Citation: Wu-Jiu JIANG, Ao-Dian LI, Ming-Hao TANG, Xiao-Long NAN, Yan-Liang TAN, Yu-Xing TAN. Solvothermal Self-Assembly Syntheses, Crystal Structures and Property of Two Uranyl Complexes with Organic Ligand Containing N and O Atoms[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2209-2218. doi: 10.11862/CJIC.2021.251 shu

Solvothermal Self-Assembly Syntheses, Crystal Structures and Property of Two Uranyl Complexes with Organic Ligand Containing N and O Atoms

1.
Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional Organometallic Materials, University of Hunan Province, Hunan Provincial Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the Upper Reaches of Xiangjiang River, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China
2.
Nuclear Bureau of Hunan Province Nuclear Industry Brigade 306, Hengyang, Hunan 421008, China
3.
Hunan Provincial Engineering Research Center for Uranium Mineral Exploration Technology, College of Physics and Electronic Engineering, Hengyang Normal University, Hengyang, Hunan 421002, China

Corresponding author: Yu-Xing TAN, tanyuxing@hynu.edu.cn
Received Date: 22 June 2021
Revised Date: 2 September 2021

Figures(14)

Under solvothermal conditions, two new UO₂²⁺ complexes[UO₂(L1)(CH₃COO)]·3CH₃OH (C1) and[UO₂ (L2)(Phen)(CH₃O)] (C2) were synthesized by self-assembly with organic ligand containing N and O atom (L1=N', N‴-((2E, 3E)-butane-2, 3-diylidene)bis(4-hydroxybenzohydrazide), L2=2, 4, 5-trifluoro-3-methoxybenzoic acid, Phen=phenanthroline). The structure of the complexes was characterized by elemental analysis, infrared spectra and X-ray single crystal diffraction. The results show that the uranium ions in complexes C1 and C2 are all +6 valence. The uranium ions in complexes C1 and C2 adopt eight- and seven-coordinated modes, respectively. C1 forms a one-dimensional infinite chain structure through abundant O-H…O hydrogen bonds, and there are π-π stacking interactions in C2. The thermal stability and spectral properties of the complexes were studied, and the structures of the complexes were calculated theoretically. The dynamic stability of the complexes was discussed. CCDC: 2077418, C1; 2077419, C2.
- UO₂²⁺ complex,
- synthesis,
- crystal structure,
- property
1. [1]
  WANG X Y, LIU Y F. Nuclear Chemistry and Radiochemistry. Beijing: Peking University Press, 2007.
2. [2]
  Settle F A. Uranium to Electricity: The Chemistry of the Nuclear Fuel Cycle[J]. J. Chem. Educ., 2009,86(3):316-323. doi: 10.1021/ed086p316
3. [3]
  Alley W M, Alley R. The Growing Problem of Stranded Used Nuclear Fuel[J]. Environ. Sci. Technol., 2014,48(4):2091-2096. doi: 10.1021/es405114h
4. [4]
  Basolo F. Frontiers of Inorganic Chemistry[J]. Coord. Chem. Rev., 1993,125(1):13-34.
5. [5]
  Brinkmann H, Patzschke M, Kaden P, Raiwa M, Rossberg A, Kloditz R, Heim K, Moll H, Stumpf T. Complex Formation Between UO₂²⁺ and α-Isosaccharinic Acid: Insights on a Molecular Level[J]. Dalton Trans., 2019,48(35):13440-13457. doi: 10.1039/C9DT01080G
6. [6]
  Liu G K, Rao L F, Tian G X. Theoretical Analysis and Quantification of the Absorption Spectra of Uranyl Complexes with Structurally-Related Tridentate Ligands[J]. Phys. Chem. Chem. Phys., 2013,15(40):17487-17495. doi: 10.1039/c3cp52900b
7. [7]
  Niklas J E, Farnum B H, Gorden J D, Gorden A E V. Structural Characterization and Redox Activity of a Uranyl Dimer and Transition-Metal Complexes of a Tetradentate BIAN Ligand[J]. Organometallics, 2017,36(23):4626-4634. doi: 10.1021/acs.organomet.7b00454
8. [8]
  Drouza C, Gramlich V, Sigalas M P, Pashalidis I, Keramidas A D. Synthesis, Structure, and Solution Dynamics of UO₂²⁺-Hydroxy Ketone Compounds[UO₂(ma)₂(H₂O)] and[UO₂(dpp) (Hdpp)₂(H₂O)] ClO₄[ma=3-Hydroxy-2-methyl-4-pyrone, Hdpp=3-Hydroxy-1, 2-dimethyl-4(1H)-pyridone][J]. Inorg. Chem., 2004,43(26):8336-8345. doi: 10.1021/ic049167+
9. [9]
  Natrajan L, Burdet F, Pécaut J, Mazzanti M. Synthesis and Structure of a Stable Pentavalent-Uranyl Coordination Polymer[J]. J. Am. Chem. Soc., 2006,128(22):7152-7153. doi: 10.1021/ja0609809
10. [10]
  Jiang W J, Fan S J, Zhou Q, Zhang F X, Kuang D Z, Tan Y X. Diversity of Complexes Based on p-Nitrobenzoylhydrazide, Benzoylformic Acid and Diorganotin Halides or Oxides Self-Assemble: Cytotoxicity, the Induction of Apoptosis in Cancer Cells and DNA-Binding Properties[J]. Bioorg. Chem., 2020,94103402. doi: 10.1016/j.bioorg.2019.103402
11. [11]
  Li L J, Miao L, Zhang Z, Pu X H, Feng Q, Yanagisawa K, Fan Y, Fan M J, Wen P H, Hu D W. Recent Progress in Piezoelectric Thin Film Fabrication via the Solvothermal Process[J]. J. Mater. Chem. A, 2019,7(27):16046-16067. doi: 10.1039/C9TA04863D
