photocatalysts: Strategies and Mechanisms[J]. Chem. Eng. J., 2021,419(4):129484-129506.
4. [4]
  Huang Y W, Zhang N, Wu Z J, Xie X Q. Artificial Nitrogen Fixation over Bismuth-Based Photocatalysts: Fundamentals and Future Perspectives[J]. J. Mater. Chem. A, 2020,8(10):4978-4995. doi: 10.1039/C9TA13589H
5. [5]
  Wang H X, Liao B, Lu T, Ai Y L, Liu G. Enhanced Visible-Light Photocatalytic Degradation of Tetracycline by a Novel Hollow BiOCl@CeO₂ Heterostructured Microspheres: Structural Characterization and Reac-tion Mechanism[J]. J. Hazard. Mater., 2020,385:121552-121561. doi: 10.1016/j.jhazmat.2019.121552
6. [6]
  Deng F, Luo Y B, Xia B H, Luo X B, Luo S L, Dionysiou D. Efficient Toxicity Elimination of Aqueous Cr (Ⅳ) by Positively-Charged BiOCl_xI1_-x, BiOBr_xI1_-x and BiOCl_xBr1_-x Solid Solution with Internal Hole-Scavenging Capacity via the Synergy of Adsorption and Photocatalytic Reduction[J]. J. Hazard. Mater., 2020,383(5):121127-121140.
7. [7]
  Eshaq G, Wang S B, Sun H Q, Sillanpää M. Core/Shell FeVO₄@BiOCl Heterojunction as a Durable Heterogeneous Fenton Catalyst for the Efficient Sonophotocatalytic Degradation of p-Nitrophenol[J]. Sep. Purif. Technol., 2020,231(16):115915-115931.
8. [8]
  Huang S Q, Li L, Zhu N W, Lou Z Y, Liu W Q, Cheng J H, Wang H M, Luo P X, Wang H. Removal and Recovery of Chloride Ions in Concentrated Leachate by Bi (Ⅲ) Containing Oxides Quantum Dots/Two-Dimensional Flakes[J]. J. Hazard. Mater., 2020,382(15):121041-121051.
9. [9]
  Wang B, Di J, Lu L, Yan S C, Liu G P, Ye Y Z. Sacrificing Ionic Liquid-Assisted Anchoring of Carbonized Polymer Dots on Perovskite-like PbBiO₂Br for Robust CO₂ Photoreduction[J]. Appl. Catal. B, 2019,254(5):551-559.
10. [10]
  Fan K H, Yu C, Chen S T, Lan S Y, Zhu M S. Metallic Bi Self-Deposited BiOCl Promoted Piezocatalytic Removal of Carbamazepine[J]. Surf. Interfaces, 2021,26:101335-101343. doi: 10.1016/j.surfin.2021.101335
11. [11]
  Asadzadeh-Khaneghah S, Habibi-Yangjeh A, Yubuta K. Novel g-C₃N₄ Nanosheets/CDs/BiOCl Photocatalysts with Exceptional Activity under Visible Light[J]. J. Am. Ceram. Soc., 2019,102(3):1435-1453. doi: 10.1111/jace.15959
12. [12]
  Li R J, Luan Q J, Dong C, Dong W J, Tang W, Wang G, Lu Y F. Light-Facilitated Structure Reconstruction on Self-Optimized Photocatalyst TiO₂@BiOCl for Selectively Efficient Conversion of CO₂ to CH₄[J]. Appl. Catal. B, 2021,286(5):119832-119843.
13. [13]
  Mei J, Tao Y, Gao C, Zhu Q, Zhang H Y, Yu J, Fang Z, Xu H, Wang Y H, Li G S. Photo-Induced Dye-Sensitized BiPO₄/BiOCl System for Stably Treating Persistent Organic Pollutants[J]. Appl. Catal. B, 2021,285(15):119841-119852.
14. [14]
  Wu S S, Yu X, Zhang J L, Zhang Y M, Zhu Y, Zhu M S. Construction of BiOCl/CuBi₂O₄ S-Scheme Heterojunction with Oxygen Vacancy for Enhanced Photocatalytic Diclofenac Degradation and Nitric Oxide Removal[J]. Chem. Eng. J., 2021,411(1):128555-128567.
15. [15]
  Hussain M, Mehmood R, Azhar U, Wang J N, Song L H. BiOCl-Coated UiO-66-NH₂ Metal-Organic Framework Nanoparticles for Visible-Light Photocatalytic Cr(Ⅵ) Reduction[J]. ACS Appl. Nano Mater., 2021,4(4):4037-4047. doi: 10.1021/acsanm.1c00380
16. [16]
  Shen T, Shi X K, Guo J X, Li J, Yuan S D. Photocatalytic Removal of NO by Light-Driven Mn₃O₄/BiOCl Heterojunction Photocatalyst: Optimization and Mechanism[J]. Chem. Eng. J., 2021,408(15):128014-128028.
