Citation: An-Ran WU, Yan-Hui CHEN, Xin-Xin WANG, Wen-Yuan ZHOU, Jia-Wei HE, Jin-Shu WANG, Hong-Yi LI. Pt/TiO₂ Nanotubes Electrode: Preparation by Electroplating Method and Electrocatalytic Hydrogen Evolution Performance[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 227-236. doi: 10.11862/CJIC.2022.034 shu

Pt/TiO₂ Nanotubes Electrode: Preparation by Electroplating Method and Electrocatalytic Hydrogen Evolution Performance

Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China

Corresponding author: Hong-Yi LI, lhy06@bjut.edu.cn
Received Date: 1 April 2021
Revised Date: 14 December 2021

Figures(15)

Here, Pt modified anatase-type titanium dioxide (TiO₂) nanotube arrays were prepared by electroplating method for a low-platinum Pt/TiO₂ nanotubes electrode (Pt/TiO₂-NTs). By contrast, we fixed Pt on TiO₂ dense film by the same procedure as a control sample (Pt/TiO₂-F). The scanning electron microscopy and transmission electron microscopy observation showed that Pt nanoparticles were distributed uniformly in nanotube arrays, and Pt/TiO₂-NTs showed a higher efficiency in electrocatalytic hydrogen evolution compared with Pt/TiO₂-F and commercial Pt/C catalyst, in which the overpotential of Pt/TiO₂-NTs was 0.079 V, the Tafel slope was 42.7 mV·dec^-1 at 10 mA·cm^-2. The catalytic activity of 3 000 cycles duration stability test results showed that Pt/TiO₂-NTs exhibited excellent stability compared with the above contrast electrodes.
- TiO₂ nanotubes carrier,
- electroplating,
- platinum-based catalyst,
- electrocatalytic hydrogen evolution
1. [1]
  LU S Q, Zhuang Z B. Electrocatalysts for Hydrogen Oxidation and Evolution Reactions[J]. Sci. China Mater., 2016,59(3):217-238. doi: 10.1007/s40843-016-0127-9
2. [2]
  Barelli L, Bidini G, Gallorini F, Servili S. Hydrogen Production through Sorption-Enhanced Steam Methane Reforming and Membrane Technology: A Review[J]. Energy, 2008,33(4):554-570. doi: 10.1016/j.energy.2007.10.018
3. [3]
  Gong S Q, Jiang Z J, Shi P H, Fan J C, Xu Q J, Min Y L. Noble-Metal-Free Heterostructure for Efficient Hydrogen Evolution in Visible Region: Molybdenum Nitride/Ultrathin Graphitic Carbon Nitride[J]. Appl. Catal. B, 2018,238(15):318-327.
4. [4]
  Carmo M, Fritz D L, Mergel J, Stolten D. A Comprehensive Review on PEM Water Electrolysis[J]. Int. J. Hydrogen Energy, 2013,38(12):4901-4934. doi: 10.1016/j.ijhydene.2013.01.151
5. [5]
  Hong W T, Jian C Y, Wang G X, He X, Li J, Cai Q, Wen Z H, Liu W. Self-Supported Nanoporous Cobalt Phosphosulfate Electrodes for Efficient Hydrogen Evolution Reaction[J]. Appl. Catal. B, 2019,251(15):213-219.
6. [6]
  Seh Z W, Kibsgaard J, Dickens C F, Chorkendorff I B, Norskov J K, Jaramillo T F. Combining Theory and Experiment in Electrocatalysis: Insights into Materials Design[J]. Science, 2017,355(6321):4998-5012. doi: 10.1126/science.aad4998
7. [7]
  Li H Y, Wang J S, Liu M, Wang H, Su P L, Wu J S, Li J. A Nanoporous Oxide Interlayer Makes a Better Pt Catalyst on a Metallic Substrate: Nanoflowers on a Nanotube Bed[J]. Nano Res., 2014,7(7):1007-1017. doi: 10.1007/s12274-014-0464-5
8. [8]
  Haneda M, Watanabe T, Ozawa M. Characterization and Reactivity Analysis of Hydrogen Adspecies on Platinum Nano-Particles Supported on Alumina[J]. J. Jpn. Pet. Inst., 2012,55(3):191-196. doi: 10.1627/jpi.55.191
