Advanced Search

Citation: Jing HUANG, Xin-Yu TIAN, Lan YANG, Xiao-Miao FENG. Mn-MOF Derived Mn2O3 Micromotors Applied to Removal of Methyl Blue in Water[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(1): 153-160. doi: 10.11862/CJIC.2022.008 shu

Mn-MOF Derived Mn2O3 Micromotors Applied to Removal of Methyl Blue in Water

  • Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials(IAM), School of Materials Science & Engineering, Nanjing University of Posts & Telecommunications, Nanjing 210023, China

  • Corresponding author: Xiao-Miao FENG, iamxmfeng@njupt.edu.cn
  • Received Date: 9 July 2021
    Revised Date: 28 September 2021

Figures(6)

  • A Mn-based metal-organic framework (Mn-MOF) was selected as the precursors to prepare the Mn-MOF derivative (Mn2O3) microspheres. The Mn2O3 microspheres had a homogenous size of ca. 4 μm, with perfect sphere morphology, rough surface, good crystallinity and high yield. At the same time, the movement behavior of Mn2O3 micromotors under different conditions and the degradation properties of methyl blue (MB) were studied. As-prepared Mn2O3 micromotors had excellent autonomous movement ability, and their moving speed can reach 81.32 μm·s-1 in 10% H2O2 solution. Experimental results show that with the addition of H2O2, the Mn2O3 micromotors can effectively remove MB through degradation within 5 min.
  • 加载中
    1. [1]

      Guix M, Weiz S M, Schmidt O G, Medina-Sánchez M. Self-Propelled Micro/Nanoparticle Motors[J]. Part. Part. Syst. Charact., 2018,35(2)1700382. doi: 10.1002/ppsc.201700382

    2. [2]

      Wang Q L, Dong R F, Yang Q X, Wang J J, Xu S Y, Cai Y P. Highly Efficient Visible-Light-Driven Oxygen-Vacancy-Based Cu2+1O Micromotors with Biocompatible Fuels[J]. Nanoscale Horiz., 2020,5(2):325-330. doi: 10.1039/C9NH00592G

    3. [3]

      Cai L J, Wang H, Yu Y R, Bian F K, Wang Y, Shi K Q, Ye F F, Zhao Y J. Stomatocyte Structural Color Barcode Micromotors for Multiplex Assays[J]. Natl. Sci. Rev., 2020,7(3):644-651. doi: 10.1093/nsr/nwz185

    4. [4]

      Wang D L, Gao C Y, Wang W, Sun M M, Guo B, Xie H, He Q. Shape-Transformable, Fusible Rodlike Swimming Liquid Metal Nanomachine[J]. ACS Nano, 2018,12(10):10212-10220. doi: 10.1021/acsnano.8b05203

    5. [5]

      Yoshizumi Y, Honegger T, Berton K, Suzuki H, Peyrade D. Trajectory Control of Self - Propelled Micromotors Using AC Electrokinetics[J]. Small, 2015,11(42):5630-5635. doi: 10.1002/smll.201501557

    6. [6]

      Wang H, Liang Y L, Gao W, Dong R F, Wang C Y. Emulsion Hydrogel Soft Motor Actuated by Thermal Stimulation[J]. ACS Appl. Mater. Interfaces, 2017,9(49):43211-43219. doi: 10.1021/acsami.7b08661

    7. [7]

      Liu W J, Ge H B, Ding X Y, Lu X L, Zhang Y N, Gu Z W. Cubic Nano -Silver-Decorated Manganese Dioxide Micromotors: Enhanced Propulsion and Antibacterial Performance[J]. Nanoscale, 2020,12(38):19655-19664. doi: 10.1039/D0NR06281B

    8. [8]

      Schattling P S, Ramos - Docampo M A, Salgueiriño V, Städler B. Double - Fueled Janus Swimmers with Magnetotactic Behavior[J]. ACS Nano, 2017,11(4):3973-3983. doi: 10.1021/acsnano.7b00441

    9. [9]

      Maria-Hormigos R, Jurado-Sánchez B, Escarpa A. Surfactant-Free β-Galactosidase Micromotors for "On - The - Move" Lactose Hydrolysis[J]. Adv. Funct. Mater., 2018,28(25)1704256. doi: 10.1002/adfm.201704256

    10. [10]

