Citation: Jing YU, Ting ZHANG, Qi LIU, Jing-Yuan LIU, Jun WANG. Preparation of Nitrogen-Doped Carbon Fiber Supported Nickel-Cobalt Selenides for Electrocatalytic Hydrogen Evolution Performance[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(1): 63-72. doi: 10.11862/CJIC.2022.021 shu

Preparation of Nitrogen-Doped Carbon Fiber Supported Nickel-Cobalt Selenides for Electrocatalytic Hydrogen Evolution Performance

  • Corresponding author: Jing YU, jing.yu@hrbeu.edu.cn
  • Received Date: 5 July 2021
    Revised Date: 16 November 2021

Figures(10)

  • Nitrogen-doped carbon fiber (NCF) loaded bimetal selenide nanoparticle material ((Ni, Co)Se2/NCF) was synthesized by calcination and selenium treatment using electrospun fibers as the precursor. A series of related characterization was carried out, and the hydrogen evolution properties of the materials were studied under acidic and alkaline conditions. (Ni, Co)Se2 nanoparticles were anchored in NCF, which effectively prevents the aggregation of nanoparticles and provides more catalytic active sites. The electrocatalytic hydrogen evolution test results showed that in 1 mol·L-1 KOH solution, the overpotential of (Ni, Co)Se2/NCF was 123.3 mV at the current density of 10 mA·cm-2, and the Tafel slope was 144.0 mV·dec-1. In 0.5 mol·L-1 H2SO4 solution, the overpotential of hydrogen evolution required for (Ni, Co)Se2/NCF to reach the current density of 10 mA·cm-2 was 95.5 mV, and the Tafel slope was 115.2 mV·dec-1, indicating excellent electrocatalytic hydrogen evolution performance.
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