Citation: Yan-Ru-Zhen WU, Le-Zhi YI, Liang ZHANG, He-Xiang DENG. Rapid Synthesis of Monodisperse Covalent Organic Frameworks Nano-Particles at Ambient Temperature[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1853-1861. doi: 10.11862/CJIC.2021.221 shu

Rapid Synthesis of Monodisperse Covalent Organic Frameworks Nano-Particles at Ambient Temperature

College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China

Corresponding author: He-Xiang DENG, hdeng@whu.edu.cn
Received Date: 12 August 2021
Revised Date: 8 September 2021

Figures(8)

Herein, the rare earth metal trifluoromethanesulfonate salts can function as new types of catalyst for the synthesis of covalent organic frameworks (COF), to accelerate the synthesis of four different types of COF (COF-42, TPB-DMTP, RT-COF-1, COF-LZU1) under ambient conditions and form desirable monodisperse COF nano-particles. Through the systematic optimization of the reaction conditions, the size of the COF particle was precisely controlled in a range of 200~900 nm. X-ray diffraction analysis showed that the resulting COF nano-particle exhibited good crystallinity. In addition, compared with the traditional method usually requiring high-temperature (120℃), this method is suitable for COF production at ambient temperature and pressure within half an hour.
- covalent organic frameworks,
- metal trifluoromethanesulfonate,
- ambient temperature synthesis,
- monodisperse,
- nano-particles
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