      Ma X, Hortelao A C, Miguel - López A, Sánchez S. Bubble - Free Propulsion of Ultrasmall Tubular Nanojets Powered by Biocatalytic Reactions[J]. J. Am. Chem. Soc., 2016,138(42):13782-13785. doi: 10.1021/jacs.6b06857

    11. [11]

      Ma X, Jang S, Popescu M N, Uspal W E, Miguel-Lopez A, Hahn K, Kim D P, Sánchez S. Reversed Janus Micro/Nanomotors with Internal Chemical Engine[J]. ACS Nano, 2016,10(9):8751-8759. doi: 10.1021/acsnano.6b04358

    12. [12]

      Moo J G S, Wang H, Pumera M. Influence of pH on the Motion of Catalytic Janus Particles and Tubular Bubble - Propelled Micromotors[J]. Chem. Eur. J., 2016,22(1):355-360. doi: 10.1002/chem.201503473

    13. [13]

      Wei X L, Beltrán-Gastélum M, Karshalev E, de Ávila B E F, Zhou J R, Ran D N, Angsantikul P, Fang R H, Wang J, Zhang L F. Biomimetic Micromotor Enables Active Delivery of Antigens for Oral Vaccination[J]. Nano Lett., 2019,19(3):1914-1921. doi: 10.1021/acs.nanolett.8b05051

    14. [14]

      Zhou M F, Hou T, Li J X, Yu S S, Xu Z J, Yin M, Wang J, Wang X L. Self-Propelled and Targeted Drug Delivery of Poly(aspartic acid)/Iron-Zinc Microrocket in the Stomach[J]. ACS Nano, 2019,13(2)1324.

    15. [15]

      Chen B R, Sun W H, Kitchaev D A, Mangum J S, Thampy V, Garten L M, Ginley D S, Gorman B P, Stone K H, Ceder G, Toney M F, Schelhas L T. Understanding Crystallization Pathways Leading to Manganese Oxide Polymorph Formation[J]. Nat. Commun., 2018,92553. doi: 10.1038/s41467-018-04917-y

    16. [16]

      Peng X, Zhu H L, Chen H J, Feng X M, Liu R Q, Huang Z D, Shen Q M, Ma Y W, Wang L H. Eco-Friendly Porous Iron(Ⅲ) Oxide Micromotors for Efficient Wastewater Cleaning[J]. New J. Chem., 2019,43(32):12594-12600. doi: 10.1039/C9NJ02592H

    17. [17]

      Keller S, Teora S P, Hu G X, Nijemeisland M, Wilson D A. High-Throughput Design of Biocompatible Enzyme-Based Hydrogel Microparticles with Autonomous Movement[J]. Angew. Chem. Int. Ed., 2018,57(31):9814-9817. doi: 10.1002/anie.201805661

    18. [18]

      Novotný F, Plutnar J, Pumera M. Plasmonic Self-Propelled Nanomotors for Explosives Detection via Solution -Based Surface Enhanced Raman Scattering[J]. Adv. Funct. Mater., 2019,29(33)1903041. doi: 10.1002/adfm.201903041

    19. [19]

      Wang D L, Gao C Y, Zhou C, Lin Z H, He Q. Leukocyte MembraneCoated Liquid Metal Nanoswimmers for Actively Targeted Delivery and Synergistic Chemophotothermal Therapy. Research, 2020: UNSP 3676954

    20. [20]

      Jurado-Sánchez B, Wang J. Micromotors for Environmental Applications: A Review[J]. Environ. Sci.-Nano, 2018,5(7):1530-1544. doi: 10.1039/C8EN00299A

    21. [21]

      Li J X, Gao W, Dong R F, Pei A, Sattayasamitsathit S, Wang J. Nanomotor Lithography[J]. Nat. Commun., 2014,55026. doi: 10.1038/ncomms6026

    22. [22]

      Neoh C H, Noor Z Z, Mutamim N S A, Lim C K. Green Technology in Wastewater Treatment Technologies: Integration of Membrane Bioreactor with Various Wastewater Treatment Systems[J]. Chem. Eng. J., 2016,283:582-594. doi: 10.1016/j.cej.2015.07.060

    23. [23]

