Citation: Chun-Yu HE, Xiao-Qing YANG, Yan-Hong ZHANG, Shuang JIANG. Synthesis, Structure and Properties of Three Copper(Ⅱ) Complexes Based on a Bifunctional Ligand 2, 2': 6'2″-Terpyridine-4'-carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2267-2278. doi: 10.11862/CJIC.2021.244 shu

Synthesis, Structure and Properties of Three Copper(Ⅱ) Complexes Based on a Bifunctional Ligand 2, 2': 6'2″-Terpyridine-4'-carboxylic Acid

1.
College of Chemistry and Environment Science, Key Laboratory of Excitonic Materials Chemistry & Devices, Inner Mongolia Normal University, Hohhot 010022, China
2.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education, Nankai University, Tianjin 300071, China

Corresponding author: Yan-Hong ZHANG, zhangyh@imnu.edu.cn
Received Date: 16 March 2021
Revised Date: 3 September 2021

Figures(5)

Two copper binuclear complexes[Cu(tpyc)(H₂btc)]₂ (1), [Cu₂(tpyc)₂(suc)(H₂O)₂] (2) and one coordination polymer {[Cu₃(tpyc)₃(OH)₂(H₂O)₂]ClO₄}_n (3) (H₃btc=1, 3, 5-benzenetricarboxylic acid, H₂suc=succinic acid, Htpyc=2, 2': 6'2″-terpyridine-4'-carboxylic acid) have been synthesized under solvothermal conditions and characterized by elemental analysis, FT-IR spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis and magnetic analysis. Structural analysis suggests that complexes 1-3 display 3D supramolecular networks by multiple hydrogen-bonding interactions. Magnetic studies show that ferromagnetic coupling exists between Cu(Ⅱ) ions in complex 1, while antiferromagnetic interaction exists between Cu(Ⅱ) ions in complex 2.
- binuclear complex,
- coordination polymer,
- crystal structure,
- magnetic property
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