Citation: Wei ZHANG, Yu-Yi ZHANG, Ya-Jie BIAN, Meng-Di CHEN, Xiao-Lei ZHANG, Qing-Yuan JIN, Bing-Wen HU. Controlling Distribution of Gold Nanoparticles in Au@ZIF-8 Core-Shell Structures for Sensing Fluorescent Molecules with Photoluminescence[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 2059-2067. doi: 10.11862/CJIC.2021.229 shu

Controlling Distribution of Gold Nanoparticles in Au@ZIF-8 Core-Shell Structures for Sensing Fluorescent Molecules with Photoluminescence

State Key Laboratory of Precision Spectroscopy, Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Electronic Science, East China Normal University, Shanghai 200062, China

Corresponding author: Meng-Di CHEN, mdchen@lps.ecnu.edu.cn Xiao-Lei ZHANG, xlzhang@admin.ecnu.edu.cn
Received Date: 18 March 2021
Revised Date: 31 August 2021

Figures(6)

Controlling the distribution of metal nanoparticles in metal@MOF core-shell structures is not easy to realize. We applied the coordination modulation method which has been studied in the synthesis of MOF colloids to synthesize Au@ZIF-8 core-shell nanostructures. Different Au@ZIF-8 core-shell nanostructures have been achieved by employing an excess amount of 2-methylimidazole and various amount of 1-methylimidazole. With our method, the distribution of Au nanoparticles (Au NPs) could be flexibly tuned in the ZIF-8 nanocrystals. Moreover, we investigated the photoluminescent spectra and lifetime of two fluorescent molecules with different sizes, combined with Au@ZIF-8 separately. The aperture size of ZIF-8 determines whether to let the molecules pass through the porous shell to approach Au NPs, and the molecular optical properties are sensitive to the competition of luminescent enhancement and fluorescent quenching of Au NPs.
- core-shell structure,
- ZIF-8,
- Au nanoparticles,
- fluorescent,
- photoluminescence
1. [1]
  El-Toni A M, Habila M A, Labis J P, ALOthman Z A, Alhoshan M, Elzatahry A A, Zhang F. Design, Synthesis and Applications of Core-Shell, Hollow Core, and Nanorattle Multifunctional Nanostructures[J]. Nanoscale, 2016,8:2510-2531. doi: 10.1039/C5NR07004J
2. [2]
  An W, Liu P. Rationalization of Au Concentration and Distribution in AuNi@Pt Core-Shell Nanoparticles for Oxygen Reduction Reaction[J]. ACS Catal., 2015,5:6328-6336. doi: 10.1021/acscatal.5b01656
3. [3]
  Wang X K, Liu J, Zhang L, Dong L Z, Li S L, Kan Y H, Li D S, Lan Y Q. Monometallic Catalytic Models Hosted in Stable Metal-Organic Frameworks for Tunable CO₂ Photoreduction[J]. ACS Catal., 2019,9:1726-1732. doi: 10.1021/acscatal.8b04887
4. [4]
  Shiga T, Kumamaru R, Newton G N, Oshio H. Heteroleptic Iron (Ⅱ) Complexes with Naphthoquinone-Type Ligands[J]. Dalton Trans., 2020,49:1485-1491. doi: 10.1039/C9DT03946E
5. [5]
  Chen X R, Tong R L, Shi Z Q, Yang B, Liu H, Ding S P, Wang X, Lei Q F, Wu J, Fang W J. MOF Nanoparticles with Encapsulated Autophagy Inhibitor in Controlled Drug Delivery System for Antitumor[J]. ACS Appl. Mater. Interfaces, 2018,10:2328-2337. doi: 10.1021/acsami.7b16522
6. [6]
  Qiao X Z, Su B S, Liu C, Song Q, Luo D, Mo G, Wang T. Selective Surface Enhanced Raman Scattering for Quantitative Detection of Lung Cancer Biomarkers in Superparticle@MOF Structure[J]. Adv. Mater., 2018,301702275. doi: 10.1002/adma.201702275
7. [7]
  He L C, Liu Y, Liu J Z, Xiong Y S, Zheng J Z, Liu Y L, Tang Z Y. Core-Shell Noble-Metal@Metal-Organic-Framework Nanoparticles with Highly Selective Sensing Property[J]. Angew. Chem. Int. Ed., 2013,125:3829-3833. doi: 10.1002/ange.201209903
8. [8]
  Lu G, Li S Z, Guo Z, Farha O K, Hauser B G, Qi X Y, Wang Y, Wang X, Han S Y, Liu X G. Imparting Functionality to a Metal-Organic Framework Material by Controlled Nanoparticle Encapsulation[J]. Nat. Chem., 2012,4:310-316. doi: 10.1038/nchem.1272
9. [9]
