Citation: Hui-Ting XU, Yang LIU, Liu-Lei QIN, Huan-Huan QI, Zun-Qi LIU. Synthesis, Phase Transition and Dielectric Properties of 1, 4-Diazabicyclo[2.2.2]octane-Cyanide Cobalt(Ⅲ) Three-Dimensional Framework Hydrogen-Bonding Crystal[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 1950-1960. doi: 10.11862/CJIC.2021.218 shu

Synthesis, Phase Transition and Dielectric Properties of 1, 4-Diazabicyclo[2.2.2]octane-Cyanide Cobalt(Ⅲ) Three-Dimensional Framework Hydrogen-Bonding Crystal

College of Chemical Engineering, Xinjiang Agricultural University, Urumqi 830052, China

Corresponding author: Yang LIU, liuyangxj85@163.com Zun-Qi LIU, zunqi85@163.com
Received Date: 21 February 2021
Revised Date: 29 August 2021

Figures(11)

A Dabco-cobalt cyanide hydrogen-bonding framework crystal material, (H₃O)(H₂Dabco)[Co(CN)₆]·H₂O (1), has been synthesized by solvent evaporation in the mixed solution of methanol and water with 1, 4-diazabicyclo[2.2.2]octane (Dabco) and cobalt cyanide. The structure, thermal energy and electrical properties of the crystal were characterized by single crystal X-ray diffraction, infrared spectroscopy, elemental analysis, X-ray powder diffraction, thermogravimetric analysis, differential scanning calorimetry and variable temperature-frequency dielectric constant test. The space group of the crystal is P2₁/c, which belongs to the monoclinic system at low and room temperature. The structure shows that the cobalt cyano anion, water molecules and protonated water molecules are mutually connected through hydrogen bonds in the crystal to form a three-dimensional network framework, and the protonated (H₂Dabco)²⁺ cations are embedded in it forming a molecular motor-type cystic structure. With the increase of temperature, the (H₂Dabco)²⁺ cations are twisted, which causes a phase transition in the crystal structure near 254 K. Dielectric anomalies occurs along the three axes of the crystal, showing obvious dielectric anisotropy at the same temperature.
- crystal structure,
- hydrogen bond,
- three-dimensional framework structure,
- phase transition,
- dielectric properties
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