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Citation: Xiao-Qing WANG, Xue-Hui MA, Dou-Dou FENG, Jing TANG, Dan WU. Synthesis of a Water-Stable Zn(Ⅱ)-Based Metal-Organic Framework for Luminescence Detecting Fe3+ and 2, 6-Dichloro-4-nitroaniline[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(1): 137-144. doi: 10.11862/CJIC.2022.015 shu

Synthesis of a Water-Stable Zn(Ⅱ)-Based Metal-Organic Framework for Luminescence Detecting Fe3+ and 2, 6-Dichloro-4-nitroaniline

  • Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China

  • Corresponding author: Xiao-Qing WANG, xqwang@nuc.edu.cn
  • Received Date: 24 May 2021
    Revised Date: 21 October 2021

Figures(6)

  • A novel thermal-stable and water-stable Zn(Ⅱ)-based metal-organic framework (MOF), [Zn2(bcpp)2(1, 4bib)2]·1.5H2O (1) was synthesized by solvothermal method based on 3, 5-bis(4-carboxylphenoxy)pyridine (H2bcpp) and 1, 4 - bis(1 - imidazoly)benzene (1, 4 - bib). Complex 1 belongs to the monoclinic system with space group I2/a, which exhibits a 1D tubular structure. The adjacent 1D tubular structures are interpenetrated with each other to obtain a 3D supramolecular structure. Moreover, complex 1 exhibits excellent photoluminescence property, which can be applied as a"turn-off"fluorescence probe to detect Fe3+ ion and pesticide 2, 6-dichloro-4-nitroaniline in an aqueous solution with high selectivity and sensitivity.
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