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Citation: Le-Heng HUANG, Gao CHENG, Ying-Xia ZHAO, Qi-Xing XIE, Yue SUN, Shi-Chang TANG, Ming SUN, Lin YU. Crystalline Form Controlled Synthesis of MnO2 Nanoarrays for Electrocatalytic Oxygen Evolution Performance[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 333-343. doi: 10.11862/CJIC.2022.030 shu

Crystalline Form Controlled Synthesis of MnO2 Nanoarrays for Electrocatalytic Oxygen Evolution Performance

  • 1.

    Key Laboratory of Clean Chemistry Technology of Guangdong Regular Higher Education, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

  • 2.

    Guangdong Key Laboratory of Plant Resources Biorefining, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

  • 3.

    Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

  • Corresponding author: Lin YU, gych@gdut.edu.cn
  • Received Date: 29 August 2021
    Revised Date: 7 December 2021

Figures(8)

  • Two kinds of MnO2 nanoarrays, including α-MnO2 nanowires and δ-MnO2 nanosheets, were synthesized on carbon fiber paper (CFP) via the one-step hydrothermal method by changing the temperature and the addition of sulfuric acid, respectively. Moreover, the oxygen evolution reaction (OER) properties for the MnO2 nanoarrays were studied. The results showed that the performance of α-MnO2 nanowires outperformed δ-MnO2 nanosheets in alkaline medium and the overpotential of α-MnO2 was 444 mV under 10 mA·cm-2 current density (the overpotential of δ-MnO2 was 522 mV). According to the analysis of X-ray photoelectron spectroscopy, the higher content of Mn3+ and more abundant oxygen vacancies on the surface are the reasons for the higher catalytic activity of α-MnO2 nanowires.
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