9. [9]
  Cherevko S, Topalov A A, Zeradjanin A R, Keeley G P, Mayrhofer K J J. Temperature-Dependent Dissolution of Polycrystalline Platinum in Sulfuric Acid Electrolyte[J]. Electrocatalysis, 2014,5(3):235-240. doi: 10.1007/s12678-014-0187-0
10. [10]
  Xing L Y, Hossain M A, Min T, Beauchemin D, Adjemian K T, Jerkiewicz G. Platinum Electro-Dissolution in Acidic Media upon Potential Cycling[J]. Electrocatalysis, 2014,5(1):96-112. doi: 10.1007/s12678-013-0167-9
11. [11]
  Dong G F, Fang M, Wang H T, Yip S P, Cheung H Y, Wang F Y, Wong C Y, Chu S T, Ho J C. Insight into the Electrochemical Activation of Carbon-Based Cathodes for Hydrogen Evolution Reaction[J]. J. Mater. Chem. A, 2015,3(24):13080-13086. doi: 10.1039/C5TA02551F
12. [12]
  Li J, Liu H Y, Lu Y, Guo X W, Song Y J. Influence of Counter Electrode Material during Accelerated Durability Test of Non-precious Metal Electrocatalysts in Acidic Medium[J]. Chin. J. Catal., 2016,37(7):1109-1118. doi: 10.1016/S1872-2067(16)62454-3
13. [13]
  Fang Y Y, Hsieh Y C, Lin C W. Electroplating of Nanostructured Pt, Ir and Pt-Ir at Room Temperature[J]. J. Electrochem. Soc., 2012,159(9):D518-D520. doi: 10.1149/2.003209jes
14. [14]
  Tachibana T, Yokota Y, Hayashi K, Kobashi K. Growth of {111}-Oriented Diamond on Pt/Ir/Pt Substrate Deposited on Sapphire[J]. Diamond Relat. Mater., 2001,10(9/10):1633-1636.
15. [15]
  Cheng X, Li Y, Zheng L, Yan Y, Zhang Y F, Chen G, Sun S R, Zhang J J. Highly Active, Stable Oxidized Platinum Clusters as Electrocatalysts for the Hydrogen Evolution Reaction[J]. Energy Environ. Sci., 2017,10(11):2450-2458. doi: 10.1039/C7EE02537H
16. [16]
  Cheng H, Wang G, Parrondo J, Sankarasubramanian S, Ramani V. Pt/RuO₂-TiO₂ Electrocatalysts Exhibit Excellent Hydrogen Evolution Activity in Alkaline Media[J]. J. Electrochem. Soc., 2017,164(12):F1234-F1240. doi: 10.1149/2.1661712jes
17. [17]
  Anitha V C, Raul Z, Milos K, Yoo J E, Sopha H, Prikryl J, Cha G, Slang S, Schmuki P, Macak J M. Anodic TiO₂ Nanotubes Decorated by Pt Nanoparticles Using ALD: An Efficient Electrocatalyst for Methanol Oxidation[J]. J. Catal., 2018,365:86-93. doi: 10.1016/j.jcat.2018.06.017
18. [18]
  Cheshideh H, Nasirpouri F. Cyclic Voltammetry Deposition of Nickel Nanoparticles on TiO₂ Nanotubes and Their Enhanced Properties for Electro-Oxidation of Methanol[J]. J. Electroanal. Chem., 2017,797:121-133. doi: 10.1016/j.jelechem.2017.05.024
19. [19]
  Yoo J E, Zazpe R, Cha G, Prikryl J, Hwang I, Macak J M, Schmuki P. Uniform ALD Deposition of Pt Nanoparticles within 1D Anodic TiO₂ Nanotubes for Photocatalytic H₂ Generation[J]. Electrochem. Commun., 2018,86:6-11.
20. [20]
  Lv L W, Liu Y S, Zhang P, Zhang X, Liu J, Chen T, Su P L, Li H Y, Zhou Y S. The Nanoscale Geometry of TiO₂ Nanotubes Influences the Osteogenic Differentiation of Human Adipose-Derived Stem Cells by Modulating H₃K₄ Trimethylation[J]. Biomaterials, 2015,39:193-205. doi: 10.1016/j.biomaterials.2014.11.002
21. [21]
  Jiao P, Li H Y, Zu G N, Zu G N, Li P P, Wu J S, Wang J S. Tribological Properties of MoS₂ Nanosheets Solid Lubricant Planted on TiO₂ Nanotube Array Bed[J]. Tribol. Int., 2018,125:12-16. doi: 10.1016/j.triboint.2018.04.008
22. [22]
