Citation: Wu-Jiu JIANG, Ao-Dian LI, Ming-Hao TANG, Xiao-Long NAN, Yan-Liang TAN, Yu-Xing TAN. Solvothermal Self-Assembly Syntheses, Crystal Structures and Property of Two Uranyl Complexes with Organic Ligand Containing N and O Atoms[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2209-2218. doi: 10.11862/CJIC.2021.251 shu

Solvothermal Self-Assembly Syntheses, Crystal Structures and Property of Two Uranyl Complexes with Organic Ligand Containing N and O Atoms

1.
Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional Organometallic Materials, University of Hunan Province, Hunan Provincial Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the Upper Reaches of Xiangjiang River, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China
2.
Nuclear Bureau of Hunan Province Nuclear Industry Brigade 306, Hengyang, Hunan 421008, China
3.
Hunan Provincial Engineering Research Center for Uranium Mineral Exploration Technology, College of Physics and Electronic Engineering, Hengyang Normal University, Hengyang, Hunan 421002, China

Corresponding author: Yu-Xing TAN, tanyuxing@hynu.edu.cn
Received Date: 22 June 2021
Revised Date: 2 September 2021

Figures(14)

Under solvothermal conditions, two new UO₂²⁺ complexes[UO₂(L1)(CH₃COO)]·3CH₃OH (C1) and[UO₂ (L2)(Phen)(CH₃O)] (C2) were synthesized by self-assembly with organic ligand containing N and O atom (L1=N', N‴-((2E, 3E)-butane-2, 3-diylidene)bis(4-hydroxybenzohydrazide), L2=2, 4, 5-trifluoro-3-methoxybenzoic acid, Phen=phenanthroline). The structure of the complexes was characterized by elemental analysis, infrared spectra and X-ray single crystal diffraction. The results show that the uranium ions in complexes C1 and C2 are all +6 valence. The uranium ions in complexes C1 and C2 adopt eight- and seven-coordinated modes, respectively. C1 forms a one-dimensional infinite chain structure through abundant O-H…O hydrogen bonds, and there are π-π stacking interactions in C2. The thermal stability and spectral properties of the complexes were studied, and the structures of the complexes were calculated theoretically. The dynamic stability of the complexes was discussed. CCDC: 2077418, C1; 2077419, C2.
- UO₂²⁺ complex,
- synthesis,
- crystal structure,
- property
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