Citation: Qi-Chao ZOU, Yan MA, Dian-Jun CHI, Hong-Bin QIAO, Jun-Ying ZHANG, Qian CHEN, Yu-Die SUN, Jian ZHANG, Kui ZHANG, Sheng-Jun LIU. Synthesis of Quasi-MIL-53(Fe) Photocatalysts for Enhanced Visible Light Photocatalytic Degradation of Organic Dyes[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2289-2297. doi: 10.11862/CJIC.2021.240 shu

Synthesis of Quasi-MIL-53(Fe) Photocatalysts for Enhanced Visible Light Photocatalytic Degradation of Organic Dyes

School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma'Anshan, Anhui 243032, China

Corresponding author: Hong-Bin QIAO, qiaohb@ahut.edu.cn Sheng-Jun LIU, lsj1990@mail.ustc.edu.cn
Received Date: 1 June 2021
Revised Date: 20 September 2021

Figures(5)

Quasi-metal-organic-frameworks (MOFs) derivative-based MFe-T (T℃ stands for calcination temperature) photocatalysts with a porous structure were synthesized by the pyrolysis of MIL-53(Fe) (termed MFe hereafter). Among the tested catalysts, MFe-250 exhibited the highest photodegradation performance, degradation of 99% methylene blue (MB) within 90 min. From the photocurrent and electrochemical impedance spectroscopy results, the electronic transmission capability of MFe-250 exceeded that of MFe. Furthermore, trapping experiments revealed that while hydroxyl radicals (·OH) were essential intermediates in the photocatalytic degradation of MB. Additionally, a mechanism for the photocatalytic process was proposed.
- metal-organic frameworks,
- visible light,
- photodegradation,
- organic dyes
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