Citation: Mu-Ge SHELE, Cui-Xia DU, Xin-Yu TIAN, Meng-He BAIYIN. Solvothermal Synthesis and Properties of Quaternary Chalcogenides Containing Transition Metals Cadmium or Mercury[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2149-2157. doi: 10.11862/CJIC.2021.255 shu

Solvothermal Synthesis and Properties of Quaternary Chalcogenides Containing Transition Metals Cadmium or Mercury

College of Chemistry & Environmental Science, Innner Mongolia Normal University, Hohhot 010022, China

Corresponding author: Meng-He BAIYIN, baiymh@imnu.edu.cn
Received Date: 7 May 2021
Revised Date: 8 October 2021

Figures(13)

Two quaternary chalcogenides Rb₂CdSbS₃(SH) (1) and Rb₂HgSb₄S₈ (2) were synthesized by solvothermal method. Single crystal X-ray diffraction analysis shows that compound 1 is 1D chain structure and composed of[CdSbS₃(SH)]^2- anion and Rb⁺ cation. Compound 2 is a 2D layered structure and composed of[HgSb₄S₈]^2- anion and Rb⁺ cation. Solid-state UV-Vis diffuse reflectance spectra showed that the band gaps of compounds 1 and 2 were 2.06 and 2.15 eV, respectively. Fluorescence analysis showed that compounds 1 and 2 had yellow emission characteristics.
- quaternary chalcogenides,
- solvothermal synthesis,
- crystal structure
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