  Chen L Y, Peng Y, Wang H, Gu Z Z, Duan C Y. Synthesis of Au@ZIF-8 Single-or Multi-core-Shell Structures for Photocatalysis[J]. Chem. Commun., 2014,50:8651-8654. doi: 10.1039/C4CC02818J
10. [10]
  Tsuruoka T, Furukawa S, Takashima Y, Yoshida K, Isoda S, Kitagawa S. Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth[J]. Angew. Chem. Int. Ed., 2009,121:4833-4837. doi: 10.1002/ange.200901177
11. [11]
  Cravillon J, Nayuk R, Springer S, Feldhoff A, Huber K, Wiebcke M. Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering[J]. Chem. Mater., 2011,23:2130-2141. doi: 10.1021/cm103571y
12. [12]
  Yanai N, Granick S. Directional Self-Assembly of a Colloidal Metal-Organic Framework[J]. Angew. Chem. Int. Ed., 2012,124:5736-5739. doi: 10.1002/ange.201109132
13. [13]
  Yanai N, Sindoro M, Yan J, Granick S. Electric Field-Induced Assembly of Monodisperse Polyhedral Metal-Organic Framework Crystals[J]. J. Am. Chem. Soc., 2013,135:34-37. doi: 10.1021/ja309361d
14. [14]
  Cravillon J, Münzer S, Lohmeier S J, Feldhoff A, Huber K, Wiebcke M. Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework[J]. Chem. Mater., 2009,21:1410-1412. doi: 10.1021/cm900166h
15. [15]
  Liu S, Xiang Z H, Hu Z, Zheng X P, Cao D P. Zeolitic Imidazolate Framework-8 as a Luminescent Material for the Sensing of Metal ions and Small Molecules[J]. J. Mater. Chem., 2011,21:6649-6653. doi: 10.1039/c1jm10166h
16. [16]
  Ding Q Q, Wang J, Chen X Y, Liu H, Li Q J, Wang Y L, Yang S K. Quantitative and Sensitive SERS Platform with Analyte Enrichment and Filtration Function[J]. Nano Lett., 2020,20:7304-7312. doi: 10.1021/acs.nanolett.0c02683
17. [17]
  Niu J X, Pan C D, Liu Y T, Lou S T, Wu E, Wu B T, Zhang X L, Jin Q Y. Plasmon-Enhanced Fluorescence of Submonolayer Porphyrins by Silver-Polymer Core-Shell Nanoparticles[J]. Opt. Express, 2018,26:3489-3496. doi: 10.1364/OE.26.003489
18. [18]
  Popov P, Steinkerchner L, Mann E K. Molecular Dynamics Study of Rhodamine 6G Diffusion at n-Decane-Water Interfaces[J]. Phys. Rev. E, 2015,91053308. doi: 10.1103/PhysRevE.91.053308
19. [19]
  Zhang X L, Chen L G, Lv P, Gao H Y, Wei S J, Dong Z C, Hou J G. Fluorescence Decay of Quasimonolayered Porphyrins near a Metal Surface Separated by Short-Chain Alkanethiols[J]. Appl. Phys. Lett., 2008,92223118. doi: 10.1063/1.2938861
20. [20]
  Reineck P, Gómez D, Ng S H, Karg M, Bell T, Mulvaney P, Bach U. Distance and Wavelength Dependent Quenching of Molecular Fluorescence by Au@SiO₂ Core-Shell Nanoparticles[J]. ACS Nano, 2013,7:6636-6648. doi: 10.1021/nn401775e
21. [21]
  Zheng G C, de Marchi S, López-Puente V, Sentosun K, Polavarapu L, Pérez-Juste I, Hill E H, Bals S, Liz-Marzán L M, Pastoriza-Santos I. Encapsulation of Single Plasmonic Nanoparticles within ZIF-8 and SERS Analysis of the MOF Flexibility[J]. Small, 2016,12:3935-3943. doi: 10.1002/smll.201600947
22. [22]
  Carrillo-Carrión C, Martínez R, Navarro Poupard, M F, Pelaz B, Polo E, Arenas-Vivo A, Olgiati A, Taboada P, Soliman M G, Catalán Ú. Aqueous Stable Gold Nanostar/ZIF-8 Nanocomposites for Light-Triggered Release of Active Cargo Inside Living Cells[J]. Angew. Chem. Int. Ed., 2019,58:7078-7082. doi: 10.1002/anie.201902817
23. [23]
  Morabito J V, Chou L Y, Li Z H, Manna C M, Petroff C A, Kyada R J, Palomba J M, Byers J A, Tsung C K. Molecular Encapsulation beyond the Aperture Size Limit Through Dissociative Linker Exchange in Metal-Organic Framework Crystals[J]. J. Am. Chem. Soc., 2014,136:12540-12543. doi: 10.1021/ja5054779
24. [24]
  Dulkeith E, Morteani A, Niedereichholz T, Klar T, Feldmann J, Levi S, Van Veggel F, Reinhoudt D, Möller M, Gittins D. Fluorescence Quenching of Dye Molecules Near Gold Nanoparticles: Radiative and Nonradiative Effects[J]. Phys. Rev. Lett., 2002,89203002. doi: 10.1103/PhysRevLett.89.203002
25. [25]
  Anger P, Bharadwaj P, Novotny L. Enhancement and Quenching of Single-Molecule Fluorescence[J]. Phys. Rev. Lett., 2006,96113002. doi: 10.1103/PhysRevLett.96.113002