      Liang C Y, Zhan C, Zeng F Y, Xu D D, Wang Y, Zhao W W, Zhang J H, Guo J H, Feng H H, Ma X. Bilayer Tubular Micromotors for Simultaneous Environmental Monitoring and Remediation[J]. ACS Appl. Mater. Interfaces, 2018,10(41):35099-35107. doi: 10.1021/acsami.8b10921

    24. [24]

      Ma W, Wang K, Pan S H, Wang H. Iron-Exchanged Zeolite Micromotors for Enhanced Degradation of Organic Pollutants[J]. Langmuir, 2020,36(25):6924-6929. doi: 10.1021/acs.langmuir.9b02137

    25. [25]

      Shi H Q, Chen X, Liu K, Ding X Y, Liu W J, Xu M L. Heterogeneous Fenton Ferroferric Oxide-Reduced Graphene Oxide-Based Composite Microjets for Efficient Organic Dye Degradation[J]. J. Colloid Interface Sci., 2020,572:39-47. doi: 10.1016/j.jcis.2020.03.073

    26. [26]

      Mou F Z, Pan D, Chen C R, Gao Y R, Xu L L, Guan J G. Magnetically Modulated Pot - like MnFe2O4 Micromotors: Nanoparticle Assembly Fabrication and Their Capability for Direct Oil Removal[J]. Adv. Funct. Mater., 2015,25(39):6173-6181. doi: 10.1002/adfm.201502835

    27. [27]

      Baptista - Pires L, Orozco J, Guardia P, Merkoçi A. Architecting Graphene Oxide Rolled - Up Micromotors: A Simple Paper - Based Manufacturing Technology[J]. Small, 2018,14(3)1702746. doi: 10.1002/smll.201702746

    28. [28]

      Villa K, Parmar J, Vilela D, Sanchez S. Metal-Oxide-Based Microjets for the Simultaneous Removal of Organic Pollutants and Heavy Metals[J]. ACS Appl. Mater. Interfaces, 2018,10(24):20478-20486. doi: 10.1021/acsami.8b04353

    29. [29]

      Hou T, Yu S, Zhou M F, Wu M, Liu J, Zheng X L, Li J X, Wang J, Wang X L. Effective Removal of Inorganic and Organic Heavy Metal Pollutants with Poly(amino acid) - Based Micromotors[J]. Nanoscale, 2020,12(8):5227-5232. doi: 10.1039/C9NR09813E

    30. [30]

      Khezri B, Pumera M. Metal-Organic Frameworks Based Nano/Micro/Millimeter-Sized Self-Propelled Autonomous Machines[J]. Adv. Mater., 2019,31(14)e1806530. doi: 10.1002/adma.201806530

    31. [31]

      Ikezoe Y, Washino G, Uemura T, Kitagawa S, Matsui H. Autonomous Motors of a Metal-Organic Framework Powered by Reorganization of Self-Assembled Peptides at Interfaces[J]. Nat. Mater., 2012,11:1081-1085. doi: 10.1038/nmat3461

    32. [32]

      Chen H J, Zhu H L, Huang J, Feng X M. Shape-Controlled Catalytic ZIF - 67 Micromotors for Dye Adsorption[J]. J. Mater. Eng. Perform., 2020,29:6196-6200. doi: 10.1007/s11665-020-05091-3

    33. [33]

      Zhang H J, Qi S D, Niu X Y, Hu J, Ren C L, Chen H L, Chen X G. Metallic Nanoparticles Immobilized in Magnetic Metal - Organic Frameworks: Preparation and Application as Highly Active, Magnetically Isolable and Reusable Catalysts[J]. Catal. Sci. Technol., 2014,4(9):3013-3024. doi: 10.1039/C4CY00072B

    34. [34]

      Zou G Q, Hou H S, Cao X Y, Ge P, Zhao G G, Yin D L, Ji X B. 3D Hollow Porous Carbon Microspheres Derived from Mn - MOFs and Their Electrochemical Behavior for Sodium Storage[J]. J. Mater. Chem. A, 2017,5(45):23550-23558. doi: 10.1039/C7TA08352A

    35. [35]

      Zhang X D, Lv X T, Bi F K, Lu G, Wang Y X. Highly Efficient Mn2O3 Catalysts Derived from Mn-MOFs for Toluene Oxidation: The Influence of MOFs Precursors[J]. Mol. Catal., 2020,482110701. doi: 10.1016/j.mcat.2019.110701

