Citation: Wei-Pu DING, Jian-Da LI, Shu-Wen CHEN, Xiang-Guo LI, Qing WANG, Ai-Yong HE, Jing-Zhou YIN. Attapulgite/g-C₃N₄-Pt/Polyaniline Composites: Preparation and Visible Light Photocatalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 253-260. doi: 10.11862/CJIC.2022.011 shu

Attapulgite/g-C₃N₄-Pt/Polyaniline Composites: Preparation and Visible Light Photocatalytic Properties

Wei-Pu DING ^{1, 2, #} ,
Jian-Da LI ^{1, #} ,
Shu-Wen CHEN ¹ ,
Xiang-Guo LI ¹ ,
Qing WANG ¹ ,
Ai-Yong HE ¹ ,
Jing-Zhou YIN ^1,,

1.
Jiangsu Key Laboratory for Low-Dimension Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian, Jiangsu 223300, China
2.
School of Environment, Hohai University, Nanjing 210098, China

Corresponding author: Jing-Zhou YIN, jingzhouyin@hytc.edu.cn
Received Date: 19 July 2021
Revised Date: 7 November 2021

Figures(9)

Graphitic carbon nitride (g-C₃N₄), an n-type semiconductor with a narrow bandgap of 2.7 eV, has been widely studied as a visible light-driven photocatalyst for organic pollutant degradation, while attapulgite exhibits strong surface activity and adsorption capacity and can be used as support for catalysts. Herein, the hybrid material of graphite phase carbon nitride and attapulgite (ATP/g-C₃N₄) were chosen as the basis of polyaniline (PANI), and ATP/g-C₃N₄-Pt/PANI was successfully prepared by depositing Pt nanoparticles onto the surface of ATP/g-C₃N₄ via a simple reduction reaction, followed by the polymerization of aniline on the surface or into the channels of ATP/g-C₃N₄-Pt using Pt nanoparticles as a catalyst in acid solution. Methyl orange (MO), a kind of anionic dye, was used as the model system to investigate the visible light photocatalytic activity of the obtained products. The results showed that conjugated structures of PANI and g-C₃N₄ were well maintained in the hybrid, implying good compatibility. The photocatalyst showed remarkable visible-light photoactivity because of the synergistic effect between multicomponent materials. The degradation rate of 20 mg·L^-1 MO solution was achieved to 96.3% within 80 min by using ATP/g-C₃N₄-Pt/PANI as the photocatalyst, and it remained at 93.5% after five cycles.
- graphitic carbon nitride,
- attapulgite,
- nano platinum,
- polyaniline,
- visible light photocatalysis
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Attapulgite/g-C₃N₄-Pt/Polyaniline Composites: Preparation and Visible Light Photocatalytic Properties