26. [26]
  Wang D, Pevzner L, Li C, Peneva K, Li C Y, Chan D Y, Müllen K, Mezger M, Koynov K, Butt H J. Layer with Reduced Viscosity at Water-Oil Interfaces Probed by Fluorescence Correlation Spectroscopy[J]. Phys. Rev. E, 2013,87012403. doi: 10.1103/PhysRevE.87.012403
1. [1]
  Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490
2. [2]
  Min ZHU , Yuxin WANG , Xiao LI , Yaxu XU , Junwen ZHU , Zihao WANG , Yu ZHU , Xiaochen HUANG , Dan XU , Monsur Showkot Hossain Abul . Construction of AgVO₃/ZIF-8 composites for enhanced degradation of tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 994-1006. doi: 10.11862/CJIC.20240392
3. [3]
  Guorong Li , Yijing Wu , Chao Zhong , Yixin Yang , Zian Lin . Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ). Chinese Chemical Letters, 2024, 35(5): 108904-. doi: 10.1016/j.cclet.2023.108904
4. [4]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
5. [5]
  Xicheng Li , Dong Mo , Shoushan Hu , Meng Pan , Meng Wang , Tingyu Yang , Changxing Qu , Yujia Wei , Jianan Li , Hanzhi Deng , Zhongwu Bei , Tianying Luo , Qingya Liu , Yun Yang , Jun Liu , Jun Wang , Zhiyong Qian . A Pt@ZIF-8/ALN-ac/GelMA composite hydrogel with antibacterial, antioxidant, and osteogenesis for periodontitis. Chinese Chemical Letters, 2025, 36(9): 110674-. doi: 10.1016/j.cclet.2024.110674
6. [6]
  Tianxia Chen , Yunhui Chen , Weiwei Li , Peipei Cen , Yan Guo , Jin Zhang , Cunding Kong , Xiangyu Liu . Fabricating AuAg-nanoparticles/ZIF-8 composites for selective detection and efficient extraction of dinitroaniline pesticides. Chinese Chemical Letters, 2025, 36(8): 110214-. doi: 10.1016/j.cclet.2024.110214
7. [7]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
8. [8]
  Shaonan Tian , Yu Zhang , Qing Zeng , Junyu Zhong , Hui Liu , Lin Xu , Jun Yang . Core-shell gold-copper nanoparticles: Evolution of copper shells on gold cores at different gold/copper precursor ratios. Chinese Journal of Structural Chemistry, 2023, 42(11): 100160-100160. doi: 10.1016/j.cjsc.2023.100160
9. [9]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
10. [10]
  Shudi Yu , Jie Li , Jiongting Yin , Wanyu Liang , Yangping Zhang , Tianpeng Liu , Mengyun Hu , Yong Wang , Zhengying Wu , Yuefan Zhang , Yukou Du . Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting. Chinese Chemical Letters, 2024, 35(12): 110068-. doi: 10.1016/j.cclet.2024.110068
11. [11]
  Jianning Zhang , Yihuai Zhang , Guoxin Ma , Jingchen Zhao , Tao Zhang , Jian Liu . Enhancing hydrothermal stability in Cu/SSZ-13 catalyst for diesel SCR applications through a novel core-shell structure. Chinese Chemical Letters, 2025, 36(7): 110516-. doi: 10.1016/j.cclet.2024.110516
12. [12]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
13. [13]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
14. [14]
  Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835
15. [15]
  Xin Zhang , Junyu Chen , Xiang Pei , Linxin Yang , Liang Wang , Luona Chen , Guangmei Yang , Xibo Pei , Qianbing Wan , Jian Wang . Drug-loading ZIF-8 for modification of microporous bone scaffold to promote vascularized bone regeneration. Chinese Chemical Letters, 2024, 35(6): 108889-. doi: 10.1016/j.cclet.2023.108889
16. [16]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
17. [17]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
18. [18]
  Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
19. [19]
  Yanting HUANG , Hua XIANG , Mei PAN . Construction and application of multi-component systems based on luminous copper nanoclusters. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2075-2090. doi: 10.11862/CJIC.20240196
20. [20]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(817)
HTML views(85)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142