Citation: Feng-He ZHAO, Chong-Min ZHANG. Application of Monodisperse SiO₂ Nanoparticles Composite Gel Electrolytes[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 313-320. doi: 10.11862/CJIC.2022.040 shu

Application of Monodisperse SiO₂ Nanoparticles Composite Gel Electrolytes

Feng-He ZHAO ^1,, ,
Chong-Min ZHANG ²

1.
Qingdao Public Service Center for Small and Medium Enterprises, Qingdao, Shandong 266199, China
2.
Qingdao Puke Parting Materials Co. Ltd., Qingdao, Shandong 266112, China

Corresponding author: Feng-He ZHAO, work3857@163.com
Received Date: 25 August 2021
Revised Date: 13 December 2021

Figures(6)

In this work, the well-monodispersed SiO₂ nanoparticles (about 130 nm) were used as the filler while the polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP) was used as the polymer matrix. The monodisperse SiO₂ composite gel polymer electrolytes (MCGPEs) were prepared by a simple method and applied to lithium batteries. SiO₂ has better dispersion and uniformity in the polymer matrix. Compared with the conventional composite gel polymer electrolytes (GPEs) and commercial SiO₂ composite gel polymer electrolytes (CGPEs), MCGPEs exhibited the more excellent ability of liquid absorption and better lithium-ion migration ability. Moreover, the cells which used MCGPEs as electrolytes maintained a high specific capacity of 121.1 mAh·g^-1 after 300 cycles at 1.0C, showing a satisfactory cycle performance. Meanwhile, the rate performance of MCGPEs was also excellent. The cells using MCGPEs owned the specific capacity of 135 mAh·g^-1 at 10C which was higher than GPEs cells (76.2 mAh·g^-1).
- lithium-ion batteries,
- gel polymer electrolytes,
- SiO₂,
- nanoparticles
1. [1]
  Sui Y M, Liu C F, Masse R C, Neale Z G, Atif M, AlSalhi M, Cao G Z. Dual-Ion Batteries: The Emerging Alternative Rechargeable Batteries[J]. Energy Storage Mater., 2020,25:1-32.
2. [2]
  Costa , C M, Lee Y H, Kim J H, Lee S Y, Lanceros-Mendez S. Recent Advances on Separator Membranes for Lithium-Ion Battery Applications: From Porous Membranes to Solid Electrolytes[J]. Energy Storage Mater., 2019,22:346-375.
3. [3]
  Qian J F, Adams B D, Zheng J M, Xu W, Henderson W A, Wang J, Bowden M E, Xu S C, Hu J Z, Zhang J G. Anode-Free Rechargeable Lithium Metal Batteries[J]. Adv. Funct. Mater., 2016,26:7094-7102. doi: 10.1002/adfm.201602353
4. [4]
  Lin D, Liu Y, Cui Y. Reviving the Lithium Metal Anode for High-Energy Batteries[J]. Nat. Nanotechnol., 2017,12(3):194-206. doi: 10.1038/nnano.2017.16
5. [5]
  Ren W H, Ding C F, Fu X W, Huang Y. Advanced Gel Polymer Electrolytes for Safe and Durable Lithium Metal Batteries: Challenges, Strategies, and Perspectives[J]. Energy Storage Mater., 2020,34:515-535.
6. [6]
  Ghazi Z A, Sun Z, Sun C, Qi F, An B, Li F, Cheng H M. Key Aspects of Lithium Metal Anodes for Lithium Metal Batteries[J]. Small, 2019,15(35)e1900687. doi: 10.1002/smll.201900687
7. [7]
  Zhao Q, Stalin S, Zhao C Z, Archer L A. Designing Solid-State Electrolytes for Safe, Energy-Dense Batteries[J]. Nat. Rev. Mater., 2020,5(3):1-24. doi: 10.1038/s41578-019-0165-5
8. [8]
  Pahari D, Puravankara S. Greener, Safer, and Sustainable Batteries: An Insight into Aqueous Electrolytes for Sodium-Ion Batteries[J]. ACS Sustainable Chem. Eng., 2020,8(29):10613-10625. doi: 10.1021/acssuschemeng.0c02145
9. [9]
  Ding X, Huang X B, Jin J L, Ming H, Wang L M, Ming J. Advanced and Safer Lithium-Ion Battery Based on Sustainable Electrodes[J]. J. Power Sources, 2018,379:53-59. doi: 10.1016/j.jpowsour.2018.01.027
10. [10]
  Yuan M Q, Liu K. Rational Design on Separators and Liquid Electrolytes for Safer Lithium-Ion Batteries[J]. J. Energy Chem., 2020,43(4):70-82.
11. [11]
