Citation: Mu-Ge SHELE, Cui-Xia DU, Xin-Yu TIAN, Meng-He BAIYIN. Solvothermal Synthesis and Properties of Quaternary Chalcogenides Containing Transition Metals Cadmium or Mercury[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2149-2157. doi: 10.11862/CJIC.2021.255 shu

Solvothermal Synthesis and Properties of Quaternary Chalcogenides Containing Transition Metals Cadmium or Mercury

College of Chemistry & Environmental Science, Innner Mongolia Normal University, Hohhot 010022, China

Corresponding author: Meng-He BAIYIN, baiymh@imnu.edu.cn
Received Date: 7 May 2021
Revised Date: 8 October 2021

Figures(13)

Two quaternary chalcogenides Rb₂CdSbS₃(SH) (1) and Rb₂HgSb₄S₈ (2) were synthesized by solvothermal method. Single crystal X-ray diffraction analysis shows that compound 1 is 1D chain structure and composed of[CdSbS₃(SH)]^2- anion and Rb⁺ cation. Compound 2 is a 2D layered structure and composed of[HgSb₄S₈]^2- anion and Rb⁺ cation. Solid-state UV-Vis diffuse reflectance spectra showed that the band gaps of compounds 1 and 2 were 2.06 and 2.15 eV, respectively. Fluorescence analysis showed that compounds 1 and 2 had yellow emission characteristics.
- quaternary chalcogenides,
- solvothermal synthesis,
- crystal structure
1. [1]
  Abudurusuli A, Wu K, Tudi A, Yang Z H, Pan S L. ABaSbQ₃ (A=Li, Na; Q=S, Se): Diverse Arrangement Modes of Isolated SbQ₃ Ligands Regulating the Magnitudes of Birefringences[J]. Chem. Commun., 2019,55:5143-5146. doi: 10.1039/C9CC00560A
2. [2]
  Ma N, Li Y Y, Chen L, Wu L M. α-CsCu₅Se₃: Discovery of a Low-Cost Bulk Selenide with High Thermoelectric Performance[J]. J. Am. Chem. Soc., 2020,142:5293-5303. doi: 10.1021/jacs.0c00062
3. [3]
  Mei D J, Yin W L, Feng K, Lin Z S, Bai L, Yao J Y. LiGaGe₂Se₆: A New IR Nonlinear Optical Material with Low Melting Point[J]. Inorg. Chem., 2012,51:1035-1040. doi: 10.1021/ic202202j
4. [4]
  Chen M C, Li L H, Chen Y B, Chen L. In-Phase Alignments of Asymmetric Building Units in Ln₄GaSbS₉(Ln=Pr, Nd, Sm, Gd-Ho) and Their Strong Nonlinear Optical Responses in Middle IR[J]. J. Am. Chem. Soc., 2011,133:4617-4624. doi: 10.1021/ja1111095
5. [5]
  Zheng Y J, Shi Y F, Tian C B, Lin H, Wu L M, Wu X T, Zhu Q L. An Unprecedented Pentanary Chalcohalide with Mn Atoms in Two Chemical Environments: Unique Bonding Characteristics and Magnetic Properties[J]. Chem. Commun., 2019,55:79-82. doi: 10.1039/C8CC08380K
6. [6]
  Heppke E M, Klenner S, Janka O, Pöttgen R, Lerch M. Mechanochemical Synthesis of Cu₂MgSn₃S₈ and Ag₂MgSn₃S₈[J]. Z. Anorg. Allg. Chem., 2020,646:5-9. doi: 10.1002/zaac.201900190
7. [7]
  JIANG H, WANG X, SHENG T L, HU S M, FU R B, WEN Y H, SHEN C J, YUAN N, WU X T. Solvothermal Synthesis and Characterization of a Novel Selenidoantimonate: [M¹(C₄H₁₃N₃)₂]_n[M²Sb₂Se₅]_n (M¹=Mn, Co; M²=Zn, Cd)[J]. Sci. Sin. Chim., 2011,41(4):726-731.
8. [8]
  Shele M G, Qi F Y, Tian X Y, Bao Y S, Baiyin M H. Preparation of 0-2 Dimensional Organic-Decorated Quaternary TM-Cd-Sb-Se (TM=Zn, Mn, Fe) Compounds by Solvothermal Method: Syntheses, Crystal Structures and Properties[J]. J. Solid State Chem., 2021,296121964. doi: 10.1016/j.jssc.2021.121964
9. [9]
  Yue C Y, Lei X W, Liu R Q, Zhang H P, Zhai X R, Li W P, Zhou M, Zhao Z F, Ma Y X. Syntheses, Crystal Structures, and Photocatalytic Properties of a Series of Mercury Thioantimonates Directed by Transition Metal Complexes[J]. Cryst. Growth Des., 2014,14(5):2411-2421. doi: 10.1021/cg500153u
