Citation: Fu-Sheng BIE, Ai-Shan REN, Hua-Qin XU, Jin-Hu WANG, Xue-Jing LIU, Dong-Jian ZHU. Fluorescent Probe Based on Carbazole-N, S-Heterocrown Ether: Synthesis and Properties of Ag⁺ Detection[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 237-243. doi: 10.11862/CJIC.2022.013 shu

Fluorescent Probe Based on Carbazole-N, S-Heterocrown Ether: Synthesis and Properties of Ag⁺ Detection

1.
Engineering and Technology Institute of LuNan Coal Chemical Engineering, Zaozhuang University, Zaozhuang, Shandong 277160, China
2.
College of Food and Bioengineering, Hezhou University, Hezhou, Guangxi 542899, China

Corresponding author: Fu-Sheng BIE, fsbie@uzz.edu.cn Dong-Jian ZHU, zhdj1983@126.com
Received Date: 10 July 2021
Revised Date: 19 October 2021

Figures(6)

A new fluorescent probe L containing heterocrown ether group was designed and synthesized from t-butyl bis(2-chloroethyl)carbamate, 2, 2'-(ethane-1, 2-diylbis(oxy))diethanethiol, and N-ethyl carbazole. The structure of L was characterized by ¹H NMR, ¹³C NMR, and high-resolution mass spectrometry. The selectivity of probe L with Ag⁺ was investigated by fluorescence spectroscopy in water/ethanol solvent (4:1, V/V). All the results showed that the binding ratio for probe L to Ag⁺ was 1:1. The binding constant K_a was calculated to be 2.01×10⁵ L·mol^-1 and the detection limit was 4.13 μmol·L^-1. The results also showed that probe L could be used to detection of Ag⁺ in the river and other environmental water samples.
- carbazole,
- heterocrown ether,
- fluorescent probe,
- silver ion
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fluorescent Probe Based on Carbazole-N, S-Heterocrown Ether: Synthesis and Properties of Ag+ Detection

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通讯作者: 陈斌, bchen63@163.com

Fluorescent Probe Based on Carbazole-N, S-Heterocrown Ether: Synthesis and Properties of Ag⁺ Detection