17. [17]
  Shahid M, Mehmood R, Athar M, Hussain J, Wei Y W, Khaliq A. BiOCl Nanoplates Doped with Fe³⁺ Ions for the Visible-Light Degradation of Aqueous Pollutants[J]. ACS Appl. Nano Mater., 2020,4(1):746-758.
18. [18]
  Zhan G M, Li j, Hu Y, Zhao S X, Gao S Y, Jia F L, Zhang L Z. The Surface Hydroxyl and Oxygen Vacancy Dependent Cr (Ⅳ) Adsorption Performance of BiOCl[J]. Environ. Sci. Nano, 2020,7(5):1454-1463. doi: 10.1039/D0EN00108B
19. [19]
  Song Z, Dong X L, Fang J D, Xiong G H, Wang N, Tang X M. Improved Photocatalytic Degradation of Perfluorooctanoic Acid on Oxygen Vacancies-Tunable Bismuth Oxychloride Nanosheets Prepared by a Facile Hydrolysis[J]. J. Hazard. Mater., 2019,377(5):371-380.
20. [20]
  Jiang Z, Xiao C, Yin X Y, Xu L G, Liu C L, Wang H L. Facile Preparation of a Novel Bi₂₄O₃₁Br₁₀/Nano-ZnO Composite Photocatalyst with Enhanced Visible Light Photocatalytic Ability[J]. Ceram. Int., 2020,46(8):10771-10778. doi: 10.1016/j.ceramint.2020.01.087
21. [21]
  Zhang Z J, Wang W Z, Shang M, Yin W Z. Photocatalytic Degradation of Rhodamine B and Phenol by Solution Combustion Synthesized BiVO₄ Photocatalyst[J]. Catal. Commun., 2010,11(11):982-986. doi: 10.1016/j.catcom.2010.04.013
22. [22]
  ZHAO J J, ZHANG Z Z, CHEN X L, WANG B, DENG J Y, ZHANG D Q, LI H X. Microwave-Induced Assembly of CuS@MoS₂ Core-Shell Nanotubes and Study on Their Photocatalytic Fenton-like Reactions[J]. Acta Chim. Sinica, 2020,78(9):961-969.
23. [23]
  Hashimoto T, Shimoda Y, Nasu H, Ishihara A. BiOCl-Coated UiO-66-NH₂ Metal-Organic Framework Nanoparticles for Visible-Light Photocatalytic Cr(Ⅳ) Reduction[J]. J. Am. Ceram. Soc., 2011,94(7):2061-2066. doi: 10.1111/j.1551-2916.2010.04383.x
24. [24]
  Chen J Q, Li Y F, Miao W L, Lei Q, Li M Y. Dependence of Glass Transition on the Structure in Bi-B-Zn Oxide Glass[J]. J. Alloys Compd., 2018,742(25):151-158.
25. [25]
  Ren Y H, Zou J H, Jing K Q, Liu Y Y, Guo B B, Song Y J, Yu Y, Wu L. Photocatalytic Synthesis of N-benzyleneamine from Benzylamine on Ultrathin BiOCl Nanosheets under Visible Light[J]. J. Catal., 2019,380:123-131. doi: 10.1016/j.jcat.2019.10.018
26. [26]
  Hou J H, Dai D, Wei R, Wu X G, Wang X Z, Tahir M, Zou J J. Narrowing the Band Gap of BiOCl for the Hydroxyl Radical Generation of Photocatalysis under Visible Light[J]. ACS Sustainable Chem. Eng., 2019,7(19):16569-16576. doi: 10.1021/acssuschemeng.9b03885
27. [27]
  Phasayavan W, Japa M, Pornsuwan S, Tantraviwat D, Kielar F. Oxygen-Deficient Bismuth Molybdate Nanocatalysts: Synergistic Effects in Boosting Photocatalytic Oxidative Coupling of Benzylamine and Mechanistic Insight[J]. J. Colloid Interface Sci., 2021,581(1):719-728.
28. [28]
  Wei Z, Li W L, Hu J S, Ma X G, Zhu Y F. Interfacial Internal Electric Field and Oxygen Vacancies Synergistically Enhance Photocatlytic Performance of Bismuth Oxychloride[J]. J. Hazard. Mater., 2021,402(15):123470-123479.
29. [29]
  Zhu X W, Yang J M, Zhu X L, Yuan J J, Zhou M. Exploring Deep Effects of Atomic Vacancies on Activating CO₂ Photoreduction via Rationally Designing Indium Oxide Photocatalysts[J]. Chem. Eng. J., 2021,422(15):129888-129897.
30. [30]
  Zhao H, Liu X, Dong Y M, Xia Y M, Wang H J. A Special Synthesis of BiOCl Photocatalyst for Efficient Pollutants Removal: New Insight into the Band Structure Regulation and Molecular Oxygen Activation[J]. Appl. Catal. B, 2019,256(5):117872-117881.
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