10. [10]
  Wang K Y, Ye D, Zhou L J, Feng M L, Huang X Y. Novel Mercury Selenidoantimonates with Structures Ranging from One-Dimensional Ribbon to Three-Dimensional Open-Framework[J]. Dalton Trans., 2013,42(15):5454-5461. doi: 10.1039/c3dt32676d
11. [11]
  Zhang M, Sheng T L, Wang X, Hu S M, Fu R B, Chen J S, He Y M, Qin Z T, Shen C J, Wu X T. Synthesis and Crystal Structure of Two New Heterometallic Thioantimonates (Ⅲ)[Ni(pda)₂]Cu₄^ⅠSb₂^ⅢS₆ and[Ni(dien)₂]Cu^ⅠSb₃^ⅢS₆[J]. CrystEngComm, 2010,12:73-76. doi: 10.1039/B906640C
12. [12]
  Yue C Y, Lei X W, Ma Y X, Sheng N, Yang Y D, Liu G D, Zhai X R. [TM(en)₃][SnSb₄S₉] (TM=Ni, Co): 3D Chiral Framework of Mixed Main-Group Metals and[Mn(dien)₂]₂Sb₄S₉: 1D Chains with Mixed-Valent Sb Centers[J]. Cryst. Growth Des., 2014,14:101-109. doi: 10.1021/cg401208p
13. [13]
  Zhang B, Li W A, Liao Y Y, Zhang C, Feng M L, Huang X Y. [CH₃NH₃]₄Ga₄SbS₉S_0.28O_0.72H: A Three-Dimensionally Open-Framework Heterometallic Chalcogenidoantimonate Exhibiting Ni²⁺ Ion-Exchange Property[J]. Chem. Asian J., 2018,13:672-678. doi: 10.1002/asia.201701763
14. [14]
  Yao H G, Zhou P, Ji S H, Zhang R C, Ji M, An Y L, Ning G L. Syntheses and Characterization of a Series of Silver-Thioantimonates (Ⅲ) and Thioarsenates(Ⅲ) Containing Two Types of Silver-Sulfur Chains[J]. Inorg. Chem., 2010,49:1186-1190. doi: 10.1021/ic902084u
15. [15]
  Shen Y Y, Liu C, Hou P P, Zhi M J, Zhou C M, Chai W X, Zhang Q C, Liu Y. Facile Surfactant-Thermal Syntheses and Characterization of Quaternary Copper Thioantimonates (Ⅲ) ACu₂SbS₃(A=K, Rb, Cs)[J]. J. Alloys Compd., 2016,660:171-177. doi: 10.1016/j.jallcom.2015.11.075
16. [16]
  Liu C, Shen Y Y, Hou P P, Zhi M J, Zhou C M, Chai W X, Cheng J W, Liu Y. Hydrazine-Hydrothermal Synthesis and Characterization of the Two New Quaternary Thioantimonates (Ⅲ) BaAgSbS₃ and BaAgSbS₃·H₂O[J]. Inorg. Chem., 2015,54:8931-8936. doi: 10.1021/acs.inorgchem.5b00974
17. [17]
  CHEN Z, WANG R J. Crystal Structures and Semiconductor Properties of Alkline Metal Selenides MHgSbSe₃(M=K, Rb, Cs)[J]. Acta Chim. Sinica, 2000,58:326-331.
18. [18]
  Mafuku M, Nakai I, Nagashima K. The Crystal-Structure of a New Synthetic Sulfosalt, KHgSbS₃[J]. Mater. Res. Bull., 1986,21:493-501. doi: 10.1016/0025-5408(86)90016-4
19. [19]
  Li J, Chen Z, Wang X X, Proserpio D M, Proserpio D M. A Novel Two-Dimensional Mercury Antimony Telluride: Low Temperature Synthesis and Characterization of RbHgSbTe₃[J]. J. Alloys Compd., 1997,262:28-33.
20. [20]
  Zhang X, Yi N, Hoffmann R, Zheng C, Lin J H, Huang F Q. Semiconductive K₂MSbS₃(SH) (M=Zn, Cd) Featuring One-Dimensional[M₂Sb₂S₆(SH₂)]^4- Chains[J]. Inorg. Chem., 2016,55:9742-9747. doi: 10.1021/acs.inorgchem.6b01529
21. [21]
  Yohannan J P, Vidyasagar K. Syntheses and Characterization of One-Dimensional Alkali Metal Antimony (Ⅲ) Thiostannates (Ⅳ), A₂Sb₂Sn₃S₁₀(A=K, Rb, Cs)[J]. J. Solid State Chem., 2015,221:426-432. doi: 10.1016/j.jssc.2014.10.022
22. [22]
  Yin W L, Zhou M L, Abishek K I, Yao J Y, Mar A. Noncentrosymmetric Quaternary Selenide Ba₂₃Ga₈Sb₂Se₃₈: Synthesis, Structure, and Optical Properties[J]. J. Alloys Compd., 2017,729:150-155. doi: 10.1016/j.jallcom.2017.09.127
23. [23]
  Hanko J A, Kanatzidis M G. A Three-Dimensional Framework with Accessible Nanopores: RbCuSb₂Se₄·H₂O[J]. Angew. Chem. Int. Ed., 1998,37(3):342-344. doi: 10.1002/(SICI)1521-3773(19980216)37:3<342::AID-ANIE342>3.0.CO;2-P