    36. [36]

      Cao H Q, Wu X M, Wang G H, Yin J F, Yin G, Zhang F, Liu J K. Biomineralization Strategy to α-Mn2O3 Hierarchical Nanostructures[J]. J. Phys. Chem. C, 2012,116(39):21109-21115. doi: 10.1021/jp306984c

    37. [37]

      Yao Y Y, Cai Y M, Lu F, Wei F Y, Wang X Y, Wang S B. Magnetic Recoverable MnFe2O4 and MnFe2O4-Graphene Hybrid as Heterogeneous Catalysts of Peroxymonosulfate Activation for Efficient Degradation of Aqueous Organic Pollutants[J]. J. Hazard. Mater., 2014,270:61-70. doi: 10.1016/j.jhazmat.2014.01.027

    38. [38]

      Yang W N, Li J, Xu Z P, Yang J, Liu Y, Liu L H. An Eu-MOF/EDTA - NiAl - CLDH Fluorescent Micromotor for Sensing and Removal of Fe3+ From Water[J]. J. Mater. Chem. C, 2019,7(33):10297-10308. doi: 10.1039/C9TC03328A

    39. [39]

      Wang R Q, Guo W L, Li X H, Liu Z H, Liu H, Ding S Y. Highly Efficient MOF-Based Self-Propelled Micromotors for Water Purification[J]. RSC Adv., 2017,7(67):42462-42467. doi: 10.1039/C7RA08127H

  • 加载中
    1. [1]

      Ruru MA , Yingjie SONG , Yahui LI , Ermin ZHOU , Deqiang LI , Xiaojuan HUANG , Jun LI . Synergistic nitrogen doping and carbon support in TiO2 for enhanced photocatalytic degradation of methylene blue and oxytetracycline. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 641-656. doi: 10.11862/CJIC.20250221

    2. [2]

      Fei ZHOU , Xiaolin JIA . Co3O4/TiO2 composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236

    3. [3]

      Bairui Zeng , Zhixiang Mu , Tianxi Shen , Xiaoliang Qi , Yuanqi Chen , Kezheng Lei , Chen Huang , Yi Wang , Rongdang Hu , Xiaojun Cai , Jianliang Shen , Hui Deng . A self-propelled nanovesicle with robust antibacterial and regeneration-promoting capabilities for treating biofilm-induced periodontitis. Chinese Chemical Letters, 2025, 36(6): 110350-. doi: 10.1016/j.cclet.2024.110350

    4. [4]

      Jia Wang , Yunxiu Fan , Shilin Xu , Zhouxue Wu , Tian Hu , Yun Lu , Yue Li , Kang Xiong , Hongjun Deng , Jingrong Huang , Bo Yang , Shaozhi Fu . Self-propelled biomotors co-deliver doxorubicin liposomes and aPD-1 antibody to fight breast cancer. Chinese Chemical Letters, 2026, 37(2): 111607-. doi: 10.1016/j.cclet.2025.111607

    5. [5]

      Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO2 nanotube array modified Ti-based Ni-Sb co-doped SnO2 anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262

    6. [6]

      Limin ZHANG , Renqiang TANG , Yifan ZHENG , Hongtao CHENG , Qian WANG , Junfeng BAI . A (3,6)-c [Fe3(μ3-O)(acetate)2(carboxyl)4(pyridyl)2] cluster-based metal-organic framework with methyl-impendent gourd-shaped pores for natural gas purification. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1412-1419. doi: 10.11862/CJIC.20260131

    7. [7]

      Fengrui Yang , Debing Wang , Xinying Zhang , Jie Zhang , Zhichao Wu , Qiaoying Wang . Synergistic effects of peroxydisulfate on UV/O3 process for tetracycline degradation: Mechanism and pathways. Chinese Chemical Letters, 2024, 35(10): 109599-. doi: 10.1016/j.cclet.2024.109599

    8. [8]

      Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe3O4. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771

    9. [9]

      Ning Liu , Man Tian , Ye Zhang , Jinming Yang , Zhihao Wang , Wangxi Dai , Guixiang Quan , Jianqiu Lei , Xiaodong Zhang , Liang Tang . Three-dimensional MIL-88A(Fe)-derived α-Fe2O3 and graphene composite for efficient photo-Fenton-like degradation of ciprofloxacin. Chinese Chemical Letters, 2025, 36(12): 111063-. doi: 10.1016/j.cclet.2025.111063

