Citation: Su-Qin ZHAO, Jin-Zhong GU. Synthesis, Structures and Catalytic Activity in Knoevenagel Condensation Reaction of Two Diphenyl Ether Tetracarboxylic Acid-Co(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(1): 161-170. doi: 10.11862/CJIC.2022.004 shu

Synthesis, Structures and Catalytic Activity in Knoevenagel Condensation Reaction of Two Diphenyl Ether Tetracarboxylic Acid-Co(Ⅱ) Coordination Polymers

Su-Qin ZHAO ^1,, ,
Jin-Zhong GU ^2,,

1.
College of Physics and Electronic Information Engineering, Qinghai University for Nationalities, Xining 810007, China
2.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Su-Qin ZHAO, qhzhsq@sina.com Jin-Zhong GU, gujzh@lzu.edu.cn
Received Date: 28 July 2021
Revised Date: 25 September 2021

Figures(8)

Two cobalt(Ⅱ) coordination polymers, namely [Co₂(μ₃-deta)(H₂biim)₃(H₂O)₂]_n (1) and {[Co₂((μ₆-deta)(phen)₂]·H₂O}_n (2), have been constructed hydrothermally using H₄deta (2, 3, 3', 4' - diphenyl ether tetracarboxylic acid), H₂biim (2, 2'-biimidazole), phen (1, 10-phenanthroline), and cobalt chloride at 160 ℃. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses, and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that compounds 1 and 2 crystallize in the triclinic and monoclinic systems, space groups P1 and P2₁/c, respectively. Compound 1 discloses a 1D chain structure, and compound 2 features a 2D network. The catalytic activities in Knoevenagel condensation reaction of the compounds were investigated. Compound 1 exhibited excellent catalytic activity in Knoevenagel condensation reaction at room temperature.
- coordination polymer,
- tetracarboxylic acid,
- catalytic property,
- Knoevenagel condensation reaction
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