  Cheng X, Pan J, Zhao Y, Liao M, Peng H S. Gel Polymer Electrolytes for Electrochemical Energy Storage[J]. Adv. Energy Mater., 2018,81702184. doi: 10.1002/aenm.201702184
12. [12]
  Zhai Y Y, Wang X W, Chen Y F, Sang X, Liu H Q, Sheng J L, Wu Y Q, Wang X Y, Li L. Multiscale-Structured Polyvinylidene Fluoride/Polyacrylonitrile/Vermiculite Nanosheets Fibrous Membrane with Uniform Li⁺ Flux Distribution for Lithium Metal Battery[J]. J. Membr. Sci., 2021,621118996. doi: 10.1016/j.memsci.2020.118996
13. [13]
  BU A X, TAN Y, FANG R P, LI F, PEI S F, REN W C. A Graphene/PVDF/PP Multilayer Composite Separator for Long-Life and High Power Lithium-Ion batteries[J]. New Carbon Mater., 2017,32(1):63-70.
14. [14]
  Zhang K, Xu L L, Jiang J G, Calin N, Lam K F, Zhang S J, Wu H H, Wu G D, Albela B, Bonneviot L. Facile Large-Scale Synthesis of Monodisperse Mesoporous Silica Nanospheres with Tunable Pore Structure[J]. J. Am. Chem. Soc., 2013,135(7):2427-2430. doi: 10.1021/ja3116873
15. [15]
  Zhao H J, Deng N P, Kang W M, Li Z, Wang G, Cheng B W. Highly Multiscale Structural Poly(vinylidene fluoridehexafluoropropylene)/Poly-m-phenyleneisophthalamide Separator with Enhanced Interface Compatibility and Uniform Lithium-Ion Flux Distribution for Dendrite-Proof Lithium-Metal Batteries[J]. Energy Storage Mater., 2020,26:334-348. doi: 10.1016/j.ensm.2019.11.005
16. [16]
  Gao S, Wang K L, Wang R X, Jiang M, Han J, Gu T T, Cheng S J, Jiang K. Poly(vinylidene fluoride)-Based Hybrid Gel Polymer Electrolytes for Additive-Free Lithium Sulfur Batteries[J]. J. Mater. Chem. A, 2017,5(34):17889-17895. doi: 10.1039/C7TA05145J
17. [17]
  Bae J, Li Y, Zhang J, Zhou X, Zhao F, Shi Y, Goodenough J B, Yu G. A 3D Nanostructured Hydrogel-Framework-Derived High-Performance Composite Polymer Lithium-Ion Electrolyte[J]. Angew. Chem. Int. Ed., 2018,57(8):2096-2100.
18. [18]
  Zheng J X, Lu J, Amine K, Pan F. Depolarization Effect to Enhance the Performance of Lithium Ions Batteries[J]. Nano Energy, 2017,33:497-507.
19. [19]
  Zhao Y B, Bai Y, Bai Y P, An M Z, Chen G R, Li W D, Li C, Zhou Y F. A Rational Design of Solid Polymer Electrolyte with High Salt Concentration for Lithium Battery[J]. J. Power Sources, 2018,407:23-30. doi: 10.1016/j.jpowsour.2018.10.045
20. [20]
  Sannier L, Bouchet R, Rosso M, Tarascon J M. Evaluation of GPE Performances in Lithium Metal Battery Technology by Means of Simple Polarization Tests[J]. J. Power Sources, 2006,158(1):564-570. doi: 10.1016/j.jpowsour.2005.09.026
21. [21]
  Yan C, Xu R, Qin J L, Yuan H, Xiao Y, Xu L, Huang J Q. 4.5 V High-Voltage Rechargeable Batteries Enabled by the Reduction of Polarization on the Lithium Metal Anode[J]. Angew. Chem. Int. Ed., 2019,58(43):15164-15164.
22. [22]
  Kurc B, Jesionowski T. Modified TiO₂-SiO₂ Ceramic Filler for a Composite Gel Polymer Electrolytes Working with LiMn₂O₄[J]. J. Solid State Electrochem., 2015,19(5):1427-1435. doi: 10.1007/s10008-015-2762-6
23. [23]
  Zhu Y S, Yang Y Q, Fu L J, Wu Y P. A Porous Gel-Type Composite Membrane Reinforced by Nonwoven: Promising Polymer Electrolyte with High Performance for Sodium Ion Batteries[J]. Electrochim. Acta, 2017,224:405-411. doi: 10.1016/j.electacta.2016.12.030
24. [24]
  Qin H F, Fu K, Zhang Y, Ye Y H, Song M Y, Kuang Y D, Jang S H, Jiang F, Cui L F. Flexible Nanocellulose Enhanced Li⁺ Conducting Membrane for Solid Polymer Electrolyte[J]. Energy Storage Mater., 2020,28(6058):293-299. doi: 10.1016/j.ensm.2020.03.019
25. [25]
  Liao H, Chen H, Zhou F, Zhang Z. A Novel SiO₂ Nanofiber-Supported Organic-Inorganic Gel Polymer Electrolyte for Dendrite-Free Lithium Metal Batteries[J]. J. Mater. Sci., 2020,55(2018):9504-9515. doi: 10.1007/s10853-020-04634-2
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Application of Monodisperse SiO₂ Nanoparticles Composite Gel Electrolytes