    10. [10]

      Aoyun Meng ,  Zhenhua Li ,  Guoyuan Xiong ,  Zhen Li ,  Jinfeng Zhang . Rapid and stable degradation of dichlorvos on chili pepper and histamine in sardines using S-scheme Al6Si2O13/g-C3N4 nanocomposites. Chinese Journal of Structural Chemistry, 2026, 45(5): 100867-100867. doi: 10.1016/j.cjsc.2026.100867

    11. [11]

      Qi HUANG , Youyi WANG , Zhujian MAO , Zhonghui YE , Weihan CHEN , Jui-yeh RAU , Jian HUANG . Enhanced photocatalytic tetracycline degradation via 2D CdS/Ti3AlC2 MAX heterostructure. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2385-2398. doi: 10.11862/CJIC.20250159

    12. [12]

      Xinlong Zheng , Zhongyun Shao , Jiaxin Lin , Qizhi Gao , Zongxian Ma , Yiming Song , Zhen Chen , Xiaodong Shi , Jing Li , Weifeng Liu , Xinlong Tian , Yuhao Liu . Recent advances of CuSbS2 and CuPbSbS3 as photocatalyst in the application of photocatalytic hydrogen evolution and degradation. Chinese Chemical Letters, 2025, 36(3): 110533-. doi: 10.1016/j.cclet.2024.110533

    13. [13]

      Shuang Zhao , Fei Jia , Kaibei Zhan , Rui-Xi Wang , Pengfei Tan , Lin Shen , Li-Ming Wu , Ling Chen . Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A2(H3C3N4S2)2•H2O (A =NH4, K, Rb, Cs). Chinese Chemical Letters, 2026, 37(3): 110625-. doi: 10.1016/j.cclet.2024.110625

    14. [14]

      Xiao-qiang Cao , Xingyao Liu , Yaqi Wang , Haining Wang , Bo Wei , Yanan Shang , Yizhen Zhang , Yujiao Kan , Yang Zhang , Xing Xu , Longlong Zhang . Surface oxygen vacancy trigger peroxymonosulfate activation with cobalt modified montmorillonite for ofloxacin degradation: The synergistic effect of 1O2 and Co(Ⅳ)=O. Chinese Chemical Letters, 2026, 37(6): 112112-. doi: 10.1016/j.cclet.2025.112112

    15. [15]

      Zhiling Du , Zhiqi Zhou , Nan Sun , Cailiang Yue , Fuqiang Liu . Pyromellitic diimide induced TiO2 mesocrystals with oxygen vacancies for synergistic photocatalytic H2O2 production and antibiotics degradation. Chinese Chemical Letters, 2026, 37(3): 111341-. doi: 10.1016/j.cclet.2025.111341

    16. [16]

      Jiangli Sun , Chaohui Zhang , Yican Zhang , Chunhong Fu , Ruiheng Liang , Zhongzheng Hu , Ge Song , Minghua Zhou . Ag3PO4/g-C3N4 S-scheme heterojunction photoanode coupled with natural air diffusion electrode for efficient organic pollutants degradation and H2O2 generation. Chinese Chemical Letters, 2026, 37(5): 111839-. doi: 10.1016/j.cclet.2025.111839

    17. [17]

      Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe3O4/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753

    18. [18]

      Juanjuan Wang , Yangxia Han , Qixia Guan , Jia Chen , Hongdeng Qiu . Photochromic ionic self-assembled ionic-bonded organic crystals: Blue-shifted and enhanced luminescence. Chinese Chemical Letters, 2026, 37(4): 111732-. doi: 10.1016/j.cclet.2025.111732

    19. [19]

      Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu2O/Bi2CrO6 Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403

    20. [20]

      Shanshan Yan ,  Sihai Sun ,  Zhiwu Chen ,  Xin Wang . Improved photocatalytic activity of SrBi2Nb2O9 for the degradation of ciprofloxacin hydrochloride via piezoelectric-enhanced charge transfer. Chinese Journal of Structural Chemistry, 2025, 44(5): 100569-100569. doi: 10.1016/j.cjsc.2025.100569

Get Citation
PDF
XML
Metrics
  • PDF Downloads(14)
  • Abstract views(1985)
  • HTML views(272)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return