24. [24]
  Wendlandt W W, Hecht H G. Reflectance Spectroscopy. New York: Interscience Publishers, 1966.
25. [25]
  Dolomanov O V, Bourhis L J, Gildea R J. OLEX2:A Complete Structure Solution, Refinement and Analysis Program[J]. J. Appl. Cryst., 2009,42:339-341. doi: 10.1107/S0021889808042726
26. [26]
  Zhou J, An L T. A Novel 3-D Thioindate-Thioantimonate Based on the Linkages of Large Heterometallic {In₂Sb₂S₉} Clusters and 1-D[In₂Sb₂S₈^4-]_n Chains[J]. CrystEngComm, 2011,13:5924-5928. doi: 10.1039/c1ce05551h
27. [27]
  Chou J H, Kanatzidis M G. Hydrothermal Synthesis and Characterization of (Me₄N)[HgAsSe₃], (Et₄N)[HgAsSe₃], and (Ph₄P)₂[Hg₂As₄Se₁₁]: Novel 1-D Mercury Selenoarsenates[J]. J. Solid State Chem., 1996,123:115-122. doi: 10.1006/jssc.1996.0159
28. [28]
  Gregory A M, Jason A H, Kanatzidis M G. New Quaternary Thiostannates and Thiogermanates A₂Hg₃M₂S₈(A=Cs, Rb; M=Sn, Ge) through Molten A₂S_x. Reversible Glass Formation in Cs₂Hg₃M₂S₈[J]. Chem. Mater., 1998,10:1191-1199. doi: 10.1021/cm970804m
29. [29]
  Du C X, Qi F Y, Chen Q, Baiyin M H. Two Mercury Antimony Chalcogenides Cs₂HgSb₄S₈ and Cs₂Hg₂Sb₂Se₆ with Cesium Cations as Counterions[J]. ACS Omega, 2018,3(11):15168-15173. doi: 10.1021/acsomega.8b02059
30. [30]
  An D C, Chen S P, Lu Z X, Li R, Chen W, Fan W H, Wang W X, Wu Y C. Low Thermal Conductivity and Optimized Thermoelectric Properties of p-Type Te-Sb₂Se₃: Synergistic Effect of Doping and Defect Engineering[J]. ACS. Appl. Mater. Interfaces, 2019,1127788. doi: 10.1021/acsami.9b07313
31. [31]
  Manocha A S, Fateley W G, Shimanouchi T. Far-Infrared Spectra and Barrier to Internal Rotation of Ethanethiol[J]. J. Phys. Chem., 1973,77:1977-1981. doi: 10.1021/j100635a011
32. [32]
  Qian W, Krimm S. Conformation Dependence of the SH and CS Stretch Frequencies of the Cysteine Residue[J]. Biopolymers, 1992,32:1503-1518. doi: 10.1002/bip.360321109
33. [33]
  BAIYIN M H, JI M, LIU X, AN Y L, JIA C Y, NING G L. Solvothermal Synthesis and Characterization of K₄Ag₂Sn₃S₉·2H₂O with Layer Structure[J]. Chem. J. Chinese Universities, 2004,25(8):1391-1394.
34. [34]
  Kong D N, Xie Z L, Feng M L, Ye D, Du K Z, Li J R, Huang X Y. From One-Dimensional Ribbon to Three-Dimensional Microporous Framework: The Syntheses, Crystal Structures, and Properties of a Series of Mercury Antimony Chalcogenides[J]. Cryst. Growth Des., 2010,10(3):1364-1372. doi: 10.1021/cg9013834
35. [35]
  Li Y Y, Liu P F, Lin H, Wu L M, Wu X T, Zhu Q L. Quaternary Semiconductor Ba₈Zn₄Ga₂S₁₅ Featuring Unique One-dimensional Chains and Exhibiting Desirable Yellow Emission[J]. Chem. Commun., 2019,55:7942-7945. doi: 10.1039/C9CC02575H
36. [36]
  Lin H, Zhou L J, Chen L. Sulfides with Strong Nonlinear Optical Activity and Thermochromism: ACd₄Ga₅S₁₂(A=K, Rb, Cs)[J]. Chem. Mater., 2012,24:3406-3414. doi: 10.1021/cm301550a
37. [37]
  Li Y Y, Liu P F, Wu L M. Ba₆Zn₇Ga₂S₁₆: A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties[J]. Chem. Mater., 2017,29:5259-5266. doi: 10.1021/acs.chemmater.7b01321
38. [38]
  Zhen N, Wu K, Wang Y, Li Q, Gao W H, Hou D W, Yang Z H, Jiang H D, Dong Y J, Pan S L. BaCdSn_S₄ and Ba₃CdSn₂S₈: Syntheses, Structures, and Non-linear Optical and Photoluminescence Properties[J]. Dalton Trans., 2016,45:10681-10688. doi: 10.1039/C6DT01537A
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