Citation: Hong-Ren RONG, Xian-Mei WANG, Ying-Hua WEI, Xiao-Juan CHEN, Li-Fang LAI, Qi LIU. A Layered Co-MOF Based Electrode Material of Supercapacitor with High-Capacity[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2227-2234. doi: 10.11862/CJIC.2021.230 shu

A Layered Co-MOF Based Electrode Material of Supercapacitor with High-Capacity

School of Petrochemical Engineering and Jiangsu Provincial Key Laboratory of Fine Petrochemicals, Changzhou University, Changzhou, Jiangsu 213164, China

Corresponding author: Hong-Ren RONG, rhr@cczu.edu.cn Qi LIU, liuqi62@163.com
Received Date: 23 July 2021
Revised Date: 15 October 2021

Figures(9)

A cobalt-based MOF ([Co(4, 4'-bpy)(tfbdc)(H₂O)₂], Co-BTH, 4, 4'-bpy=4, 4'-bipyridune, H₂tfbdc=tetrafluo-roterephthalic acid) was synthesized by a simple solvothermal reaction, and its performance as the electrode material for supercapacitors was evaluated for the first time. The results show that Co-BTH electrode has good pseudocapacitance performance, including high specific capacitance and good rate performance. In 1 mol·L^-1 KOH solution, the maximum specific capacitance was 2 316 F·g^-1 at a current density of 1 A·g^-1. At the current density of 2 A·g^-1, the specific capacity of the electrode still kept 847 F·g^-1 after 1 000 cycles. The good pseudo-capacitance performance is related to the layered structure of Co-BTH and the small size nanosheets.
- cobalt,
- metal-organic frameworks,
- supercapacitor,
- electrode materials,
- electrochemical performances
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