12. [12]
  Modeshia D R, Walton R I. Solvothermal Synthesis of Perovskites and Pyrochlores: Crystallisation of Functional Oxides under Mild Conditions[J]. Chem. Soc. Rev., 2010,39(11):4303-4325. doi: 10.1039/b904702f
13. [13]
  Sanna Angotzi M, Musinu A, Mameli V, Ardu A, Cara C, Niznansky D, Xin H L, Cannas C. Spinel Ferrite Core-Shell Nanostructures by a Versatile Solvothermal Seed-Mediated Growth Approach and Study of Their Nanointerfaces[J]. ACS Nano, 2017,11(8):7889-7900. doi: 10.1021/acsnano.7b02349
14. [14]
  McSkimming A, Su J, Cheisson T, Gau M R, Carroll P J, Batista E R, Yang P, Schelter E J. Coordination Chemistry of a Strongly-Donating Hydroxylamine with Early Actinides: An Investigation of Redox Properties and Electronic Structure[J]. Inorg. Chem., 2018,57(8):4387-4394. doi: 10.1021/acs.inorgchem.7b03238
15. [15]
  Yao J, Zheng X J, Pan Q J, Schreckenbach G. Highly Valence-Diversified Binuclear Uranium Complexes of a Schiff-Base Polypyrrolic Macrocycle: Prediction of Unusual Structures, Electronic Properties, and Formation Reactions[J]. Inorg. Chem., 2015,54(11):5438-5449. doi: 10.1021/acs.inorgchem.5b00483
16. [16]
  Castro-Rodríguez I, Meyer K. Small Molecule Activation at Uranium Coordination Complexes: Control of Reactivity via Molecular Architecture[J]. Chem. Commun., 2006(13):1353-1368. doi: 10.1039/b513755c
17. [17]
  Melfi P J, Kim S K, Lee J T, Bolze F, Seidel D, Lynch V M, Veauthier J M, Gaunt A J, Neu M P, Ou Z, Kadish K M, Fukuzumi S, Ohkubo K, Sessler J L. Redox Behavior of Cyclo[6]pyrrole in the Formation of a Uranyl Complex[J]. Inorg. Chem., 2007,46(13):5143-5145. doi: 10.1021/ic700781t
18. [18]
  Azam M, Al-Resayes S I, Velmurugan G, Venuvanalingam P, Wagler J, Kroke E. Novel Uranyl(Ⅵ) Complexes Incorporating Propylene-Bridged Salen-Type N₂O₂-Ligands: A Structural and Computational Approach[J]. Dalton Trans., 2015,44(2):568-577. doi: 10.1039/C4DT02112F
19. [19]
  Li J X, Du Z X. A Binuclear Cadmium (Ⅱ) Cluster Based on π …π Stacking and Halogen…Halogen Interactions: Synthesis, Crystal Analysis and Fluorescent Properties[J]. J. Clust. Sci., 2020,31(2):507-511. doi: 10.1007/s10876-019-01666-w
20. [20]
  Cheng B H. Improving Oxygen Sensing Performance via Inner-Molecular π-π Stacking in a Series of Phosphorescent Cu (Ⅰ) Complexes[J]. Spectrochim. Acta Part A, 2020,239118537. doi: 10.1016/j.saa.2020.118537
21. [21]
  GE R, WU S, ZENG L W, LI F Z, MEI L, LIU C L. Synthesis, Structure and Physico-chemical Properties of Two Uranyl Complexes of Cucurbiturils Mediated by Sulfate Ions[J]. Sci. Sin. Chim, 2019,49(8):1073-1082.
22. [22]
  WANG C. Synthesis, Structural Analysis and Adsorption Properties of the Uranyl Complex[J]. Chemical Reagents, 2019,41(5):431-436.
23. [23]
  GUO G, LI J, WU Y, DING W M, ZHANG S Z, SUN Y X. Self-Assembled Zn²⁺, Co²⁺ and Ni²⁺ Complexes Based on Coumarin Schiff Base Ligands: Synthesis, Crystal Structure and Spectral Properties[J]. Chinese J. Inorg. Chem., 2021,37(6):1113-1124.
24. [24]
  SONG G, SUN Q, HOU Y N, ZHAN R, WEI D M, SHI Z, XING Y H. Synthesis, Structure and Quantum Chemistry Study of the 4-Iodopyrazole Copper Complexes[J]. Chinese J. Inorg. Chem., 2013,29(10):2150-2156.
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
4. [4]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
5. [5]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
6. [6]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
9. [9]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
10. [10]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
11. [11]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
12. [12]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
13. [13]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
14. [14]
  Simin Fang , Hong Wu , Sizhe Sheng , Lingling Li , Yuxi Wang , Hongchun Li , Jun Jiang . The Food Kingdom Lecture Series: The Science behind Color. University Chemistry, 2024, 39(9): 177-182. doi: 10.12461/PKU.DXHX202402012
15. [15]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
16. [16]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
17. [17]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
18. [18]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
19. [19]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
20. [20]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1475)
HTML views(204)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142