Citation: Jing LIANG, Lu HAN, Bao LI, Zhen-Zhu SHI, Xing-Chi LIU, Li-Chao PENG, Xue-Yan ZOU. Fast and Efficient Immobilization Behavior of Bifunctional Magnetic Nano-Amendment Against Multi-heavy Metal[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 1981-1990. doi: 10.11862/CJIC.2021.243 shu

Fast and Efficient Immobilization Behavior of Bifunctional Magnetic Nano-Amendment Against Multi-heavy Metal

Jing LIANG ^{1, 2} ,
Lu HAN ^{1, 2} ,
Bao LI ^{1, 3} ,
Zhen-Zhu SHI ^{1, 3} ,
Xing-Chi LIU ^{1, 3} ,
Li-Chao PENG ^{1, 5,,} ,
Xue-Yan ZOU ^{1, 4, 5,,}

1.
Engineering Research Center for Nanomaterials, Henan University, Kaifeng, Henan 475004, China
2.
School of Pharmacy, Henan University, Kaifeng, Henan 475004, China
3.
College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China
4.
State Key Laboratory of Cotton Biology, Henan University, Kaifeng, Henan 475004, China
5.
Collaborative Innovation Center of Nano Functional Materials and Applications of Henan Province, Henan University, Kaifeng, Henan 475004, China

Corresponding author: Li-Chao PENG, plc@henu.edu.cn Xue-Yan ZOU, zouxueyan@henu.edu.cn
Received Date: 6 April 2021
Revised Date: 9 October 2021

Figures(9)

Ferroferric oxide/L-cysteine (Fe₃O₄/Cys) magnetic nanospheres were synthesized by one pot method. Subsequently, the obtained Fe₃O₄/Cys were further modified by conjugating iminodiacetic acid (IDA) to obtain Fe₃O₄/Cys/IDA nanospheres. It was indicated that L-Cys was grafted on the surface of Fe₃O₄ by -SH group and Fe₃O₄/Cys/IDA, with more branched chains and more -COOH groups, was obtained by amido bond formed by the -NH₂ group of Fe₃O₄/Cys and the -COOH group of IDA. Due to the alternative short and long chains grafting, Fe₃O₄/Cys/IDA nanospheres displayed high density modification of -COOH groups. Meanwhile, we found that the adsorption of Pb²⁺, Cd²⁺, Cu²⁺, Co²⁺, Ni²⁺, Zn²⁺ ions by Fe₃O₄/Cys/IDA nanospheres were specific adsorption and that of Hg²⁺ ions was unspecific adsorption. And all the complexes (Fe₃O₄/Cys/IDA-M, M was the metal) obtained after immobilization exhibited good stability. Experimental equilibrium data were also analyzed by the Langmuir and Freundlich models, and the best fit was obtained with the Langmuir isotherm equation, which was monolayer homogeneous adsorption. The kinetic study indicated that the adsorption kinetic data was well described by the pseudo-second kinetic model and the maximum immobilization capacity was 49.05 mg·g^-1, which was a fast and efficient heavy metal immoblization material.
- Fe₃O₄,
- polycarboxylic,
- heavy metal,
- graft mechanism,
- kinetic,
- thermodynamic
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