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Citation: Hong-Mei CHAI, Jia-Ling YAN, Yi-Xia REN, Lou-Jun GAO, Gang-Qiang ZHANG, Yan ZHANG, Shu-Yuan HAO. Heterometallic Ln(Na)-MOFs (Ln=Tb, Dy, Ho): Crystal Structures, Luminescent Sensing for Acetaldehyde, Fe3+, Cr2O72-, and Electrochemical Sensing for Catechol[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 1913-1921. doi: 10.11862/CJIC.2021.232 shu

Heterometallic Ln(Na)-MOFs (Ln=Tb, Dy, Ho): Crystal Structures, Luminescent Sensing for Acetaldehyde, Fe3+, Cr2O72-, and Electrochemical Sensing for Catechol

  • 1.

    Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

  • 2.

    Xinjiang Xuanli Environmental Protection Energy Co., Ltd., Hami, Xinjiang 839000, China

Figures(9)

  • Three new 3D microporous isostructural heterometallic metal organic frameworks Ln(Na)-MOFs: {[LnNa(BDT)(H2O)3]·2H2O}n (Ln=Tb (1), Dy (2), Ho (3), H4BDT=3, 5-bis(3', 5'-dicarboxylphenyl)-1H-1, 2, 4-triazole), have been synthesized under solvothermal condition, and characterized by single crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and powder X-ray diffraction. Structural analysis demonstrates that they possess the same 3D frameworks based on similar heteronuclear bimetallic units. Fluorescence studies show that Tb (Na)-MOF (1) can detect Fe3+ ion, Cr2O72- anion, and acetaldehyde molecules with high sensitivity and selectivity by luminescent sensing, and can also be used for electrochemical detection of catechol in water.
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