  Ozkan S, Yoo J E, Nguyen N T, Nguyen N T, Mohajernia S, Zazpe R, Prikryl J, Macak J M, Schmuki P. Spaced TiO₂ Nanotubes Enable Optimized Pt Atomic Layer Deposition for Efficient Photocatalytic H₂ Generation[J]. Chemistryopen, 2018,7(10):797-802. doi: 10.1002/open.201800172
23. [23]
  Li H Y, Liu S J, Wang X X, Zu G N, Li D D, Wang J S. Platinum Nano-Flowers with Controlled Facet Planted in Titanium Dioxide Nanotube Arrays Bed and Their High Electro-catalytic Activity[J]. Sustainable Mater. Technol., 2019,20:93-101.
24. [24]
  Zu G N, Li H Y, Jiao P, Li P P, Wang X X, Wang J S. Effect of TiO₂ Nanotube Arrays Morphology/Structure on Photocatalytic Hydrogen Production[J]. J. Nanosci. Nanotechnol., 2020,20(2):852-857. doi: 10.1166/jnn.2020.16945
25. [25]
  Li B S, Anwer S, Huang X H, Luo S H, Fu J, Liao K. Nitrogen-Doped Carbon Encapsulated in Mesoporous TiO₂ Nanotubes for Fast Capacitive Sodium Storage[J]. J. Energy Chem., 2021,55:202-210. doi: 10.1016/j.jechem.2020.06.074
26. [26]
  Zu G N, Li H Y, Liu S J, Li D D, Wang J S, Zhao J L. Highly Efficient Mass Determination of TiO₂ Nanotube Arrays and Its Application in Lithium-Ion Batteries[J]. Sustainable Mater. Technol., 2018,18:79-86.
27. [27]
  Parkinson C R, Walker M, Mcconville C F. Reaction of Atomic Oxygen with a Pt(111) Surface: Chemical and Structural Determination Using XPS, CAICISS and LEED[J]. Surf. Sci., 2003,545:19-33. doi: 10.1016/j.susc.2003.08.029
28. [28]
  Xu G Q, Liu H P, Wang J W, Lv J, Zheng Z X, Wu Y C. Photoelectrochemical Performances and Potential Applications of TiO₂ Nano-tube Arrays Modified with Ag and Pt Nanoparticles[J]. Electrochim. Acta, 2014,121:194-202. doi: 10.1016/j.electacta.2013.12.154
29. [29]
  Su Y, Deng Y. Effect of Structure on the Photocatalytic Activity of Pt-Doped TiO₂ Nanotubes[J]. Appl. Surf. Sci., 2011,257(23):9791-9795. doi: 10.1016/j.apsusc.2011.05.133
1. [1]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
4. [4]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
5. [5]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
6. [6]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
7. [7]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
8. [8]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
9. [9]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
10. [10]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
11. [11]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
12. [12]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
13. [13]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
14. [14]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
15. [15]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
16. [16]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
17. [17]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
18. [18]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
19. [19]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
20. [20]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317

Get Citation

PDF

XML

Metrics

PDF Downloads(29)
Abstract views(1853)
HTML views(614)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Pt/TiO2 Nanotubes Electrode: Preparation by Electroplating Method and Electrocatalytic Hydrogen Evolution Performance

Metrics

通讯作者: 陈斌, bchen63@163.com

Pt/TiO₂ Nanotubes Electrode: Preparation by Electroplating Method and Electrocatalytic Hydrogen Evolution Performance